Reaction mechanisms and structural characterization of the reactive intermediates observed after the photolysis of 3-(hydroxymethyl)benzophenone in acetonitrile, 2-propanol, and neutral and acidic aqueous solutions

Journal of Organic Chemistry

Volumn 76, Issue 10, 2011, Pages 3710-3719

  Ma, Jiani ^a   Li, Ming De ^a   Phillips, David Lee ^a   Wan, Peter ^b  

^a UNIVERSITY OF HONG KONG   (Hong Kong)

^b UNIVERSITY OF VICTORIA   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

2-PROPANOL; ACIDIC AQUEOUS SOLUTION; AQUEOUS SOLUTIONS; CROSS COUPLING REACTIONS; DENSITY FUNCTIONAL THEORY CALCULATIONS; EXPERIMENTAL SPECTRA; HYDROGEN ABSTRACTION REACTION; HYDROGEN ATOMS; KETYL RADICALS; NEUTRAL PH; PHOTOINDUCED REACTION; PHOTOREDOX REACTIONS; PHOTOREDUCTION REACTION; PREDOMINANT REACTIONS; REACTION MECHANISM; REACTIVE INTERMEDIATE; SOLVENT MOLECULES; STRUCTURAL CHARACTERIZATION; TIME RESOLVED RESONANCE; TIME-SCALES; TRANSIENT SPECIES; TRIPLET STATE;

ABSTRACTING; ACETONITRILE; CHEMICAL BONDS; DENSITY FUNCTIONAL THEORY; FREE RADICAL REACTIONS; HYDROGEN; METHANOL; PHOTOLYSIS; PROPANOL; SOLUTIONS;

REACTION INTERMEDIATES;

2 [4 [HYDROXY[3 (HYDROXYMETHYL)PHENYL]METHYLENE]CYCLOHEXA 2,5 DIENYL]PROPAN 2 OL; 2 PROPANOL; 3 (HYDROXYMETHYL)BENZOPHENONE; ACETONITRILE; BENZOPHENONE DERIVATIVE; CYCLOPROPANE DERIVATIVE; HYDROGEN; SOLVENT; UNCLASSIFIED DRUG; WATER;

ACIDITY; AQUEOUS SOLUTION; ARTICLE; CROSS COUPLING REACTION; DENSITY FUNCTIONAL THEORY; PH; PHOTOCHEMISTRY; PHOTOLYSIS; RAMAN SPECTROMETRY; REACTION ANALYSIS;

EID: 79956135687     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo1024249     Document Type: Article

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