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Volumn 353, Issue 7, 2011, Pages 1087-1095

Charge-transfer interactions: An efficient tool for recycling bis(oxazoline)-copper complexes in asymmetric henry reactions

Author keywords

asymmetric catalysis; bis(oxazolines); catalyst recycling; charge transfer complex; nitroaldol reaction

Indexed keywords


EID: 79955911271     PISSN: 16154150     EISSN: 16154169     Source Type: Journal    
DOI: 10.1002/adsc.201000934     Document Type: Article
Times cited : (35)

References (50)
  • 5
  • 43
    • 79955913036 scopus 로고    scopus 로고
    • As far as we know, this report is the first procedure for the synthesis of these two isomers in their enantioenriched form.
    • See Supporting Information for details of configuration assignment. As far as we know, this report is the first procedure for the synthesis of these two isomers in their enantioenriched form.
  • 45
    • 79955922348 scopus 로고    scopus 로고
    • We assume that this temporary interruption of catalytic activity is related to the low reactivity of nitroethane compared to nitromethane as can be observed from the results described in Table2. Furthermore, an important loss of activity between the two first runs of the recycling procedure was already detected in Table1. Here run 2 was performed for only 24h, a probably not long enough period to detect quantifiable amounts of expected compound 7f.
    • [21] We assume that this temporary interruption of catalytic activity is related to the low reactivity of nitroethane compared to nitromethane as can be observed from the results described in Table2. Furthermore, an important loss of activity between the two first runs of the recycling procedure was already detected in Table1. Here run 2 was performed for only 24h, a probably not long enough period to detect quantifiable amounts of expected compound 7f.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.