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See the Supporting Information.
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See the Supporting Information.
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26
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79959712543
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3CN as a source of the succinate dianion. Other anions were prepared as well. When a CD experiment with chiral methylsuccinic acid was carried out in the absence of dicyclohexylamine, no CD signal was induced by 1b.
-
3CN as a source of the succinate dianion. Other anions were prepared as well. When a CD experiment with chiral methylsuccinic acid was carried out in the absence of dicyclohexylamine, no CD signal was induced by 1b.
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27
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79959755647
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Ligand exchange with a succinate anion on the platinum center was largely acceralated in 1b by cooperative binding (required period to reach the equilibrium at room temperature: 10 h for 3 and 1 h for 1b).
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Ligand exchange with a succinate anion on the platinum center was largely acceralated in 1b by cooperative binding (required period to reach the equilibrium at room temperature: 10 h for 3 and 1 h for 1b).
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79959691171
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Complex 2b similarly exhibited UV and CD spectral changes upon complexation with succinate 4a. See Figure S5 in the Supporting Information.
-
Complex 2b similarly exhibited UV and CD spectral changes upon complexation with succinate 4a. See Figure S5 in the Supporting Information.
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