A Pd-Fe/α-Al2O3/cordierite monolithic catalyst for CO coupling to oxalate

Chemical Engineering Science

Volumn 66, Issue 15, 2011, Pages 3513-3522

  Gao, Xiaochen ^a   Zhao, Yujun ^a   Wang, Shengping ^a   Yin, Yilin ^a   Wang, Baowei ^a   Ma, Xinbin ^a  

^a TIANJIN UNIVERSITY   (China)

Author keywords

Catalysis; CO coupling; Diethyl oxalate; Monolithic; Palladium; Washcoat

Indexed keywords

ACTIVE METALS; CATALYTIC PERFORMANCE; CHARACTERIZATION TECHNIQUES; CO CONVERSION; CONTINUOUS FLOWS; DIETHYL OXALATES; ETHYL NITRITE; FIXED-BED; HIGH DISPERSION; MICRO-REACTOR; MILD REACTION CONDITIONS; MONOLITHIC; MONOLITHIC CATALYSTS; OPTIMAL THICKNESS; PD NANO PARTICLE; PHYSICOCHEMICAL PROPERTY; SPACE TIME YIELD; SURFACE ACIDITY; WASHCOATS;

ALUMINUM; CATALYST ACTIVITY; IONIC LIQUIDS; METALS; PALLADIUM; SILICATE MINERALS; SURFACE STRUCTURE; SYNTHESIS (CHEMICAL);

CATALYST SELECTIVITY;

EID: 79958712085     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2011.04.012     Document Type: Article

References (49)

