Removal of Cu 2+ and Pb 2+ Ions Using CMC Based Thermoresponsive Nanocomposite Hydrogel

Clean - Soil, Air, Water

Volumn 39, Issue 7, 2011, Pages 658-664

  Özkahraman, Bengi ^a   Acar, Işil ^b   Emik, Serkan ^b  

^a HITIT UNIVERSITY   (Turkey)

^b ISTANBUL UNIVERSITY   (Turkey)

Author keywords

CMC; Heavy metal removal; Hydrogel; Montmorillonite; Nanocomposite; NIPAm

Indexed keywords

ADSORPTION; COMPOSITE; COPPER; LEAD; MONTMORILLONITE; POLLUTANT REMOVAL;

EID: 79960128359     PISSN: 18630650     EISSN: 18630669     Source Type: Journal    
DOI: 10.1002/clen.201000553     Document Type: Article

References (53)

1. Y. Ren, M. Zhang, D. Zhao, Synthesis and Properties of Magnetic Cu(II) Ion Imprinted Composite Adsorbent for Selective Removal of Copper, Desalination 2008, 228, 135- 149.
2. B. S. Kim, S. T. Lim, Removal of Heavy Metal Ions from Water by Cross-Linked Carboxymethyl Corn Starch, Carbohydr. Polym. 1999, 39, 217- 223.
3. L. Yi, W. Wenbo, W. Aiqin, Adsorption of Lead Ions from Aqueous Solution by Using Carboxymethyl Cellulose-g-Poly (Acrylic Acid)/Attapulgite Hydrogel Composites, Desalination 2010, 259, 258- 264.
4. A. K. Bhattacharya, S. N. Mandal, S. K. Das, Adsorption of Zn(II) from Aqueous Solution by Using Different Adsorbents, Chem. Eng. J. 2006, 123, 43- 51.
5. X.-J. Ju, S.-B. Zhang, M.-Y. Zhou, R. Xie, L. Yang, L.-Y. Chu, Novel Heavy-Metal Adsorption Material: Ion-Recognition p(NIPAM-co-BCAm) Hydrogels for Removal of Lead(II) Ions, J. Hazard. Mater. 2009, 167, 114- 118.
6. B. Özkahraman, I. Acar, S. Emik, Removal of Cationic Dyes from Aqueous Solutions with Poly(N-Isopropylacrylamide-co-Itaconic Acid) Hydrogels, Polym. Bull. 2011, 66, 551- 557.
7. A. Kara, L. Uzun, N. Beşirli, A. Denizli, Poly(Ethylene Glycol Dimethacrylate-n-Vinyl Imidazole) Beads for Heavy Metal Removal, J. Hazard. Mater. 2004, 106B, 93- 99.
8. R. Ilnam, T. Çaykara, Ö. Kantoǧlu, Polarographic Determination of Uranyl Adsorption onto Poly(Acrylamide-g-Ethylenediaminetetraacetic Acid) Hydrogels in the Presence of Cadmium and Lead, Nuclear Inst. Met. Phys. Res. 2003, 208, 400- 404.
9. A. El-Hag Ali, H. A. Shawky, H. A. Abd El Rehim, E. A. Hegazy, Synthesis and Characterization of PVP/AAc Copolymer Hydrogel and Its Applications in the Removal of Heavy Metals from Aqueous Solution, Eur. Polym. J. 2003, 39, 2337- 2344.
10. H. A. Essawy, H. S. Ibrahim, Synthesis and Characterization of Poly(Vinylpyrrolidone-co-Methylacrylate) Hydrogel for Removal and Recovery of Heavy Metal Ions from Wastewater, React. Funct. Polym. 2004, 61, 421- 432.
11. G. Güçlü, G. Gürdaǧ, S. Özgümüş Competitive Removal of Heavy Metal Ions by Cellulose Graft Copolymers, J. Appl. Polym. Sci. 2003, 90, 2034- 2039.
12. 2+ Ions by Cellulose Graft Copolymers, Desalination 2000, 130, 85- 88.
13. F. E. Okieimen, C. E. Sogbaike, J. E. Ebhoaye, Removal of Cadmium and Copper Ions from Aqueous Solution with Cellulose Graft Copolymers, Sep. Purif. Technol. 2005, 44, 85- 89.
14. 2+ Ions from Aqueous Solutions by Starch-Graft-Acrylic Acid/Montmorillonite Superabsorbent Nanocomposite Hydrogels, Polym. Bull. 2010, 65, 333- 346.
15. S. Keleş, G. Güçlü, Competitive Removal of Heavy Metal Ions by Starch-Graft-Acrylic Acid Copolymers, Polym. Plast. Technol. Eng. 2006, 45, 365- 371.
16. 2+ Ions from Aqueous Solutions by Starch-Graftacrylic Acid Hydrogels, Polym. Plast. Technol. Eng. 2006, 45, 55- 59.
