Linear and branched alkyl substituted octakis(dimethylsiloxy) octasilsesquioxanes: WAXS and thermal properties

European Polymer Journal

Volumn 47, Issue 7, 2011, Pages 1370-1382

  Xavier Perrin, F ^a   Viet Nguyen, T B ^a,b   Margaillan, Andre ^a  

^a UNIVERSITÉ DE TOULON   (France)

^b VIETNAM NATIONAL UNIVERSITY   (Viet Nam)

Author keywords

Hybrid inorganic organic materials; Nanostructure; POSS; Silsesquioxanes

Indexed keywords

AIR ATMOSPHERE; ALKYL CHAIN; ALKYL CHAIN LENGTHS; ALKYL GROUPS; ALKYL SUBSTITUENT; AMORPHOUS GLASS; ENTROPY OF FUSION; HEAT OF FUSION; HIGH YIELD; HYBRID INORGANIC/ORGANIC MATERIALS; INTERDIGITATIONS; OCTASILSESQUIOXANE; POLARIZED OPTICAL MICROSCOPY; POSS; PT-CATALYZED; SILSESQUIOXANES; THERMAL BEHAVIORS;

CHAIN LENGTH; CRYSTAL STRUCTURE; HYBRID MATERIALS; HYDROSILYLATION; OLEFINS; OPTICAL MICROSCOPY; ORGANIC POLYMERS; PLATINUM;

THERMODYNAMIC PROPERTIES;

EID: 79959334711     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2011.04.004     Document Type: Article

References (42)

