Formation of a strandlike polycatenane of icosahedral cages for reversible one-dimensional encapsulation of guests

Journal of the American Chemical Society

Volumn 133, Issue 26, 2011, Pages 10018-10021

  Heine, Johanna ^a   Schmedt Auf Der Günne, Jörn ^b   Dehnen, Stefanie ^a  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

^b UNIVERSITY OF MUNICH   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

DYNAMIC COMPOSITION; GUEST MOLECULES; NANO-DROPLETS; SOLID-STATE NMR SPECTROSCOPY;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

CAGES (MINE HOISTS);

CATENANE; CRYSTALLIN; NANOCAGE;

ARTICLE; CHEMICAL STRUCTURE; ENCAPSULATION; PARTICLE SIZE; POLARIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; SOLID STATE;

EID: 79959917417     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja2030273     Document Type: Article

References (47)

1. For example, see: Caulder, D. L.; Raymond, K. N. Acc. Chem. Res. 1999, 32, 975
2. Leininger, S.; Olenyuk, B.; Stang, P. J. Chem. Rev. 2000, 100, 853
3. Dinolfo, P. H.; Hupp, J. T. Chem. Mater. 2001, 13, 3113
4. Holliday, B. J.; Mirkin, C. A. Angew. Chem., Int. Ed. 2001, 40, 2022
5. Cotton, F. A.; Lin, C.; Murillo, C. A. Acc. Chem. Res. 2001, 34, 759
6. Swiegers, G. F.; Malefetse, T. J. Coord. Chem. Rev. 2002, 225, 91
7. Seidel, S. R.; Stang, P. J. Acc. Chem. Res. 2002, 35, 972
8. Gianneschi, N. C.; Masar, M. S., III; Mirkin, C. A. Acc. Chem. Res. 2005, 38, 825
9. Fujita, M.; Tominaga, M.; Hori, A.; Therrien, B. Acc. Chem. Res. 2005, 38, 371
10. Fujita, M.; Nagao, S.; Ogura, K. J. Am. Chem. Soc. 1995, 117, 1649
11. Su, C.-Y.; Cai, Y.-P.; Chen, C.-L.; Smith, M. D.; Kaim, W.; zur Loye, H.-C. J. Am. Chem. Soc. 2003, 125, 8595-8613
12. Yoshizawa, M.; Nakagawa, J.; Kumazawa, K.; Nagao, M.; Kawano, M.; Ozeki, T.; Fujita, M. Angew. Chem., Int. Ed. 2005, 44, 1810
13. Ghosh, S.; Mukherjee, P. S. Organometallics 2008, 27, 316
14. Zheng, Y.-R.; Zhao, Z.; Wang, M.; Ghosh, K.; Pollock, J. B.; Cook, T. R.; Stang, P. J. J. Am. Chem. Soc. 2010, 132, 16873
15. Wang, M.; Zheng, Y.-R.; Ghosh, K.; Stang, P. J. J. Am. Chem. Soc. 2010, 132, 6282
16. Wang, M.; Vajpayee, V.; Shanmugaraju, S.; Zheng, Y.-R.; Zhao, Z.; Kim, H.; Mukherjee, P. S.; Chi, K.-W.; Stang, P. J. Inorg. Chem. 2011, 50, 1506
17. Sun, Q.-F.; Iwasa, J.; Ogawa, D.; Ishido, Y.; Sato, S.; Ozeki, T.; Sei, Y.; Yamaguchi, K.; Fujita, M. Science 2010, 328, 1144
18. Fiedler, D.; Leung, D. H.; Bergman, R. G.; Raymond, K. N. Acc. Chem. Res. 2005, 38, 351
19. Yoshizawa, M.; Klosterman, J. K.; Fujita, M. Angew. Chem., Int. Ed. 2009, 48, 3418
20. Suzuki, K.; Takao, K.; Sato, S.; Fujita, M. Angew. Chem., Int. Ed. 2011, 50, 4858
21. Molecular Catenanes, Rotaxanes and Knots; Sauvage, J.-P.; Dietrich-Buchecker, C., Eds.; Wiley-VCH: Weinheim, Germany, 1999.
