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Chemistry - A European Journal

Volumn 17, Issue 29, 2011, Pages 8023-8027

Synthesis of polyaromatic hydrocarbons from bis(biaryl)diynes: Large PAHs with low Clar sextets

(2) Chen, Tse An a Liu, Rai Shung a

a NATIONAL TSING HUA UNIVERSITY (Taiwan)

Author keywords

aromaticity; hydrocarbons; oxidation; synthetic methods; UV Vis spectroscopy

Indexed keywords

AROMATICITIES; BENZOQUINONES; POLYAROMATIC HYDROCARBONS; SYNTHETIC METHODS; SYNTHETIC PROTOCOLS; UV/ VIS SPECTROSCOPY;

OXIDATION;

HYDROCARBONS;

EID: 79960020285 PISSN: 09476539 EISSN: 15213765 Source Type: Journal
DOI: 10.1002/chem.201101057 Document Type: Article

Times cited : (33)

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- For compound 3e, we envisage that the two cove regions have the same stereochemistry as that of 3a; hence, the chirality of fjord region is dependent on the cove stereochemistry because the A-ring should have the three hydrogen atoms coplanar with the benzene ring. Therefore an alteration of the cove chirality is always accompanied by the change of fjord chirality.

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