Iron speciation in urban dust

Atmospheric Environment

Volumn 45, Issue 26, 2011, Pages 4528-4532

  Elzinga, Evert J ^a   Gao, Yuan ^a   Fitts, Jeffrey P ^b   Tappero, Ryan ^b  

^a RUTGERS UNIVERSITY   (United States)

^b BROOKHAVEN NATIONAL LABORATORY   (United States)

Author keywords

Iron; Micro focused X ray absorption spectroscopy; Speciation; Urban dust

Indexed keywords

ANTHROPOGENIC IMPACTS; CHARACTERIZATION TECHNIQUES; CRITICAL STEPS; DUST PARTICLE; DUST SAMPLES; FE K-EDGE; FE SPECIES; MAGNETITE CONTENTS; MINERALOGICAL COMPOSITIONS; NEW JERSEY , USA; PARTICLE COMPOSITION; PARTICLE HETEROGENEITY; QUANTITATIVE DETERMINATIONS; RELATIVE ABUNDANCE; SIZE FRACTION; SOLUBILITY MODELS; SPECIATION; URBAN DUST; X-RAY MICROPROBES; XRD;

ABSORPTION; ABSORPTION SPECTROSCOPY; CRYSTALLOGRAPHY; IRON COMPOUNDS; IRON ORES; MINERALOGY; OXIDE MINERALS; SPECTRUM ANALYSIS; X RAY ABSORPTION; X RAY ABSORPTION SPECTROSCOPY; X RAYS;

DUST;

FERRIC HYDROXIDE; FERRIC OXIDE; IRON; MAGNETITE;

ANTHROPOGENIC EFFECT; ATOMIC ABSORPTION SPECTROSCOPY; CHEMICAL COMPOSITION; DUST; IRON; MAGNETITE; MINERAL; PARTICLE SIZE; QUANTITATIVE ANALYSIS; SOLUBILITY; SPECIATION (CHEMISTRY); SPECTRAL ANALYSIS; URBAN ATMOSPHERE; X-RAY DIFFRACTION; X-RAY SPECTROSCOPY;

ARTICLE; CONTROLLED STUDY; DUST; MINERALOGY; OXIDATION; PRIORITY JOURNAL; QUANTITATIVE ANALYSIS; UNITED STATES; URBAN AREA; X RAY ABSORPTION SPECTROSCOPY;

NEW JERSEY; NEWARK; UNITED STATES;

EID: 79959871110     PISSN: 13522310     EISSN: 18732844     Source Type: Journal    
DOI: 10.1016/j.atmosenv.2011.05.042     Document Type: Article

References (26)

