Multi-ionic nanofiltration of highly concentrated salt mixtures in the seawater range

Desalination

Volumn 277, Issue 1-3, 2011, Pages 29-39

  Silva, V ^a   Geraldes, V ^b   Brites Alves, A M ^b   Palacio, L ^a   Pradanos P ^a   Hernandez A ^a  

^a UNIVERSITY OF VALLADOLID   (Spain)

^b INSTITUTO SUPERIOR TÉCNICO   (Portugal)

Author keywords

Ionic separation; Multicomponent; Nanofiltration; Seawater; SEDE VCh

Indexed keywords

COUNTERIONS; DIELECTRIC CONSTANTS; DIVALENT IONS; EXPERIMENTAL OBSERVATION; IONIC COMPOSITION; IONIC SEPARATIONS; MEMBRANE CHARGE; MEMBRANE PARAMETERS; MEMBRANE PORES; MONOVALENT IONS; MONOVALENT SALT; MULTICOMPONENTS; NACL CONCENTRATION; SALT MIXTURES; SEDE-VCH;

FORECASTING; NANOFILTRATION; NANOFILTRATION MEMBRANES; SEAWATER; SODIUM CHLORIDE;

IONS;

CONCENTRATION (COMPOSITION); DIELECTRIC PROPERTY; EXPERIMENTAL STUDY; FILTRATION; IONIC COMPOSITION; MEMBRANE; SEAWATER; SEPARATION; SOLUTION;

EID: 79960171703     PISSN: 00119164     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.desal.2011.03.088     Document Type: Article

References (43)

