Room-temperature spontaneous magnetization in a coordination π-π Framework

Journal of Physical Chemistry Letters

Volumn 2, Issue 13, 2011, Pages 1567-1571

  Giri, Sanjib ^a   Saha, Shyamal K ^a  

^a DEPARTMENT OF MATERIALS SCIENCE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

BIPYRIDINE LIGANDS; HIGHER TEMPERATURES; HYDROGEN ATOMS; PYRIDYL RINGS; ROOM TEMPERATURE; SPONTANEOUS MAGNETIZATION; STERIC REPULSIONS; TEMPERATURE REGIONS;

LIGANDS; MAGNETIC SUSCEPTIBILITY; PARAMAGNETISM;

MAGNETIZATION;

EID: 79960169284     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz200607q     Document Type: Article

References (28)

1. 2O: A Crystalline Molecule-Based Magnet with a Magnetic Ordering Temperature above 100AC J. Am. Chem. Soc. 1999, 121, 5593-5594 (Pubitemid 29292989)
2. Coronado, E.; Galaén-Mascaroés, J. R.; Goémez- Garciéa, C. J.; Laukhin, V. Coexistence of Ferromagnetism and Metallic Conductivity in a Molecule-Based Layered Compound Nature 2009, 408, 447-449
3. Ferlay, S.; Mallah, T.; Ouahès, R.; Veillet, P.; Verdaguer, M. A Chromium-Vanadyl Ferrimagnetic Molecule-Based Magnet: Structure, Magnetism, and Orbital Interpretation Inorg. Chem. 1999, 38, 229-234
4. Kahn, O. Molecular Magnetism; VCH Publishers: New York, 1993.
5. Nakagawa, M.; Ishida, T.; Suzuki, M.; Hashizume, D.; Yasui, M.; Iwasaki, F.; Nogami, T. Intermolecular Ferromagnetic Interaction in the Crystal of a Diphenyl Nitroxide Derivative. The Role of Spin-Polarized Hydrogen Atoms Located Near a Neighboring N-O Site Chem. Phys. Lett. 1999, 302, 125-131 (Pubitemid 129549427)
6. Awaga, K.; Inabe, T.; Maruyama, Y.; Nakamura, T.; Matsumoto, M. Ferromagnetic and Antiferromagnetic Intermolecular Interactions in the Two-Dimensional Triangular Lattice of the m-N -Methylpyridinium Nitronyl Nitroxide Cation Radical Chem. Phys. Lett. 1992, 195, 21-24
7. Maspoch, D.; Catala, L.; Gerbier, P.; Ruiz-Molina, D.; Vidal-Gancedo, J.; Wurst, K.; Rovira, C.; Veciana, J. Radical para -Benzoic Acid Derivates: Transmission of Ferromagnetic Interactions through Hydrogen Bonds at Long Distances Chem.-Eur. J. 2002, 8, 3635-3645 (Pubitemid 34951451)
8. Ma, Y.; Chenga, A.-L.; Gao, E.-Q. Ferromagnetic Interactions through Triple Hydrogen Bonds in the Coordination Polymers of α,α′- Dihydroxy-bibenzyl-4,4′-dicarboxylate Dalton Trans. 2010, 39, 3521-3526
9. Li, L.-L.; Lin, K.-J.; Ho, C.-J.; Sun, C.-P.; Yang, H.-D. A Coordination π-π Framework Exhibits Spontaneous Magnetization Chem. Commun. 2006, 1286-1288
10. Guennic, B. L.; Amor, N. B.; Maynau, D.; Robert, V. Addressing Through-H Magnetic Interactions: A Comprehensive Ab Initio Analysis of This Efficient Coupler J. Chem. Theory Comput. 2009, 5, 1506-1510
11. Chi, Y.-H.; Yu, L.; Shi, J.-M.; Zhang, Y.-Q.; Hu, T.-Q.; Zhang, G.-Q.; Shi, W.; Cheng, P. π-π Stacking and Ferromagnetic Coupling Mechanism on a Binuclear Cu(II) Complex Dalton Trans. 2011, 40, 1453-1462
