Friedel-Crafts reactions of 2,2-difluorocyclopropanecarbonyl chloride: Unexpected ring-opening chemistry

Journal of Organic Chemistry

Volumn 76, Issue 9, 2011, Pages 3450-3456

  Dolbier Jr , William R ^a   Cornett, Eric ^a   Martinez, Henry ^a   Xu, Wei ^a  

^a University of Florida ^*  (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACYLIUM; P-XYLENE; REACTIVE SUBSTRATES; RELATED SYSTEMS; RING OPENING; RING-OPENED PRODUCTS; SUBSTITUTED BENZENES;

AROMATIC HYDROCARBONS; BENZENE; CHEMICAL REACTIONS; CHLORINE COMPOUNDS; FRIEDEL-CRAFTS REACTION; KETONES; ORGANIC POLYMERS; THIOPHENE; TOLUENE; XYLENE;

SUBSTRATES;

(2,2 DIFLUOROCYCLOPROPYL)(4 METHOXYPHENYL)METHANONE; (2,2 DIFLUOROCYCLOPROPYL)(4 METHYLPHENYL)METHANONE; (2,2 DIFLUOROCYCLOPROPYL)(PHENYL)METHANONE; (2,2 DIFLUOROCYCLOPROPYL)(THIOPHEN 2 YL)METHANONE; 2,2 DIFLUOROCYCLOPROPANECARBONYL CHLORIDE; 4 CHLORO 1 (2,5 DIMETHYLPHENYL) 4,4 DIFLUOROBUTAN 1 ONE; 4 CHLORO 1 (4 ETHYLPHENYL) 4,4 DIFLUOROBUTAN 1 ONE; 4 CHLORO 1 (4 METHOXYPHENYL) 4,4 DIFLUOROBUTAN 1 ONE; 4 CHLORO 1 (4 METHYLPHENYL) 4,4 DIFLUOROBUTAN 1 ONE; 4 CHLORO 1 PHENYL 4,4 DIFLUOROBUTAN 1 ONE; 4 CHLORO 4,4 DIFLUORO 1 (THIOPHEN 2 YL)BUTAN 1 ONE; ANISOLE; BENZENE; CARBONYL DERIVATIVE; DICHLOROMETHANE; ETHYLBENZENE; PARA XYLENE; POLYCYCLIC AROMATIC HYDROCARBON; THIOPHENE; TOLUENE; UNCLASSIFIED DRUG;

ACYLATION; ARTICLE; FRIEDEL CRAFTS REACTION; REACTION ANALYSIS; RING OPENING; SYNTHESIS; THERMODYNAMICS;

EID: 79955563568     PISSN: 00223263     EISSN: 15206904     Source Type: Journal    
DOI: 10.1021/jo200423y     Document Type: Article

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