1. G. Calzaferri Octasilsesquioxanes R. Corriu, P. Jutzi, Tailor-made silicon-oxygen compounds 1996 Braunschweig Vieweg
2. D.B. Cordes, P.D. Lickiss, and F. Rataboul Recent developments in the chemistry of cubic polyhedral oligosilsesquioxanes Chem Rev 110 2010 2081 2173
3. J. Lichtenhan Silsesquioxane-based polymers J.C. Salmone, Polymeric materials encyclopedia 1996 CRC Press New York
4. A. Purkayastha, and J.B. Baruah Review: synthetic methodologies in siloxanes Appl Organomet Chem 18 2004 166 175
5. L. Matejka, A. Strachota, J. Plestil, P. Whelan, M. Steinhart, and M. Slouf Epoxy networks reinforced with polyhedral oligomeric silsesquioxanes (POSS). Structure and morphology Macromolecules 37 2004 9449 9456 (Pubitemid 40002672)
6. B.X. Fu, L. Yang, R.H. Somani, S.X. Zong, B.S. Hsiao, and S. Philipps Crystallization studies of isotactic polypropylene containing nanostructured polyhedral oligomeric silsesquioxane molecules under quiescent and shear conditions J Polym Sci Part B Polym Phys 39 2001 2727 2739 (Pubitemid 33025721)
7. J.H. Chen, B.X. Yao, W.B. Su, and Y.B. Yang Isothermal crystallization behavior of isotactic polypropylene blended with small loading of polyhedral oligomeric silsesquioxane Polymer 48 2007 1756 1769
8. A. Fina, D. Tabuani, and G. Camino Polypropylene-polysilsesquioxane blends Eur Polym J 46 2010 14 23
9. K. Olson Ark Kemi 13 1958 367
10. M.M. Sprung, and F.O. Guenther The partial hydrolysis of ethyltriethoxysilane J Am Chem Soc 77 1955 3996 4002
11. 8 silsesquioxane cages and X-ray crystal structures of some novel spherosilicates Dalton Trans 2003 2945 2949
12. 12 mittels hydrosilylierung kurzmitteilung Helv Chim Acta 74 1991 1278 1280
13. A.R. Bassindale, and T.E. Gentle Siloxane and hydrocarbon octopus molecules with silsesquioxane cores J Mater Chem 3 1993 1319 1325
14. C. Bolln, A. Tsuchida, H. Frey, and R. Mulhaupt Thermal properties of the homologous series of 8-fold alkyl-substituted octasilsesquioxanes Chem Mater 9 1997 1475 1479 (Pubitemid 127471942)
15. 15 Inorg Chem 30 1991 2707 2708
16. A. Tsuchida, C. Bolln, F.G. Sernetz, H. Frey, and R. Mulhaupt Ethene and propene copolymers containing silsesquioxane side groups Macromolecules 30 1997 2818 2824 (Pubitemid 127579415)
17. I. Hasegawa, and S. Sakka Silicate species with cagelike structure in solutions and rapid solidification with organic quaternary ammonium ions M.L. Occelli, H.E. Robson, Zeolite synthesis. ACS symposium series 398 1989 American Chemical Society Washington DC
18. x (x = 6, 8, 10) octasilsesquioxanes J Mater Chem 15 2005 3725 3744 (Pubitemid 41417058)
19. I. Hasegawa, K. Ino, and H. Ohnishi An improved procedure for syntheses of silyl derivatives of the cubeoctameric silicate anion Appl Organometal Chem 17 2003 287 290
20. J. Huang, Z. Liu, X. Liu, C. He, S.Y. Chow, and J. Pan Platinum nanoparticles from the hydrosilylation reaction: capping agents, physical characterizations, and electrochemical properties Langmuir 21 2005 699 704 (Pubitemid 40168856)
21. P.R. Dvornic, and V.V. Gerov Polymerization by hydrosilation. 1. Preparation of poly[(1,1,3,3-tetramethyldisiloxanyl)ethylene]. A preliminary report Macromolecules 27 1994 1068 1070
22. R. Knischka, F. Dietsche, R. Hanselmann, H. Frey, and R. Mulhaupt Silsesquioxane-based amphiphiles Langmuir 15 1999 4752 4756 (Pubitemid 128769771)
23. Y.C. Sheen, C.H. Lu, C.F. Huang, S.W. Kuo, and F.C. Chang Synthesis and characterization of amorphous octakis-functionalized polyhedral oligomeric silsesquioxanes for polymer nanocomposites Polymer 49 2008 4017 4024
24. J. Choi, A.F. Yee, and R.M. Laine Organic/inorganic hybrid composites from cubic silsesquioxanes. Epoxy resins of octa(dimethylsiloxyethylcyclohexylepoxide) silsesquioxane Macromolecules 36 2003 5666 5682
25. E. Markovic, J. Matisons, M. Hussain, and G.P. Simon Poly(ethylene glycol) octafunctionalized polyhedral oligomeric silsesquioxane: WAXD and rheological studies Macromolecules 40 2007 4530 4534 (Pubitemid 47110746)
26. K.Y. Mya, C. He, J. Huang, Y. Xiao, J. Dai, and Y.P. Siow Preparation and thermomechanical properties of epoxy resins modified by octafunctional cubic silsesquioxane epoxides J Polym Sci Part A Polym Chem 42 2004 3490 3503
27. Y.S. Ye, Y.C. Yen, W.Y. Chen, C.C. Cheng, and F.C. Chang A simple approach toward low-dielectric polyimide nanocomposites: Blending the polyimide precursor with a fluorinated polyhedral oligomeric silsesquioxane J Polym Sci Part A Polym Chem 46 2008 6296 6304
28. 8 with vinylcyclohexene Polym Int 56 2007 1378 1391 (Pubitemid 47593187)
29. J. Zhang, R. Xu, and D. Yu A novel poly-benzoxazinyl functionalized polyhedral oligomeric silsesquioxane and its nanocomposite with polybenzoxazine Eur Polym J 43 2007 743 752 (Pubitemid 46273403)
30. M. Voronkov, V. Mileshkevich, and Yu. Yuzhelevskii The siloxane bond - physical properties and chemical transformations 1978 Plenum Publishing Corporation New York
31. C. Eaborn Organosilicon compounds 1960 Academic Press New York
32. M. Sanchez-Soto, D.A. Schiraldi, and S. Illescas Study of the morphology and properties of melt-mixed polycarbonate-POSS nanocomposites Eur Polym J 45 2009 341 352
33. A.J. Waddon, and E.B. Coughlin Crystal Structure of polyhedral oligomeric silsequioxane (POSS) nano-materials: a study by x-ray diffraction and electron microscopy Chem Mater 15 2003 4555 4561
34. N. Auner, B. Ziemer, B. Herrschaft, W. Ziche, P. John, and J. Weis Structural studies of novel siloxysilsesquioxanes Eur J Inorg Chem 1999 1087 1094
35. M.E. Glicksman, and A.O. Lupulescu Dendritic crystal growth in pure materials J Crystal Growth 264 2004 541 549
36. G.M. Poliskie, T.S. Haddad, R.L. Blanski, and K.K. Gleason Characterization of the phase transitions of ethyl substituted polyhedral oligomeric silsesquioxane Thermochim Acta 438 2005 116 125 (Pubitemid 41543014)
37. M.J. Abad, L. Barral, D.P. Fasce, and R.J.J. Williams Epoxy networks containing large mass fractions of a monofunctional polyhedral oligomeric silsesquioxane (POSS) Macromolecules 36 2003 3128 3135
38. G.S. Parks, H.M. Huffman, and S.B. Thomas Thermal data on organic compounds. VI. The heat capacities, entropies and free energies of some saturated, non-benzenoid hydrocarbons J Am Chem Soc 52 1930 1032 1041
39. I.S. Isayeva, and J.P. Kennedy Amphiphilic membranes crosslinked and reinforced by POSS J Polym Sci Part A Polym Chem 42 2004 4337 4352
40. R. Mantz, P.F. Jones, K.P. Chaffee, J.D. Lichtenhan, J.W. Gilman, and I.M.K. Ismail Thermolysis of polyhedral oligomeric silsesquioxane (POSS) macromers and POSS-siloxane copolymers Chem Mater 8 1996 1250 1259 (Pubitemid 126477670)
41. A. Fina, D. Tabuani, F. Carniato, A. Frache, E. Boccaleri, and G. Camino Polyhedral oligomeric silsesquioxanes (POSS) thermal degradation Thermochim Acta 440 2006 36 42 (Pubitemid 41770841)
42. C.M. Brick, E.R. Chan, S.C. Glotzer, J.C. Marchal, D.C. Martin, and R.M. Laine Self-lubricating nano-ball-bearings Adv Mater 19 2007 82 86 (Pubitemid 46144814)