Hydrogen isotope effects on the structural phase transition of NH 3BH3

International Journal of Hydrogen Energy

Volumn 36, Issue 13, 2011, Pages 7927-7931

  Palumbo, Oriele ^a,b   Paolone, Annalisa ^a,b   Rispoli, Pasquale ^a   Cantelli, Rosario ^a   Autrey, Tom ^c   Karkamkar, Abhijeet ^c   Navarra, Maria Assunta ^a  

^a SAPIENZA UNIVERSITY OF ROME   (Italy)

^b ISC CNR   (Italy)

^c PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

Author keywords

Complex hydrides; Hydrogen storage; Phase transition

Indexed keywords

ANELASTIC SPECTROSCOPY; COEXISTENCE REGION; COMPLEX HYDRIDES; DEUTERATED ANALOGUE; FIRST-ORDER; HIGH TEMPERATURE; HIGHER TEMPERATURES; HYDROGEN ISOTOPE; ISOTHERMAL AGEING; LOW TEMPERATURES; ORTHORHOMBIC PHASE; STRUCTURAL PHASE TRANSITION; SYSTEMATIC STUDY; TEMPERATURE HYSTERESIS; TIME CONSTANTS;

DEUTERIUM; HYDROGEN; HYDROGEN STORAGE; HYSTERESIS;

PHASE TRANSITIONS;

EID: 79957593607     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.12.076     Document Type: Article

References (25)

1. T.B. Marder Will we soon be fueling our automobiles with ammonia-borane? Angew Chem. Int Ed 46 2007 8116 8118 (Pubitemid 350096581)
2. B. Peng, and J. Chen Ammonia borane as an efficient and lightweight hydrogen storage medium Energy Environ Sci 1 2008 479 483
3. G. Wolf, J. Baumann, F. Baitalowa, and P. Hoffmann Calorimetric process monitoring of thermal decomposition of B-N-H compounds Thermochim Acta 343 2000 19 25
4. 11B MAS-NMR studies of the thermal decomposition of ammonia borane: mechanistic studies of the hydrogen release pathways from a solid state hydrogen storage material Phys Chem Chem Phys 15 2007 1831
5. D.J. Heldebrant, A. Karkamkar, N.J. Hess, M. Bowden, S. Rassat, and F. Zheng The effects of chemical additives on the induction phase in solid-state thermal decomposition of ammonia borane Chem Mater 20 2008 5332 5336
6. 3 J Chem Phys 79 1983 2932 2940
7. 3 by neutron diffraction J Am Chem Soc 121 1999 6337 6343 (Pubitemid 29334612)
8. 3 molecular crystal, J. Phys. Chem. B 107 (2003) 9231
9. 3 at 295 K and 110 K J Phys C 16 1983 6129 6136
10. M.E. Bowden, G.J. Gainsford, and W.T. Robinson Room-temperature structure of ammonia borane Aust J Chem 60 2007 149 153 (Pubitemid 46524295)
11. 3 Inorg Chem 38 1999 2868 2873
12. 3): mixed order-disorder and displacive behavior J Phys Chem B 111 2007 677 681
13. 3 as a function of temperature from 88 to 330 K J Chem Phys 128 2008 034508
14. J.B. Yang, J. Lamsal, Q. Cai, W.J. James, and W.B. Yelon The structural evolution of ammonia borane for hydrogen storage Appl Phys Lett 92 2008 091916
15. A. Paolone, O. Palumbo, P. Rispoli, R. Cantelli, and T. Autrey Hydrogen dynamics and characterization of the tetragonal-to-orthorhombic phase transformation in ammonia borane J Phys Chem C 113 2009 5872 5878
16. V.M. Parvanov, G.K. Schenter, N.J. Hess, L.L. Daemen, M. Hartl, and A.C. Stowe Materials for hydrogen storage: structure and dynamics of borane ammonia complex Dalton Trans 33 2008 4514 4522
17. O. Palumbo, R. Cantelli, A. Paolone, C.M. Jensen, and S.S. Srinivasan Hydrogen dynamics and evolution of chemical reactions in alanates by anelastic spectroscopy J Phys Chem B 109 2005 1168 1173 (Pubitemid 40211040)
18. A.S. Nowick, and B.S. Berry Anelastic relaxation in crystalline solids 1972 Academic Press New York
19. -1 2001 with applications to materials science 2002 Trans Tech Publ.
20. 4 J Phys Cond Mat 15 2003 457 465
21. A. Paolone, O. Palumbo, P. Rispoli, R. Cantelli, T. Autrey, and A. Karkamkar Absence of the structural phase transition in ammonia borane dispersed in mesoporous silica: evidence of novel thermodynamic properties J Phys Chem C 113 2009 10319 10321
22. O. Palumbo, R. Cantelli, A. Paolone, C.M. Jensen, and M. Sulic Fast H-vacancy dynamics during alanate decomposition by anelastic spectroscopy: model for Ti-induced defect transport J Phys Chem B 110 2006 9105 9111 (Pubitemid 43832838)
23. O. Palumbo, R. Cantelli, A. Paolone, C.M. Jensen, and S.S. Srinivasan Motion of point defects and monitoring of chemical reactions in sodium aluminium hydride J All Compds 404-406 2005 748 751 (Pubitemid 41688706)
24. O. Palumbo, A. Paolone, R. Cantelli, and D. Chandra Lithium nitride as hydrogen storage material Int J Hydr En 33 2008 3107 3110
25. 3) in the temperature range from 10 to 289 K Thermochim Acta 317 1998 111 116 (Pubitemid 128351308)