1. Arai Y., Marcus M.K., Tamura N., Davis J.A., Zachara J.M. Spectroscopic evidence for uranium bearing precipitates in vadose zone sediments at the Hanforf 300-area site. Environmental Science & Technology 2007, 41:4633-4639.
2. Chuang P.Y., Duvall R.M., Shafer M.M., Schauer J.J. The origin of water soluble particulate iron in the Asian atmospheric outflow. Geophysical Research Letters 2005, 32:L07813.
3. Coale K.H., Johnson K.S., Fitzwater S.E., et al. A massive phytoplankton bloom induced by an ecosystem-scale iron fertilization experiment in the equatorial Pacific Ocean. Nature 1996, 383:495-501.
4. Cornell R.M., Schwertmann U. The Iron Oxides: Structure, Properties, Reactions, Occurrences and Uses 2003, Wiley Verlag, Weinheim, Germany.
5. Cwiertny D.M., Baltrusaitis J., Hunter G.J., Laskin A., Scherer M.M., Grassian V.H. Characterization and acid-mobilization study of iron-containing mineral dust source materials. Journal of Geophysical Research 2008, 113:D05202.
6. Dedik A.N., Hoffmann P. Chemical characterization of iron in atmospheric aerosols. Atmospheric Environment Part A - General Topics 1992, 26:2545-2548.
7. Falkowski P.G. Evolution of the nitrogen cycle and its influence on the biological sequestration of CO2 in the ocean. Nature 1997, 387:272-275.
8. Isaure M.P., Laboudique A., Manceau A., Sarret G., Tiffreau C., Trocellier P., Lamble G., Hazemann J.L., Chateigner D. Quantitative Zn speciation in a contaminated dredged sediment by u-PIXE, u-SXRF, EXAFS spectroscopy and principal component analysis. Geochimica et Cosmochimica Acta 2002, 66:1549-1567.
9. Klementiev K.V. XANES Dactyloscope for Windows, Freeware 2002, (accessed 31.05.10.). http://www.cells.es/Beamlines/CLAESS/software/xanda.html.
10. Majestic B.J., Schauer J.J., Shafer M.M. Application of synchrotron radiation for measurement of iron red-ox speciation in atmospherically processed aerosols. Atmospheric Chemistry and Physics 2007, 7:2475-2487.
11. Manceau A., Lanson B., Schlegel M.L., Harge J.C., Musso M., Eybert-Berard L., Hazemann J.L., Chateigner D., Lamble G.M. Quantitative Zn speciation in smelter-contaminated soils by EXAFS spectroscopy. American Journal of Science 2000, 300:289-343.
12. Manceau A., Marcus M.A., Tamura N., Proux O., Geoffroy N., Lanson B. Natural speciation of Zn at the micrometer scale in a clayey soil using X-ray fluorescence, absorption and diffraction. Geochimica et Cosmochimica Acta 2004, 68:2467-2483.
13. Matzka J., Maher B.A. Magnetic biomonitoring of roadside tree leaves: identification of spatial and temporal variations in vehicle-derived particulates. Atmospheric Environment 1999, 33:4565-4569.
14. Morris W.A., Versteeg J.K., Bryant D.W., Legzdins A.E., McCarry B.E., Marvin C.H. Preliminary comparison between mutagenicity and magnetic susceptibility of respirable airborne particulates. Atmospheric Environment 1995, 29:3441-3450.
15. O'Day P.A., Rivera N., Root R., Carroll S.A. X-ray absorption spectroscopic study of Fe reference compounds for the analysis of natural sediments. American Mineralogist 2004, 89:572-585.
16. Ostergren J.D., Brown G.E., Parks G.A., Tingle T.N. Quantitative speciation of lead in selected mine tailings from Leadville, CO. Environmental Science & Technology 1999, 33:1627-1636.
17. Ressler T. WinXAS: a new software package not only for the analysis of energy-dispersive XAS data. Journal de Physique IV 1997, 7:269-270.
18. Scheinost A.C., Kretzschmar R., Pfister S. Combining selective sequential extractions, X-ray absorption spectroscopy, and principal component analysis for quantitative zinc speciation in soil. Environmental Science & Technology 2002, 36:5021-5028.
19. Schroth A.W., Crusius J., Sholkovitz E.R., Bostick B.C. Iron solubility driven by speciation in dust sources to the ocean. Nature Geoscience 2009, 2:337-340.
20. Sedwick P.N., Sholkovitz E.R., Church T.M. Impact of anthropogenic combustion emissions on the fractional solubility of aerosol iron: evidence from the Sargasso Sea. Geochemistry Geophysics Geosystems 2007, 8:Q10Q06.
21. Tong Y., Li A., Cai Y., Ni X., Zhang Y., Wang J., Guo P., Li X., Zhang G. Mössbauer study of atmospheric aerosols of Shanghai. Environmental Science & Technology 2001, 35:1432-1436.
22. Wang Y., Li A., Zhang Y., Xie Y., Li D., Li Y., Zhang G. Speciation of iron in atmospheric particulate matter by EXAFS. Chinese Science Bulletin 2006, 51:2275-2280.
23. Watson A.J., Lefevre N. The sensitivity of atmospheric CO2 concentrations to input of iron to the oceans. Tellus 1999, 51B:453-460.
24. Wilke M., Farges F., Petit P.M., Brown G.E., Martin F. Oxidation state and coordination of Fe in minerals: an Fe K-XANES spectroscopic study. American Mineralogist 2001, 86:714-730.
25. Xia D.S., Chen F.H., Bloemendal J., Liu X.M., Yu Y., Yang L.P. Magnetic properties of urban dustfall in Lanzhou, China, and its environmental implications. Atmospheric Environment 2008, 42:2198-2207.
26. Zhao Y.L., Gao Y. Mass size distributions of water soluble inorganic and organic ions in size-segregated aerosols over metropolitan Newark in the US east coast. Atmospheric Environment 2008, 42:4063-4078.