Diverse Cd(II) coordination polymers with a multidentate N-donor ligand 3,5-bis(4-pyridyl)-4-(3-pyridyl)-1,2,4-triazole and pseudohalide anions

Inorganic Chemistry Communications

Volumn 14, Issue 6, 2011, Pages 873-876

  Sun, Yan ^a   Guo, Wei ^a   Du, Miao ^a  

^a TIANJIN NORMAL UNIVERSITY   (China)

Author keywords

Cd(II) coordination polymers; Crystal structures; Fluorescence; Pseudohalide anions; Tripyridyltriazole

Indexed keywords

EID: 79955864992     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.03.015     Document Type: Article

References (25)

1. (a) W.-T. Liu, Y.-C. Ou, Y.-L. Xie, Z. Lin, M.-L. Tong, Photoluminescent metalorganic nanotubes via hydrothermal in situ ligand reactions, Eur. J. Inorg. Chem. (2009) 4213-4218;
2. (b) C. Janiak, J.K. Vieth, MOFs, MILs andmore: concepts, properties and applications for porous coordination networks (PCNs), New J. Chem. 34 (2010) 2366-2388.
3. (a) J. Seo, R. Matsuda, H. Sakamoto, C. Bonneau, S. Kitagawa, A pillared-layer coordination polymer with a rotatable pillar acting as a molecular gate for guest molecules, J. Am. Chem. Soc. 131 (2009) 12792-12800;
4. (b) H.-X. Yang, S.-P. Guo, J. Tao, J.-X. Lin, R. Cao, Hydrothermal syntheses, crystal structures, and magnetic properties of a series of complexes constructed from multinuclear copper clusters and polyoxometalates, Cryst. Growth Des. 9 (2009) 4735-4744.
5. (a) R.-Q. Zou, H. Sakurai, Q. Xu, Preparation, adsorption properties, and catalytic activity of 3D porous metal-organic frameworks composed of cubic building blocks and alkali-metal ions, Angew. Chem. Int. Ed. 45 (2006) 2542-2546;
6. (b) M. Khanpour, A. Morsali, Solid state crystal-to-crystal transformation from a monomeric structure to 1-D coordination polymers on anion exchange, CrystEngComm 11 (2009) 2585-2587.
7. (a) R. Cao, J. Lü, S.R. Batten, Copper 5-sulfoisophthalato quasi-planar squares in coordination polymers modulated by alkaline-earth metals: a way to molecular squares, CrystEngComm 10 (2008) 784-789;
8. 4MDIP), CrystEngComm 10 (2008) 207-216.
9. (a) Z.-X. Li, Y. Xu, Y. Zuo, L. Li, Q. Pan, T.-L. Hu, X.-H. Bu, Varying ligand backbones for modulating the interpenetration of coordination polymers based on homoleptic cobalt(II) nodes, Cryst. Growth Des. 9 (2009) 3904-3909;
10. (b) J.-C. Jin, Y.-Y. Wang, P. Liu, R.-T. Liu, C. Ren, Q.-Z. Shi, An unusual independent 1D metal-organic nanotube with mesohelical structure and 1D → 2D interdigitation, Cryst. Growth Des. 10 (2010) 2029-2032.
11. 4·DMF, Chem. Commun. (2005) 987-989;
12. 4 core, and Cd(II) mixed-ligand metal-organic frameworks constructed from 1,2-bis(1,2,4-triazol-4- yl)ethane and benzene-1,3,5-tricarboxylate, Inorg. Chim. Acta 362 (2009) 2452-2460.
13. 3tma/Bpt mixed-ligand system, Inorg. Chem. 45 (2006) 3998-4006;
14. (b) M. Du, X.-J. Jiang, X.-J. Zhao, Molecular tectonics of mixed-ligand metal-organic frameworks: positional isomeric effect, metal-directed assembly, and structural diversification, Inorg. Chem. 46 (2007) 3984-3995;
15. 2, and -COOH) as modular building blocks for mixed-ligand coordination polymers incorporated with a versatile connector 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole, CrystEngComm 10 (2008) 306-321.
16. (a) W. Guo, Y.-Y. Yang, M. Du, Anion-directed assembly of two fluorescent Cd(II) coordination polymers with a versatile multidentate N-donor building block 3-(2-pyridyl)-4,5-bis(4-pyridyl)-1,2,4-triazole, Inorg. Chem. Commun. 13 (2010) 863-866;
17. (b) Y.-Y. Yang, W. Guo, M. Du, Solvent-controlled assemblies, structures, and properties of two Hg(II) coordination polymers with a multidentate N-donor tecton 3,4-bis(2-pyridyl)-5-(4-pyridyl)-1,2,4-triazole, Inorg. Chem. Commun. 13 (2010) 1195-1198.
18. (a) M.B. Duriska, S.M. Neville, S.R. Batten, Variable length ligands: a new class of bridging ligands for supramolecular chemistry and crystal engineering, Chem. Commun. (2009) 5579-5581;
19. 3-Ni results in ferromagnetic behavior, Inorg. Chem. 48 (2009) 7174-7180;
20. (c) Y.-F. Zeng, X. Hu, F.-C. Liu, X.-H. Bu, Azido-mediated systems showing different magnetic behaviors, Chem. Soc. Rev. 38 (2009) 469-480.
21. M.H. Klingele, S. Brooker, From N-substituted thioamides to symmetrical and unsymmetrical 3,4,5-trisubstituted 4 H-1,2,4-triazoles: synthesis and characterisation of new chelating ligands, Eur. J. Org. Chem. (2004) 3422-3434.
22. -1): 2061s, 1609 m, 1524w, 1473m, 1433m, 1335w, 1218w, 1065w, 1007w, 830m, 704m, 627w, 535w.
23. 2=0.0450.
24. H. Zhang, X.-M. Wang, K.-C. Zhang, B.K. Teo, Molecular and crystal engineering of a new class of inorganic cadmium-thiocyanate polymers with host-guest complexes as organic spacers, controllers, and templates, Coord. Chem. Rev. 183 (1999) 157-195.
25. M.D. Allendorf, C.A. Bauer, R.K. Bhakta, R.J.T. Houk, Luminescent metal-organic frameworks, Chem. Soc. Rev. 38 (2009) 1330-1352.