The first example for the asymmetric synthesis of allenes by the Doering-LaFlamme allene synthesis with enantiopure cyclopropylmagnesium carbenoids

Tetrahedron Letters

Volumn 52, Issue 23, 2011, Pages 3016-3019

  Momochi, Hitoshi ^a   Noguchi, Takafumi ^a   Miyagawa, Toshifumi ^a   Ogawa, Naoki ^a   Tadokoro, Makoto ^a   Satoh, Tsuyoshi ^a  

^a TOKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

Asymmetric synthesis; Cyclopropylmagnesium carbenoid; Doering LaFlamme allene synthesis; Magnesium carbenoid; Optically active allene

Indexed keywords

1 CHLOROCYCLOPROPYL 4 TOLYL SULFOXIDE; ALCOHOL DERIVATIVE; ALLENE DERIVATIVE; CARBENOID; CARBONYL DERIVATIVE; CYCLOPROPYLMAGNESIUM CARBENOID; DICHLOROMETHYL 4 TOLYL SULFOXIDE; GRIGNARD REAGENT; LITHIUM; SULFUR; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC SYNTHESIS; CHEMICAL ANALYSIS; CHEMICAL MODIFICATION; CHEMICAL REACTION; CHIRALITY; DIASTEREOISOMER; DOERING LAFLAMME REARRANGEMENT; ENANTIOSELECTIVITY; GRIGNARD REACTION; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; LOW TEMPERATURE; PROTON NUCLEAR MAGNETIC RESONANCE; ROOM TEMPERATURE; STEREOCHEMISTRY; X RAY ANALYSIS;

EID: 79955656929     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2011.03.150     Document Type: Article

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