1. Agraotis C., Tsetsekou A. The effect of powder characteristics on washcoat quality. Part I: alumina washcoats. J. Eur. Ceram. Soc. 2008, 20:815-824.
2. Amato G., Brunetto N. Porous silicon via freeze drying. Mater. Lett. 1996, 26:295-298.
3. Bartley, W.J., Charleston, W.V., 1987. Process for the preparation of ethylene glycol. US Pat. 4,677,234.
4. Celik F.E., Lawrence H., Bell A.T. Synthesis of precursors to ethylene glycol from formaldehyde and methyl formate catalyzed by heteropoly acids. J. Mol. Catal. A 2008, 288:87-96.
5. Centi G., Perathoner S. Novel catalyst design for multiphase reactions. Catal. Today 2001, 79-80:3-13.
6. Chen J.W., Yang H., Wang N., Ring Z., Dabros T. Mathematical modeling of monolith catalysts and reactors for gas phase reactions. Appl. Catal. A 2008, 345:1-11.
7. Chen L.F., Guo P.J., Qiao M.H., Yan S.R., Li H.X., Shen W., Xua H.L., Fan K.N. Cu/SiO2 catalysts prepared by the ammonia-evaporation method: texture, structure, and catalytic performance in hydrogenation of dimethyl oxalate to ethylene glycol. J. Catal. 2008, 257:172-180.
8. Chilba T. Process for the preparation of oxalate by ethylene glycol. J. Chem. Phys. 1964, 41:1352.
9. Coq B., Figueras F. Bimetallic palladium catalysts: influence of the co-metal on the catalyst performance. J. Mol. Catal. A 2001, 173:117-134.
10. Cybulski A., Moulijn J.A. Structured Catalysts and Reactors 1998, Marcel Dekker, New York.
11. Fable J. New synthesis with carbon monoxide. J. Mol. Catal. 1980, 31:123-126.
12. Fang J.G., Wang B.W., Li Z.H., Xu G.H. Study on the reaction of CO coupling to oxalate. React. Kinet. Catal. Lett. 2003, 80:293-301.
13. Fenton D.M., Steinwand P.J. Noble metal catalysis. III. Preparation of dialkyl oxalates by oxidative carbonylation. J. Org. Chem. 1974, 39:701-704.
14. Franco R., Ugo R. Alkoxy carbonyl complexes of palladium and their role in alcohol carbonylation. J. Org. Chem. 1978, 154:323-326.
15. Gao Z.H., Liu Z.C., He F., Xu G.H. Combined XPS and in situ DRIRS study of mechanism of Pd-Fe/α-Al2O3 catalyzed CO coupling reaction to diethyl oxalate. J. Mol. Catal. A 2005, 235:143-149.
16. Gao Z.H., Wu Q., He F., Li Z.H., Xu G.H. Effect of oxygen on the activity of a Pd-Fe/a-Al2O3 catalyst for CO coupling to diethyl oxalate. React. Kinet. Catal. Lett. 2002, 76:303-310.
17. Geus J.W., van Giezen J.C. Monoliths in catalytic oxidation. Catal. Today 1999, 47:69-180.
18. Heck R.M., Gulati S., Farrauto R.J. The application of monoliths for gas phase catalytic reactions. Chem. Eng. J. 2001, 82:149-156.
19. Jiang X.Z. Palladium supported catalysts in CO+RONO reactions. Platinum Met. Rev. 1990, 34:178-180.
20. Jiang X.Z., Su Y.H., Lee B.J., Chien S.H. A study on the synthesis of diethyl oxalate over Pd/Al2O3 catalysts. Appl. Catal. A 2001, 211:47-51.
21. Kapteijn F., Heiszwolf J.J., Nijhuis T.A., Moulijn J.A. Monoliths in multiphase catalytic processes-aspects and prospects. CATTECH 1999, 3:24-40.
22. Kapteijn F., Moulijn J.A. Laboratory catalytic reactors: aspects of catalyst testing. Handb. Heterogeneous Catal. 1997, 3:1359-1376.
23. Kapteijn F., Nijhuis T.A., Heiszwolf J.J., Moulijn J.A. New non-traditional multiphase catalytic reactors based on monolithic structures. Catal. Today 2001, 6:133-144.
24. Kenji, N., Kozo, F., Keigo, N., Masaoki, M., Shinichiro, U., 1980. Process for preparing a diester of oxalic acid in the gaseous phase. US Pat. 4,229,591.
25. Kirk O. Encyclopedia of Chemical Technology 1980, p. 16, 619. third ed.
26. Li Y.C., Yan S.R., Yang W.M., Xie Z.K., Chen Q.L., Yue B., He H.Y. Effects of support modification on Nb2O5/α-Al2O3 catalyst for ethylene oxide hydration. J. Mol. Catal. A 2005, 226:285-290.
27. Li Z.H., He C.Y., Yin D.X., Wang B.W., Ma X.B., Xu G.H. Macrokinetics of CO catalytic coupling reaction to produce diethyl oxalate. J. Chem. Ind. Eng. (China) 2005, 12:2315-2319.
28. Li Z.H., Song Y., Du P., Ma X.B., Wang B.W., Xu G.H. Effect of hydrogen on catalytic coupling reaction of carbon monoxide to diethyl oxalate. React. Kinet. Catal. Lett. 2001, 73:135-143.
29. Li Z.H., Xu G.H., Du P., Ma X.B., Wang B.W. Deactivation kinetics of CO coupling reaction after addition of H2 to the system. React. Kinet. Catal. Lett. 2003, 78:201-209.
30. Matsuzaki T., Nakamura A. Dimethyl carbonate synthesis and other oxidative reactions using alkyl nitrites. Catal. Surv. Jpn. 1997, 1:77-88.
31. Ma X.B., Xu G.H., Chen J.W., Chen H.F. Kinetics of carbon monoxide catalytic coupling to diethyl oxalate in gaseous phase. J. Chem. Ind. Eng. (China) 1995, 46:50-56.
32. Meng F.D., Xu G.H., Guo Q.R. Kinetics of the catalytic coupling reaction of carbon monoxide to diethyl oxalate over Pd-Fe/a-Al2O3 catalyst. J. Mol. Catal. A 2003, 201:283-288.
33. Meng F.D., Xu G.H., Guo R.Q., Yan H.F., Chen M.Q. Kinetic study of carbon monoxide coupling reaction over supported palladium catalyst. Chem. Eng. Prog. 2004, 43:785-790.
34. Metzner A.B., Ehrreich J.E. The vapor-phase catalytic hydration of ethylene oxide to glycols. AIChE J. 1959, 5:496-501.
35. Miyazaki, H., Shiomi, Y., Fujitus, S., Masunaga, K., Yanagisawa, H., 1983. Process for preparing oxalic acid diesters using platinum group metals supported on alumina. US Pat. 4,410,722.
36. Miyazaki, H., Shiomi, Y., Fujitus, S., Masunaga, K., Yanagisawa, H., 1985. Process for the production of a diester of oxalic acid. US Pat. 4,507,494.
37. Miyazaki, H., Uda, T., Hirai, K., Nakamura, Y., Ikezawa, H., Tsuchie, T., 1986. Process for producing ethylene glycol and/or glycolic acid ester, catalyst composition used there for, and process for production. US Pat. 4,585,890.
38. Nijhuis A., Beers A.E.W., Vergunst T., Hoek I., Kapteijn F., Moulijn J.A. Preparation of monolithic catalysts. Catal. Rev. 2001, 43:345-380.
39. Ohdan, K., Matsuzaki, T., Hidaka, M., 1997. Process for preparation of dialkyl oxalate. EP Pat. 0,802,175.
40. Shiomi, Y., Matsuzaki, T., Masunaga, K., 1989. Process for the preparation of a diester of oxalic acid. US Pat. 4,874,888.
41. Tahara, S., Fujii, K., Nishihira, K., Matsuda, M., Mizutare, K., 1984a. Process for continuous preparation of diester of oxalic acid. US Pat. 4,467,109.
42. Tahara, S., Fujii, K., Nishihira, K., Matsuda, M., Mizutare, K., 1984b. Process for continuously preparing ethylene glycol. US Pat. 4,453,026.
43. Thomas D.J., Wehrli J.T., Wainwright M.S., Trimm D.L. Hydrogenolysis of diethyl oxalate over copper-based catalysts. Appl. Catal. A 1992, 86:101-114.
44. Uchiumi S., Ataka K., Matsuzaki T. Oxidative reactions by a palladium-alkyl nitrite system. J. Organomet. Chem. 1999, 576:278-289.
45. Vergunst T., Kapteijn F., Moulijn J.A. Monolithic catalysts-non-uniform active phase distribution by impregnation. Appl. Catal. A 2001, 213:179-187.
46. Williams J.L. Monolith structures, materials, properties and uses. Catal. Today 2001, 69:3-9.
47. Xu G.H., Li Y.C., Li Z.H., Wang H.J. Kinetics of the hydrogenation of diethyl oxalate to ethylene glycol. Ind. Eng. Chem. Res. 1995, 34:2371-2378.
48. Xu G.H., Ma X.B., He F., Chen H.F. Characteristics of catalyst for carbon monoxide coupling reaction. Ind. Eng. Chem. Res. 1995, 34:2379-2382.
49. Zhao X.G., Lin Q., Xiao W.D. Characterization of Pd-CeO2/α-alumina catalyst for synthesis of dimethyl oxalate. Appl. Catal. A 2005, 84:253-257.