22. Fujita, M.; Fujita, N.; Ogura, K.; Yamaguchi, K. Nature 1999, 400, 52
23. Westcott, A.; Fisher, J.; Harding, L. P.; Rizkallah, P.; Hardie, M. J. J. Am. Chem. Soc. 2008, 130, 2950
24. Kuang, X.; Wu, X.; Yu, R.; Donahue, J. P.; Huang, J.; Lu, C.-Z. Nat. Chem. 2010, 2, 461
25. 2 (all data) = 0.2312, S (all data) = 0.854. CCDC 809386. Additional details may be found in the SI.
26. Sheldrick, G. M. SHELXTL, version 5.1; Bruker AXS Inc.: Madison, WI, 1997.
27. Spek, A. L. Acta Crystallogr. 1990, A46, c34
28. Brasey, T.; Scopelliti, R.; Severin, K. Chem. Commun. 2006, 3308
29. In principle, the composition of eight planar tripodal ligands and 12 bidentate components may also yield a cuboctahedron. Several cuboctahedral coordination cages have been reported, both as singular units (15) and contained within a network of cages. (16) However, in the present case, the icosahedron is a more appropriate description because the windows of the cage, while quadrilateral in nature, deviate significantly from the planar square required for the formation of a cuboctahedron.
30. Olenyuk, B.; Whiteford, J. A.; Fechtenkötter, A.; Stang, P. J. Nature 1999, 398, 796
31. Ghosh, K.; Hu, J.; White, H. S.; Stang, P. J. J. Am. Chem. Soc. 2009, 131, 6695
32. Inokuma, Y.; Arai, T.; Fujita, M. Nat. Chem. 2010, 2, 780
33. Niu, Z.; Gibson, H. W. Chem. Rev. 2009, 109, 6024
34. Fang, L.; Olson, M. A.; Beniétez, D.; Tkatchouk, E.; Goddard, W. A., III; Stoddart, J. F. Chem. Soc. Rev. 2010, 39, 17
35. Jin, C.-M.; Lu, H.; Wu, L.-Y.; Huang, J. Chem. Commun. 2006, 5039
36. Jin, C.-M.; Wu, L.-Y.; Lu, H.; Xu, Y. Cryst. Growth Des. 2008, 8, 215
37. Wells, A. F. Structural Inorganic Chemistry, 5 th ed.; Oxford University Press: Oxford, U.K., 1984.
38. Eichinger, K.; Nussbaumer, P.; Vytlacil, R. Spectrochim. Acta, Part A 1987, 43, 731
39. Batten, S. R.; Hoskins, B. F.; Robson, R. J. Am. Chem. Soc. 1995, 117, 5385
40. Avadhut, Y. S.; Schneider, D.; Schmedt auf der Günne, J. J. Magn. Reson. 2009, 201, 1
41. For the network nomenclature, see the following references: O'Keeffe, M.; Peskov, M. A.; Ramsden, S. J.; Yaghi, O. M. Acc. Chem. Res. 2008, 41, 1782
42. Blatov, V. A.; Carlucci, L.; Ciani, G.; Proserpio, D. M. CrystEngComm. 2004, 6, 377
43. Baburin, I. A.; Blatov, V. A.; Carlucci, L.; Ciani, G.; Proserpio, D. M. J. Solid State Chem. 2005, 178, 2452
44. Biradha, K.; Fujita, M. Angew. Chem., Int. Ed. 2002, 41, 3392
45. Batten, S. R.; Robson, R. Angew. Chem., Int. Ed. 1998, 37, 1460
46. Wang, B.-C.; Wu, Q.-R.; Hu, H.-M.; Chen, X.-L.; Yang, Z.-H.; Shangguan, Y.-Q.; Yang, M.-L.; Xue, G.-L. CrystEngComm. 2010, 12, 485
47. Feike, M.; Demco, D. E.; Graf, R.; Gottwald, J.; Hafner, S.; Spiess, H. W. J. Magn. Reson. 1996, A122, 214