12. Yoshizawat, K.; Hoffmann, R. The Role of Orbital Interactions in Determining Ferromagnetic Coupling in Organic Molecular Assemblies J. Am. Chem. Soc. 1995, 117, 6921-6926
13. Bhatt, P.; Kanciurzewska, A.; Carlegrim, E.; Kapilashrami, M.; Belova, L.; Rao, K. V.; Fahlman, M. Ferromagnetism above Room Temperature in Nickel-Tetracyanoethylene Thin Films J. Mater. Chem. 2009, 19, 6610-6615
14. Ferlay, S.; Mallah, T.; Ouahes, R.; Veillet, P.; Verdaguer, M. Room-Temperature Organometallic Magnet Based on Prussian Blue Nature 1995, 378, 701-703 (Pubitemid 126647272)
15. Kurmoo, M.; Kepert, C. J. A Room-Temperature Organometallic Magnet Based on Prussian Blue New J. Chem. 1998, 22, 1515-1524
16. Jain, R.; Kabir, K.; Gilroy, J. B.; Mitchell, K. A. R.; Wong, K.-C.; Hicks, R. G. High-Temperature Metal-Organic Magnets Nature 2007, 445, 291-294 (Pubitemid 46127400)
17. 4 Bull. Chem. Soc. Jpn. 1971, 44, 2412-2415
18. n J. Coord. Chem. 2004, 57, 401-409
19. Sun, J.; Xu, H. Synthesis, Structures and Properties of Cu(II) and Mn(II) Complexes with 1,10-Phenanthroline-2-carboxylic acid and 2,2′-Bipyridine Ligands Molecules 2010, 15, 8349-8359
20. Pabst, G.; Katsaras, J.; Raghunathan, V. A. Enhancement of Steric Repulsion with Temperature in Oriented Lipid Multilayers Phys. Rev. Lett. 2002, 88, 128101-128104
21. Miyake, Y.; Watanabe, S.; Aono, S.; Nishinaga, T.; Miyazaki, A.; Enoki, T.; Miyasaka, H.; Otani, H.; Iyoda, M. Long-Distance Ferromagnetic Coupling through Spin Polarization in a Linear Heterotrinuclear Iron(III)-Copper(II)- Iron(III) Complex Derived from 5-Ferrocenyl-2-aminotropone Chem. Commun. 2008, 6167-6169
22. Dul, M.-C.; Ottenwaelder, X.; Pardo, E.; Lescouzec, R.; Journaux, Y.; Chamoreau, L.-M.; Ruiz-Garca, R.; Cano, J.; Julve, M.; Lloret, F. Ferromagnetic Coupling by Spin Polarization in a Trinuclear Copper(II) Metallacyclophane with a Triangular Cage-Like Structure Inorg. Chem. 2009, 48, 5244-5249
23. Frisch, M. J.; Trucks, G. W.; Schlegel, H. B.; Scuseria, G. E.; Robb, M. A.; Cheeseman, J. R.; Montgomery, J. A., Jr.; Vreven, T.; Kudin, K. N.; Burant, J. C.; Gaussian 03, revision E.01; Gaussian Inc.: Pittsburgh, PA, 2004.
24. Becke, A. D. Density-Functional Thermochemistry. III. The Role of Exact Exchange J. Chem. Phys. 1993, 98, 5648-5652
25. Becke, A. D. Density-Functional Exchange-Energy Approximation with Correct Asymptotic Behavior Phys. Rev. A: At., Mol., Opt. Phys. 1988, 38, 3098-3100
26. Lee, C.; Yang, W.; Parr, R. G. Development of the Colle-Salvetti Correlation-Energy Formula into a Functional of the Electron Density Phys. Rev. B 1988, 37, 785-789
27. Schäfer, A.; Huber, C.; Ahlrichs, R. Fully Optimized Contracted Gaussian Basis Sets of Triple Zeta Valence Quality for Atoms Li to Kr J. Chem. Phys. 1994, 100, 5829-5835
28. Giri, S.; Biswas, S.; Drew, M. G. B.; Ghosh, A.; Saha, S. K. Structure and Magnetic Properties of a Tetranuclear Cu(II) Complex Containing the 2-(Pyridine-2-yliminomethyl)-Phenol Ligand Inorg. Chim. Acta 2011, 368, 152-156