17. G. Güçlü, K. Güçlü, S. Keleş, Competitive Removal of Nickel(II), Cobalt(II), and Zinc(II) Ions from Aqueous Solutions by Starch-Graft-Acrylic Acid Copolymers, J Appl. Polym. Sci. 2007, 106, 1800- 1805.
18. M. I. Khalil, S. Farag, Utilization of Some Starch Derivatives in Heavy Metal Ions Removal, J. Appl. Polym. Sci. 1998, 69, 45- 50.
19. M. I. Khalil, M. G. Abdel-Halim, Preparation of Anonic Starch Containing Carboxyl Groups and 1st Utilization as Chelating Agent, Starch 2001, 53, 35- 41.
20. F. C. F. Barros, F. W. Sousa, R. M. Cavalcante, T. V. Carvalho, F. S. Dias, D. C. Queiroz, L. C. G. Vasconcellos, R. F. Nascimento, Removal of Copper, Nickel and Zinc Ions from Aqueous Solution by Chitosan-8-Hydroxyquinoline Beads, Clean - Soil Air Water 2008, 36, 292- 298.
21. W. S. W. Ngah, N. F. M. Ariff, A. Hashim, M. A. K. M. Hanafiah, Malachite Green Adsorption onto Chitosan Coated Bentonite Beads: Isotherms, Kinetics and Mechanism, Clean - Soil Air Water 2010, 38, 394- 400.
22. X. S. Wang, Y. J. Tang, L. F. Chen, F. Y. Li, W. Y. Wan, Y. B. Tan, Removal of Cr(VI) by Zero-Valent, Iron-Encapsulated Alginate Beads, Clean - Soil Air Water 2010, 38, 263- 267.
23. J. Chen, F. Tendeyong, S. Yiacoumi, Equilibrium and Kinetic Studies of Copper Ion Uptake by Calcium Alginate, Environ. Sci. Technol. 1997, 31, 1433- 1439.
24. X. Wanga, Y. Zheng, A. Wang, Fast Removal of Copper Ions from Aqueous Solution by Chitosan-g-Poly(Acrylic Acid)/Attapulgite Composites, J. Hazard. Mater. 2009, 168, 970- 977.
25. A. R. Wach, H. Mitomo, F. Yoshii, T. Kume, Hydrogel of Biodegradable Cellulose Derivatives. II. Effect of Some Factors on Radiation-Induced Crosslinking of CMC, J. Appl. Polym. Sci. 2001, 81, 3030- 3037.
26. A. Pourjavadi, H. Ghasemzadeh, F. Mojahedi, Swelling Properties of CMC-g-Poly (AAm-co-AMPS) Superabsorbent Hydrogel, J. Appl. Polym. Sci. 2009, 113, 3442- 3449.
27. A. Pourjavadi, S. Barzegar, G. R. Mahdavinia, MBA-Crosslinked Na-Alg/CMC as a Smart Full-Polysaccharide Superabsorbent Hydrogel, Carbohydr. Polym. 2006, 66, 386- 395.
28. J. Li, J. Lu, Y. Li, Carboxylmethylcellulose/Bentonite Composite Gels: Water Sorption Behavior and Controlled Release of Herbicide, J. Appl. Polym. Sci. 2009, 112, 261- 268.
29. K. M. E. Salmawi, Application of Polyvinyl Alcohol (PVA)/Carboxymethyl Cellulose (CMC) Hydrogel Produced by Conventional Crosslinking or by Freezing and Thawing, J. Macromol. Sci. Part A Pure Appl. Chem. 2007, 44, 619- 624.
30. A. Pourjavadi, M. J. Zohuriaan-Mehr, S. N. Ghasempoori, H. Hossienzadeh, Modified CMC. V. Synthesis and Super-Swelling Behavior of Hydrolyzed CMC-g-PAN Hydrogel, J. Appl. Polym. Sci. 2007, 103, 877- 883.
31. J. Ma, Y. Xu, B. Fan, B. Liang, Preparation and Characterization of Sodium Carboxymethylcellulose/Poly(N-Isopropylacrylamide)/Clay Semi-IPN Nanocomposite Hydrogels, Eur. Polym. J. 2007, 43, 2221- 2228.
32. J. Ma, L. Zhang, B. Fan, Y. Xu, B. Liang, A Novel Sodium Carboxymethylcellulose/Poly(N-Isopropylacrylamide)/Clay Semi-IPN Nanocomposite Hydrogel with Improved Response Rate and Mechanical Properties, J. Polym. Sci. Part B Polym. Phys. 2008, 46, 1546- 1555.
33. R. Zhang, Y. Hu, J. Xu, W. Fan, Z. Chen, Flammability and Thermal Stability Studies of Styrene-Butyl Acrylate Copolymer/Graphite Oxide Nanocomposite, Polym. Degrad. Stab. 2004, 85, 583- 588.
