Long-distance ferromagnetic coupling through spin polarization in a linear heterotrinuclear iron(III)-copper(II)-iron(III) complex derived from 5-ferrocenyl-2-aminotropone

Chemical Communications

Volumn , Issue 46, 2008, Pages 6167-6169

  Miyake, Yoshihiro ^a,d   Watanabe, Sayaka ^a   Aono, Satoshi ^a   Nishinaga, Tohru ^a   Miyazaki, Akira ^b   Enoki, Toshiaki ^b   Miyasaka, Hitoshi ^a,e   Otani, Hiroyuki ^c   Iyoda, Masahiko ^a  

^a TOKYO METROPOLITAN UNIVERSITY   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

^c YOKOHAMA NATIONAL UNIVERSITY   (Japan)

^d UNIVERSITY OF TOKYO   (Japan)

^e TOHOKU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPLEX; FERROCENE DERIVATIVE; FERROMAGNETIC MATERIAL; IRON COMPLEX; TROPONE DERIVATIVE;

ABSORPTION SPECTROSCOPY; ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; MOLECULAR INTERACTION; REACTION ANALYSIS; SOLID STATE; TEMPERATURE DEPENDENCE;

EID: 56849118125     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b813944j     Document Type: Article

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37. Cu)
38. Electronic structure calculations were performed with density functional B3LYP method and the triple-ζ (TZV) basis set by using Gaussian-03 program. The broken-symmetry approach was implemented for the doublet state. The atomic spin densities were obtained by Mulliken population analysis