Bond rotation dynamics of enamides: The effect of the acyl group and potential for chirality transfer during 5-endo trig radical cyclizations

Journal of Organic Chemistry

Volumn 76, Issue 11, 2011, Pages 4546-4551

  Clark, Andrew J ^a   Curran, Dennis P ^b   Geden, Joanna V ^a   James, Natalie ^a   Wilson, Paul ^a  

^a UNIVERSITY OF WARWICK   (United Kingdom)

^b UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACYL GROUP; BOND ROTATIONS; CHIRALITY TRANSFER; DIFFERENT SOLVENTS; ENAMIDES; NON-POLAR SOLVENTS; POLAR SOLVENTS; RADICAL CYCLIZATIONS; RELATIVE ORDER; VARIABLE-TEMPERATURE NMR;

CHIRALITY; CYCLIZATION; ENANTIOMERS; METHANOL; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC SOLVENTS; SOLVENTS; STEREOCHEMISTRY; TOLUENE;

ROTATION;

ACETAMIDE DERIVATIVE; CHLOROFORM; METHANOL; N CYCLOHEX 1 ENYL N BENZAMIDE; N CYCLOHEX 1 ENYL N BENZYL 2 BROMO 2 METHYLPROPIONAMIDE; N CYCLOHEX 1 ENYL N BENZYL 2 BROMOPROPIONAMIDE; N CYCLOHEX 1 ENYL N BENZYL 2 DIMETHYLPROPIONAMIDE; N CYCLOHEX 1 ENYL N BENZYL 2 METHYLPROPIONAMIDE; N CYCLOHEX 1 ENYL N BENZYL 2 PHENYLACETAMIDE; N CYCLOHEX 1 ENYL N BENZYLACETAMIDE; N CYCLOHEX 1 ENYL N BENZYLDICHLOROACETAMIDE; N CYCLOHEX 1 ENYL N BENZYLPROP 2 ENAMIDE; N CYCLOHEX 1 ENYL N BENZYLPROPIONAMIDE; N CYCLOHEX 1 ENYL N BENZYLTRICHLOROACETAMIDE; TOLUENE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL STRUCTURE; CHIRALITY; CYCLIZATION; MOLECULAR DYNAMICS; PROTON NUCLEAR MAGNETIC RESONANCE; TEMPERATURE;

EID: 79957829082     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo200343z     Document Type: Article

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