Non-noble metal composite cathodes for hydrogen evolution. Part I: The Ni-MoOx coatings electrodeposited from Watt's type bath containing MoO3 powder particles

International Journal of Hydrogen Energy

Volumn 36, Issue 11, 2011, Pages 6441-6449

  Krstajic N V ^a   Gajic Krstajic Lj ^b   Lacnjevac U ^c   Jovic B M ^c   Mora, S ^d   Jovic V D ^c  

^a UNIVERSITY OF BELGRADE   (Serbia)

^b INSTITUTE OF TECHNICAL SCIENCES   (Serbia)

^c UNIVERSITY OF BELGRADE   (Serbia)

^d Industrie de Nora SpA   (Italy)

Author keywords

H2 evolution; Morphology; Ni MoOx coating; Phase composition

Indexed keywords

ALKALINE SOLUTIONS; CODEPOSITION; CROSS SECTION; DEPOSITION CONDITIONS; H2 EVOLUTION; HYDROGEN EVOLUTION; HYDROGEN EVOLUTION REACTIONS; MOLYBDATE IONS; MOLYBDENUM SPECIES; NI-MOOX COATING; NOBLE METALS; PHASE DEPOSITION; POLARIZATION CHARACTERISTICS; POWDER PARTICLES; REACTION MECHANISM; SEM; XRD ANALYSIS; XRD TECHNIQUE; INDUCED CO DEPOSITIONS;

CATHODES; DISSOLUTION; ELECTROCATALYSTS; HYDROGEN; MOLYBDENUM; MORPHOLOGY; NICKEL DEPOSITS; PHASE COMPOSITION; POLARIZATION; POWDER METALS; PRECIOUS METALS; DEPOSITION; NICKEL; POWDER COATINGS;

COATINGS; MOLYBDENUM OXIDE;

EID: 79955690824     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.02.105     Document Type: Article

References (42)