1. V. Nikolay, S. Raphael, Seawater Desalination, Dr. Norman N. Li, Dr Anthony G. Fane Dr W. S. Winston Ho Dr T. Matsuura, 2008.
2. Council Directive 98/83/EC of 3 November 1998 on the quality of water intended for human consumption., in.
3. Dickson A.G., Goyet C. Chapter 5. Handbook of methods for the analysis of the various parameters of the carbon dioxide system in sea water, version 2, ORNL/CDIAC-74 1994.
4. Redondo J.A. Brackish-, sea- and wastewater desalination, in: European Conference on Desalination and the Environment - Water Shortage 2001, Lemesos, Cyprus, pp. 29-40.
5. Bouranene S., Fievet P., Szymczyk A. Investigating nanofiltration of multi-ionic solutions using the steric, electric and dielectric exclusion model. Chem. Eng. Sci. 2009, 64:3789-3798.
6. Cavaco Morão A.I., Szymczyk A., Fievet P., Brites Alves A.M. Modelling the separation by nanofiltration of a multi-ionic solution relevant to an industrial process. J. Membr. Sci. 2008, 322:320-330.
7. Wang D.-X., Wang X.-L., Tomi Y., Ando M., Shintani T. Modeling the separation performance of nanofiltration membranes for the mixed salts solution. J. Membr. Sci. 2006, 280:734-743.
8. Tanninen J., Mänttäri M., Nyström M. Effect of salt mixture concentration on fractionation with NF membranes. J. Membr. Sci. 2006, 283:57-64.
9. Sabaté J., Labanda J., Llorens J. Influence of coion and counterion size on multi-ionic solution nanofiltration. J. Membr. Sci. 2009, 345:298-304.
10. Garcia-Aleman J., Dickson J.M. Permeation of mixed-salt solutions with commercial and pore-filled nanofiltration membranes: membrane charge inversion phenomena. J. Membr. Sci. 2004, 239:163-172.
11. Bowen W.R., Julian S.W., Paul M.W. Linearized transport model for nanofiltration: development and assessment. AlChE J. 2002, 48:760-773.
12. Déon S., Dutournié P., Limousy L., Bourseau P. Transport of salt mixtures through nanofiltration membranes: numerical identification of electric and dielectric contributions. Sep. Purif. Technol. 2009, 69:225-233.
13. Silva V. Theoretical foundations and modelling in nanofiltration membrane systems, in: PhD-Thesis Facultad de Ciencias 2009, Universidad de Valladolid, Valladolid, pp. 208.
14. Silva V., Martín Á., Martínez F., Malfeito J., Prádanos P., Palacio L., Hernández A. Electrical Characterization of NF Membranes. A Modified Model with Charge Variation along the Pores. Chem. Eng. Sci. 2011, 66:2898-2911.
15. Robinson R.A., Stokes R.H. Electrolyte solutions July 2002, Dover Publications, Mineola, NY. Second Revised Edition.
16. Perez-Villasenor F., Bedolla-Hernandez M.L., Iglesias-Silva G.A. Osmotic and activity coefficients of 1:1, 1:3, 1:4, 2:1, 2:2, 3:1, 3:2 and 4:1 strong electrolytes at 298.15K using a modified Pitzer equation. Ind. Eng. Chem. Res. 2007, 46:6366-6374.
17. Perez-Villasenor F., Iglesias-Silva G.A., Hall K.R. Prediction of osmotic and activity coefficients using a modified Pitzer equation for multicomponent strong electrolyte systems at 298K. Ind. Eng. Chem. Res. 2003, 42:1087-1092.
18. Perez-Villasenor F., Iglesias-Silva G.A., Hall K.R. Osmotic and activity coefficients using a modified Pitzer equation for strong electrolytes 1:1 and 1:2 at 298.15K. Ind. Eng. Chem. Res. 2002, 41:1031-1037.
19. Walter J.H., Yung-Chi W. Osmotic coefficients and mean activity coefficients of uni-univalent electrolytes in water at 25[degree]C. J. Physical Chemical Reference Data 1972, 1:1047-1100.
20. Van Gauwbergen D., Baeyens J., Creemers C. Modeling osmotic pressures for aqueous solutions for 2-1 and 2-2 electrolytes. Desalination 1997, 109:57-65.
21. Mohammad A.W., Hilal N., Al-Zoubi H., Darwish N.A. Prediction of permeate fluxes and rejections of highly concentrated salts in nanofiltration membranes. J. Membr. Sci. 2007, 289:40-50.
22. Bowen W.R., Welfoot J.S. Modelling of membrane nanofiltration-pore size distribution effects. Chem. Eng. Sci. 2002, 57:1393-1407.
23. Bowen W.R., Welfoot J.S. Modelling the performance of membrane nanofiltration-critical assessment and model development. Chem. Eng. Sci. 2002, 57:1121-1137.
24. Szymczyk A., Sbai M., Fievet P., Vidonne A. Transport properties and electrokinetic characterization of an amphoteric nanofilter. Langmuir 2006, 22:3910-3919.
25. Bandini S., Vezzani D. Nanofiltration modeling: the role of dielectric exclusion in membrane characterization. Chem. Eng. Sci. 2003, 58:3303-3326.
26. Bowen W.R., Mohammad A.W., Hilal N. Characterisation of nanofiltration membranes for predictive purposes - use of salts, uncharged solutes and atomic force microscopy. J. Membr. Sci. 1997, 126:91-105.
27. Rashin A.A., Honig B. Reevaluation of the Born model of ion hydration. J. Phys. Chem. 1985, 89:5588-5593.
28. Newman J., Thomas-Alyea K.E. Electrochemical systems 2004, University of California, Berkley. 3rd edition.
29. Dechadilok P., Deen W.M. Hindrance factors for diffusion and convection in pores. Ind. Eng. Chem. Res. 2006, 45:6953-6959.
30. Silva V., Prádanos P., Palacio L., Calvo J.I., Hernández A. Relevance of hindrance factors and hydrodynamic pressure gradient in the modelization of the transport of neutral solutes across nanofiltration membranes. Chem. Eng. J. 2009, 149:78-86.
31. Otero J.A., Mazarrasa O., Villasante J., Silva V., Prádanos P., Calvo J.I., Hernández A. Three independent ways to obtain information on pore size distributions of nanofiltration membranes. J. Membr. Sci. 2008, 309:17-27.
32. Cheryan M. Ultrafiltration Handbook 1986, Technomic Pub. Co., Lancaster, USA.
33. Geraldes V., Afonso M.D. Prediction of the concentration polarization in the nanofiltration/reverse osmosis of dilute multi-ionic solutions. J. Membr. Sci. 2007, 300:20-27.
34. van den Berg G.B., Rácz I.G., Smolders C.A. Mass transfer coefficients in cross-flow ultrafiltration. J. Membr. Sci. 1989, 47:25-51.
35. Koutsou C.P., Yiantsios S.G., Karabelas A.J. A numerical and experimental study of mass transfer in spacer-filled channels: Effects of spacer geometrical characteristics and Schmidt number. J. Membr. Sci. 2009, 326:234-251.
36. Vítor G., Maria Diná A. Generalized mass-transfer correction factor for nanofiltration and reverse osmosis. AlChE J. 2006, 52:3353-3362.
37. Hussain A.A., Nataraj S.K., Abashar M.E.E., Al-Mutaz I.S., Aminabhavi T.M. Prediction of physical properties of nanofiltration membranes using experiment and theoretical models. J. Membr. Sci. 2008, 310:321-336.
38. Wesolowska K., Koter S., Bodzek M. Modelling of nanofiltration in softening water. Desalination 2004, 162:137-151.
39. Lide D.R. Handbook of Chemistry and Physics 1994, (Boca Raton). 75th ed.
40. M. Montalvillo, V. Silva, L. Palacio, A. Hernández, P. Prádanos., Dielectric properties of electrolyte solutions in polymeric nanofiltration membranes, Desalin. Water Treat., (Accepted for publication).
41. Rodrigues C., Cavaco Morão A.I., de Pinho M.N., Geraldes V. On the prediction of permeate flux for nanofiltration of concentrated aqueous solutions with thin-film composite polyamide membranes. J. Membr. Sci. 2010, 346:1-7.
42. Braeken L., Bettens B., Boussu K., Van der Meeren P., Cocquyt J., Vermant J., Van der Bruggen B. Transport mechanisms of dissolved organic compounds in aqueous solution during nanofiltration. J. Membr. Sci. 2006, 279:311-319.
43. Navarro R., González M.P., Saucedo I., Avila M., Prádanos P., Martínez F., Martín A., Hernández A. Effect of an acidic treatment on the chemical and charge properties of a nanofiltration membrane. J. Membr. Sci. 2008, 307:136-148.