Activity function for describing alteration of three-way catalyst performance over palladium-only three-way catalysts by catalyst mileage

Industrial and Engineering Chemistry Research

Volumn 50, Issue 9, 2011, Pages 5499-5509

  Kang, Sung Bong ^a   Kwon, Hyuk Jae ^a   Nam, In Sik ^a   Song, Young Il ^b   Oh, Se H ^c  

^a Pohang University of Science and Technology (POSTECH)   (South Korea)

^b Hyundai Motor Co   (South Korea)

^c GENERAL MOTORS CORPORATION   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYTIC PERFORMANCE; METAL CONTENT; METAL LOADINGS; METALLIC SURFACE; OVERALL REACTIONS; SECOND ORDERS; SINTERING KINETICS; THREE WAY CATALYSTS;

PALLADIUM; RARE EARTH COMPOUNDS; REACTION KINETICS; SINTERING;

CATALYST ACTIVITY;

EID: 79955544534     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie200083f     Document Type: Article

References (35)

1. Moulijn, J. A.; Van Diepen, A. E.; Kapteijn, F. Catalyst deactivation: Is it predictable? What to do? Appl. Catal., A 2001, 212, 3-6
2. Nam, I.-S.; Froment, G. F. Catalyst deactivation by site coverage through multi-site reaction mechanisms J. Catal. 1987, 108, 271-282
3. 3 catalyst Appl. Catal., A 2007, 330, 49-56 (Pubitemid 47321101)
4. Flynn, P. C.; Wanke, S. E. Experimental studies of sintering of supported platinum catalysts J. Catal. 1975, 37, 432-448
5. Granados, M. L.; Larese, C.; Galisteo, F. C.; Mariscal, R.; Fierro, J. L. G.; Fernández-Ruíz, R.; Sanguino, R.; Luna, M. Effect of mileage on the deactivation of vehicle-aged three-way catalysts Catal. Today 2005, 107/108, 77-85
6. Gandhi, H. S.; Graham, G. W.; McCabe, R. W. Automotive exhaust catalysis J. Catal. 2003, 216, 433-442
7. Ekström, F.; Wallin, F.; Fathali, A.; Russ, G. Modeling of catalytic exhaust aftertreatment systems: From laboratory reactor data to successful prediction of emissions from vehicles Top. Catal. 2009, 52, 1915-1920
8. Baba, N.; Yokota, K.; Matsunaga, S.; Kojima, S.; Ohsawa, K.; Ito, T.; Domyo, H. Numerical simulation of deactivation process of three-way catalytic converters SAE Tech. Pap. 2000, 2000-01-0214
9. Boll, W.; Tischer, S.; Deutschmann, O. Loading and aging effects in exhaust gas after-treatment catalysts with Pt As active component Ind. Eng. Chem. Res. 2010, 49, 10303-10310
10. Hauff, K.; Tuttlies, U.; Eigenberger, G.; Nieken, U. A global description of DOC kinetics for catalysts with different platinum loadings and aging status Appl. Catal., B 2010, 100, 10-18
11. Koltsakis, G. C.; Stamatelos, A. M. Catalytic automotive exhaust aftertreatment Prog. Energy Combust. Sci. 1997, 23, 1-39 (Pubitemid 127418691)
12. 2 in the deterioration of its oxygen storage and release properties J. Catal. 2006, 239, 410-421
13. 6 oxidation Appl. Catal., B 2009, 92, 114-125
14. Liu, R.-J.; Crozier, P. A.; Smith, C. M.; Hucul, D. A.; Blackson, J.; Salaita, G. Metal sintering mechanisms and regeneration of palladium/alumina hydrogenation catalysts Appl. Catal., A 2005, 282, 111-121
15. Kašpar, J.; Fornasiero, P.; Hickey, N. Automotive catalytic converters: Current status and some perspectives Catal. Today 2003, 77, 419-449
16. Forzatti, P.; Lietti., L. Catalyst deactivation Catal. Today 1999, 52, 165-181 (Pubitemid 129587997)
17. Shelef, M.; McCabe, R. W. Twenty-five years after introduction of automotive catalysts: what next? Catal. Today 2000, 62, 35-50 (Pubitemid 32067468)
18. Shinjoh, H.; Muraki, H.; Fujitani, Y. Effect of severe thermal aging on noble metal catalysts Stud. Surf. Sci. Catal. 1991, 71, 617-628
19. 3 catalysts and their behavior in enantioselective hydrogenation J. Catal. 2004, 222, 307-314
20. González-Velasco, J. R.; Botas, J. A.; González-Marcos, J. A.; Gutiérrez-Ortiz, M. A. Influence of water and hydrogen processed in feedstream on the three-way behaviour of platinum-alumina catalysts Appl. Catal., B 1997, 12, 61-79 (Pubitemid 27201361)
21. 3 Catalysts J. Phys. Chem. B 1997, 101, 10769-10774 (Pubitemid 127585227)
22. 3 catalysts in the total oxidation of methane Catal. Today 2006, 112, 134-138 (Pubitemid 43238155)
23. Müller, C. A.; Maciejewski, M.; Koeppel, R. A.; Baiker, A. Combustion of methane over palladium/zirconia: Effect of Pd-particle size and role of lattice oxygen Catal. Today 1999, 47, 245-252 (Pubitemid 129603102)
24. 2(110) model catalysts: Particle size effects Top. Catal. 2007, 44, 3-13
25. Kwon, H. J.; Baik, J. H.; Kwon., Y. T.; Nam, I.-S.; Oh, S. H. Detailed reaction kinetics over commercial three-way catalysts Chem. Eng. Sci. 2007, 62, 5042-5047 (Pubitemid 47268417)
26. Baik, J. H.; Kwon, H. J.; Kwon, Y. T.; Nam, I.-S.; Oh, S. H. Effect of catalyst aging on the activity and selectivity of commercial three-way catalysts Top. Catal. 2007, 42/43, 337-340
27. Kwon, H. J.; Baik, J. H.; Kwon, Y. T.; Nam, I.-S.; Oh, S. H. Enhancement effect of water on oxidation reactions over commercial three-way catalyst Chem. Eng. J. 2008, 141, 194-203
28. Hahn, H. C.; Nowacki, P.; Fuess, H. Influence of ageing conditions on the performance and structure of commercial Three-way catalysts Top. Catal. 2009, 52, 2019-2024
29. Marquardt, D. W. An algorithm for least-squares estimation of nonlinear parameters J. Soc. Ind. Appl. Math. 1963, 11, 431-441
30. Wanke, S. E.; Flynn, P. C. The sintering of supported metal catalysts Catal. Rev. 1975, 12, 93-135
31. Hughes, T. R.; Houston, R. J.; Sieg, R. P. Flow adsorption method for catalyst metal surface measurements Ind. Eng. Chem. Process Des. Dev. 1962, 1, 96-102
32. González-Velasco, J. R.; Botas, J. A.; Ferret, R.; González-Marcos, M. P.; Marc, J.-L.; Gutiérrez-Ortiz, M. A. Thermal aging of Pd/Pt/Rh automotive catalysts under a cycle oxidizing-reducing environment Catal. Today 2000, 59, 395-402
33. Beeckman, J. W.; Froment, G. F. Catalyst deactivation by active site coverage and pore blockage Ind. Eng. Chem. Fundam. 1979, 18, 245-256
34. Flynn, P. C.; Wanke, S. E. Experimental studies of sintering of supported platinum catalysts J. Catal. 1975, 37, 432-448
35. 3 automotive catalysts Stud. Surf. Sci. Catal. 2001, 139, 157-164