1. J.S. Sconce Chlorine, its manufacture, properties and uses 1962 Reinhold Publishing Corporation, Chapman & Hall, Ltd. New York, London
2. S. Trasatti Electrocatalysis of hydrogen evolution: Progress in cathode activation H. Gerischer, C.W. Tobias, Advances in electrochemical science and engineering 1992 Wiley-VCH Verlag GmbH Weinheim 2 85
3. R. Parsons The rate of electrolytic hydrogen evolution and the heat of adsorption of hydrogen Trans Farady Soc 54 1958 1053 1063
4. M.H. Miles Evaluation of electrocatalysts for water electrolysis in alkaline solutions J Electroanal Chem 60 1975 89 96
5. E. Beltowska-Lehman Kinetic correlations in codeposition of coatings of molybdenum-iron group metal alloys J Appl Electrochem 20 1990 132 139
6. D.E. Brown, M.N. Mahmood, A.K. Turner, S.M. Hall, and P.O. Fogarty Low overvoltage electrocatalysts for hydrogen evolving electrodes Int J Hydrogen Energy 7 1982 405 410 (Pubitemid 12554495)
7. J.H. Huot, and L. Brossard In situ activation of cobalt cathodes in alkaline water electrolysis J Appl Electrochem 18 1988 815 822
8. 2 evolution reactions and the characterization of participating adsorbed intermediates Int J Hydrogen Energy 12 1987 607 621
9. I.A. Raj, and K.I. Vasu Transition metal-based cathodes for hydrogen evolution in alkaline solution: electrocatalysis on nickel-based ternary electrolytic codeposits J Appl Electrochem 22 1992 471 477
10. 2-evolving, Ni-based cathodes J Electroanal Chem 161 1984 39 49 (Pubitemid 14530563)
11. C. Fan, D.L. Piron, and P. Paradis Hydrogen evolution on electrodeposited nickel-cobalt-molybdenum in alkaline water electrolysis Electrochim Acta 39 1994 2715 2722
12. 2 evolution electrocatalysis at porous Ni-Fe composite electrodes J Chem Soc Farady Trans I 81 1985 1841 1862
13. I.A. Raj, and V.K. Venkatesan Characterization of nickel-molybdenum and nickel-molybdenum-iron alloy coatings as cathodes for alkaline water electrolysers Int J Hydrogen Energy 13 1988 215 223 (Pubitemid 18623395)
14. C. Fan, D.L. Piron, A. Sleb, and P. Paradis Study of electrodeposited nickel-molybdenum, nickel-tungsten, cobalt-molybdenum, and cobalt-tungsten as hydrogen electrodes in alkaline water electrolysis J Electrochem Soc 141 1994 382 391
15. J. Divisek, H. Schmitz, and J. Balej Ni and Mo coatings as hydrogen cathodes J Appl Electrochem 19 1989 519 530
16. A. Lasia, and A. Rami Kinetics of hydrogen evolution on nickel electrodes J Electroanal Chem 294 1990 123 141
17. J.M. Jakšić, M.V. Vojnović, and N.V. Krstajić Kinetic analysis of hydrogen evolution at Ni-Mo alloy electrodes Electrochim Acta 45 2000 4151 4158 (Pubitemid 32092657)
18. M.R. Gennero de Chialvo, and A.C. Chialvo Hydrogen evolution reaction on smooth Ni(1-x) + Mo(x) alloys (0 ≤ x ≤ 0.25) J Electroanal Chem 448 1998 87 93 (Pubitemid 128411172)
19. M.M. Jakšić Brewer intermetallic phases as synergetic electrocatalysts for hydrogen evolution Mat Chem Phys 22 1989 1 26
20. E.J. Podlaha, and D. Landolt Induced codeposition I. An experimental investigation of Ni-Mo alloys J Electrochem Soc 143 1996 885 892 (Pubitemid 126597398)
21. E.J. Podlaha, and D. Landolt Induced codeposition II. A Mathematical model describing the electrodeposition of Ni-Mo alloys J Electrochem Soc 143 1996 893 899 (Pubitemid 126597399)
22. E. Chassaing, N. Portail, A.-F. Levy, and G. Wang Characterization of electrodeposited nanocrystalline Ni-Mo alloys J Appl Electrochem 34 2004 1085 1091 (Pubitemid 40003509)
23. M. Donten, H. Cesiulis, and Z. Stojek Electrodeposition of amorphous/nanocrystalline and polycrystalline Ni-Mo alloys from pyrophosphate baths Electrochim Acta 50 2005 1405 1412
24. M. Donten, H. Cesiulis, and Z. Stojek Electrodeposition and properties of Ni-W, Fe-W and Fe-Ni-W amorphous alloys. A comparative study Electrochim Acta 45 2000 3389 3396
25. H. Cesiulis, A. Baltutiene, M. Donten, M.L. Donten, and Z. Stojek Increase in rate of electrodeposition and in Ni(II) concentration in the bath as a way to control grain size of amorphous/nanocrystalline Ni-W alloys J Solid State Electrochem 6 2002 237 244 (Pubitemid 36160404)
26. L.S. Sanches, S.H. Domingues, A. Carubelli, and L.H. Mascaro Electrodeposition of Ni-Mo and Fe-Mo alloys from sulfate-citrate acid solutions J Braz Chem Soc 14 2003 556 563 (Pubitemid 37158116)
27. L.S. Sanches, S.H. Domingues, C.E.B. Marino, and L.H. Mascaro Characterisation of electrochemically deposited Ni-Mo alloy coatings Electrochem Commun 6 2004 543 548
28. V.D. Jović, B.M. Jović, G.R. Stafford, N.V. Krstajić, and Z. Twardowski Composition and morphology changes and their influence on hydrogen evolution on Ni-Mo and Fe-Mo alloys electrodeposited by dc and pulsed current 2002 SURFIN Chicago 76-84
29. U. Lačnjevac, B.M. Jović, Z. Bašč arević, V.M. Maksimović, and V.D. Jović Morphology and phase composition of as-deposited and recrystallized Ni-Mo-O powders Electrochim Acta 54 2009 3115 3123
30. V.D. Jović, B.M. Jović, U. Lačnjevac, G. Branković, S. Bernik, and A. Rečnik An attempt to predict the mechanism of Mo-Ni-O powders electrodeposition from the results of their TEM analysis Electrochim Acta 55 2010 4188 4193
31. A.L. Antozzi, C. Bargioni, L. Iacopetti, M. Musiani, and L. Vasquez-Gomez EIS study of the service life of activated cathodes for the hydrogen evolution reaction in the chlor-alkali membrane cell process Electrochim Acta 53 2008 7410 7416
32. Z.M. Hanafe, M.A. Khilla, and M.H. Askae The thermal decomposition of ammonium heptamolybdate Thermochim Acta 45 1981 221 232
33. G. Kreysa, B. Hokansson, and P. Egdunge Kinetic and thermodynamic analysis of hydrogen evolution at nickel electrodes Electrochim Acta 33 1988 1351 1357
34. N. Krstajić, M. Popović, B. Grgur, M. Vojnović, and D. Šepa On the kinetics of the hydrogen evolution reaction on nickel in alkaline solution. Part I. The mechanism J Electroanal Chem 512 2001 16 26 (Pubitemid 32903645)
35. Handbook of chemistry and physics 57th ed. 1976-1977 CRC Press Inc Cleveland p. B133
36. C.H. Huang Effect of imides on nickel-tungsten alloy electroforming J Mater Sci 34 1999 1373 1377
37. C.H. Huang Study of the effects of diammonium citrate on electroformed nickel-tungsten alloy Plat Surf Finish 84 1997 62 65
38. C.H. Huang, W.Y. She, and H.M. Wu Study of stress reducers in nickel-tungsten electroforming bath Plat Surf Finish 86 1999 79 83 (Pubitemid 129570058)
39. J. Kubisztal, A. Budniok, and A. Lasia Study of the hydrogen evolution reaction on nickel-based composite coatings containing molybdenum powder Int J Hydrogen Energy 32 2007 1211 1218 (Pubitemid 46777201)
40. 2-cathodes. Part II: correlation of morphology and effective catalytic activity of Raney-nickel coated cathodes J Appl Electrochem 22 1992 1031 1038 (Pubitemid 23588478)
41. G. Sheela, M. Pushapavanam, and S. Pusphavanam Zinc-nickel alloy electrodeposits for water electrolysis Int J Hydrogen Energy 27 2002 627 633 (Pubitemid 34247714)
42. M. Jayalakshmi1, I. Puspitasari, K.-D. Jung, and O.-S. Joo Effect of different substrates on the electrochemical behavior of Ni-Mo-Fe-Co-S composite film in alkali solution Int J Electrochem Sci 3 2008 787 796