메뉴 건너뛰기




Volumn 7, Issue 10, 2011, Pages 1440-1447

Probing the collapse dynamics of poly(N-isopropylacrylamide) brushes by AFM: Effects of Co-nonsolvency and grafting densities

Author keywords

atomic force microscopy; collapse dynamics; grafting density; polymer brushes; solvent effects

Indexed keywords

AFM; COLLAPSE DYNAMICS; COLLOIDAL PROBES; DIFFERENT SOLVENTS; GRAFTING DENSITIES; HIGH-DENSITY POLYMER BRUSHES; IN-SITU; MIXED-SOLVENT SYSTEMS; N-ISOPROPYLACRYLAMIDES; POLY(N-ISOPROPYL ACRYLAMIDE) (PNIPAM); POLYMER BRUSHES; PULL-OFF FORCES; RESPONSE KINETICS; SOLVATION STATE; SOLVENT EFFECTS; SOLVENT EXCHANGES; SURFACE-INITIATED; TIME-SCALES; YOUNG'S MODULUS;

EID: 79956354316     PISSN: 16136810     EISSN: 16136829     Source Type: Journal    
DOI: 10.1002/smll.201002229     Document Type: Article
Times cited : (91)

References (64)
  • 6
  • 39
    • 0345979435 scopus 로고    scopus 로고
    • A. Ulman, Chem. Rev. 1996, 96, 1533-1554.
    • (1996) Chem. Rev. , vol.96 , pp. 1533-1554
    • Ulman, A.1
  • 43
    • 79956344107 scopus 로고    scopus 로고
    • A DIRECT MEASUREMENT OF GRAFTING DENSITY AND THE POLYMER CHAIN LENGTH IS RATHER DIFFICULT DUE TO THE VERY SMALL NUMBER OF POLYMER CHAINS AT SURFACES
    • A direct measurement of grafting density and the polymer chain length is rather difficult due to the very small number of polymer chains at surfaces.
  • 46
    • 77954545527 scopus 로고    scopus 로고
    • A. Halperin, Langmuir 2010, 26, 8933-8940.
    • (2010) Langmuir , vol.26 , pp. 8933-8940
    • Halperin, A.1
  • 49
    • 79956351916 scopus 로고    scopus 로고
    • WE NOTE THAT FOR DEFORMABLE MATERIALS THE ZERO DISTANCE BECOMES A MATTER OF DEFINITION. [35] THERE IS AN ERROR OF A FEW NANOMETERS DUE TO THE DETERMINATION OF THE POINT OF CONTACT, WHICH IS SHOWN IN FIGURE 3A-C
    • We note that for deformable materials the "zero distance" becomes a matter of definition. [35] There is an error of a few nanometers due to the determination of the point of contact, which is shown in Figure 3a-c.
  • 50
    • 79956352098 scopus 로고    scopus 로고
    • IT SHOULD BE NOTED THAT THE OBTAINED YOUNGS MODULUS VALUE HERE IS THE APPARENT YOUNGS MODULUS, AS THE EFFECT OF THE SOLID SUPPORT CANNOT BE NEGLECTED, EVEN THOUGH ONLY A SMALL AMOUNT OF DEFORMATION WAS PROBED
    • It should be noted that the obtained Young's modulus value here is the apparent Young's modulus, as the effect of the solid support cannot be neglected, even though only a small amount of deformation was probed.
  • 58
    • 79956344488 scopus 로고    scopus 로고
    • FOR THIS FILM, THE STRESS FIELD DOES NOT DECAY WITHIN THE BRUSH; THUS THERE IS A FINITE FORCE ACTING ON THE SUBSTRATE WHICH WILL INFLUENCE THE MODULUS MEASURED
    • For this film, the stress field does not decay within the brush; thus there is a finite force acting on the substrate which will influence the modulus measured.
  • 59
    • 79956368892 scopus 로고    scopus 로고
    • USE ADHERENCE TO DESCRIBE THE PRACTICAL WORK OF ADHESION TO EMPHASIZE DIFFERENCES BETWEEN ITS VALUE AND THE MAGNITUDE OF THERMODYNAMIC ADHESION. THE LATTER, IF EXPRESSED IN WORK OF ADHESION, CORRESPONDS TO THE REVERSIBLE FREE ENERGY CHANGE PER UNIT SURFACE AREA WHEN TWO CONTACTING SURFACES ARE MOVED APART FROM CONTACT TO INFINITE DISTANCE OF SEPARATION. THUS, ADHERENCE ALSO INCLUDES THE ENERGY DISSIPATED DURING SEPARATION OF THE CONTACTING SURFACES FROM EACH OTHER Here we
    • Here we use "adherence" to describe the practical work of adhesion to emphasize differences between its value and the magnitude of thermodynamic adhesion. The latter, if expressed in work of adhesion, corresponds to the reversible free energy change per unit surface area when two contacting surfaces are moved apart from contact to infinite distance of separation. Thus, adherence also includes the energy dissipated during separation of the contacting surfaces from each other.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.