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note
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4bpta (16.5 mg,0.05 mmol) under stirring. The green suspension was then sealed in a 25 mL Teflon-lined stainless steel vessel and heated to 140 °C for 2 days. Upon cooling to room temperature, octahedron green crystals were obtained (ca. 40 mg, 50% yield based on Ni). Crystals of 1 were collected, washed with methanol, and dried in air. Anal. found: C, 42.24; H, 4.97; N, 8.66%.
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4bpta (16.5 mg,0.05 mmol) was mixed in 14 mL DMF in a vial. The vial was sealed and allowed to stand at 100 °C for 24 h. As the reaction progresses, light yellow rod shape crystal formed. Homogeneous crystals of 2 were collected, washed with DMF, and dried in air (yield: 35 mg). Anal. found: C, 50.83; H, 4.19; N, 13.52%.
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note
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2=0.3211 (all data), GOF=1.061, Flack parameter= 0.15(11). CCDC No.: 779829.
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