34. H. Essawy, A. Badran, A. Youssef, A. E. A. El-Hakim, Synthesis of Poly(Methylmethacrylate)/Montmorillonite Nanocomposites via In situ Intercalative Suspension and Emulsion Polymerization, Polym. Bull. 2009, 53, 9- 17.
35. P. B. Messersmith, F. Znidarsich, Synthesis and LCST Behavior of Thermally Responsive Poly(N-isopropylacrylamide)/Layered Silicate Nanocomposites, in Nanophase and Nanocomposite Materials. II. Materials Research Society Symposium Proceedings (Eds: S. Komarneni, J. C. Parker, H. J. Wollenberger ) Materials Research Society, Pittsburgh, PA 1997, 457- 507.
36. X. H. Xia, J. Yih, N. A. D'Souza, Z. B. Hu, Swelling and Mechanical Behavior of Poly(N-Isopropylacrylamide)/Namontmorillonite Namontmorillonite Layered Silicates Composite Gels, Polymer 2003, 44, 3389- 3393.
37. S. V. Vinogradov, T. K. Bronich, V. A. Kabanov, Nanosized Cationic Hydrogels for Drug Delivery: Preparation, Properties and Interactions with Cells, Adv. Drug. Delivery Rev. 2002, 54, 135- 147.
38. F. Bergaya, M. Vayer, CEC of Clays: Measurement by Adsorption of a Copper Ethylenediamine Complex, Appl. Clay Sci. 1997, 12, 275- 280.
39. H. Y. Liu, X. X. Zhu, Lower Critical Solution Temperatures of N-Substituted Acrylamide Copolymers in Aqueous Solutions, Polymer 1999, 40, 6985- 6990.
40. R. Pelton, Temperature-Sensitive Aqueous Microgels, Adv. Colloid Interface Sci. 2000, 85, 1- 33.
41. M. Dalaran, S. Emik, G. Güçlü, T. B. Iyim, S. Özgümüş, Removal of Acidic Dye from Aqueous Solutions Using Poly(DMAEMA-AMPS-HEMA) Terpolymer/MMT Nanocomposite Hydrogels, Polym. Bull. 2009, 63, 159- 171.
42. G. Chen, S. Liu, S. Chen, Z. Qi, FTIR Spectra, Thermal Properties, and Dispersibility of a Polystyrene/Montmorillonite Nanocomposite, Macromol. Chem. Phys. 2001, 202, 1189- 1193.
43. L. J. Bellamy, The Infra-Red Spectra of Complex Molecules, 3rd ed., Chapman & Hall, London 1975.
44. K. Kratz, T. Hellweg, W. Eimer, Influence of Charge Density on the Swelling of Colloidal Poly(N-Isopropylacrylamide-co-Acrylic Acid) Microgels, Colloids Surf., A 2000, 170, 137- 149.
45. F. Seker, A. B. Ellis, Correlation of Chemical Structure and Swelling Behavior in N-Alkylacrylamide Hydrogels, J. Polym. Sci. Part A Polym. Chem. 1998, 36, 2095- 2102.
46. J. Zhang, Q. Wang, A. Wang, Synthesis and Characterization of Chitosan-g-Poly(acrylic acid)/Attapulgite Superabsorbent Composites, Carbohydr. Polym. 2007, 68, 367- 374.
47. A. Li, R. F. Liu, A. Q. Wang, Preparation of Starch-Graft Poly (Acrylamide)/Attapulgite Superabsorbent Composite, J. Appl. Polym. Sci. 2005, 98, 1351- 1357.
48. A. Li, A. Q. Wang, Synthesis and Properties of Clay-Based Superabsorbent Composite, Eur. Polym. J. 2005, 41, 1630- 1637.
49. A. Li, A. Q. Wang, J. M. Chen, Studies on Poly(Acrylic Acid)/Attapulgite Superabsorbent Composite. I. Synthesis and Characterization, J. Appl. Polym. Sci. 2004, 92, 1596- 1603.
50. L. Wang, J. Zhang, A. Wang, Fast Removal of Methylene Blue from Aqueous Solution by Adsorption onto Chitosan-g-Poly (Acrylic Acid)/Attapulgite Composite, Desalination 2011, 266, 33- 39.
51. H. Chen, A. Wang, Adsorption Characteristics of Cu(II) from Aqueous Solutions onto Poly(Acrylamide)/Attapulgite Composite, J. Hazard. Mater. 2009, 165, 223- 231.
52. G. McKay, Y. S. Ho, The Sorption of Lead(II) on Peat, Water. Res. 1999, 33, 78- 584.
53. G. McKay, Y. S. Ho, Pseudo-Second Order Model for Sorption Processes, Process Biochem. 1999, 34, 451- 465.