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23
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84871141079
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The reason for the involvement of both the oxygen atoms of each of the carboxylate end of this ligand as well as the non-ligation of the nitrogen to bismuth is most likely due to the transfer of a carboxylic acid proton to the nitrogen rendering lone pair of electrons on the latter not available for donation. The cif file as deposited in the Cambridge database, gives only the coordinates of all the atoms and the final R values are not available
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The reason for the involvement of both the oxygen atoms of each of the carboxylate end of this ligand as well as the non-ligation of the nitrogen to bismuth is most likely due to the transfer of a carboxylic acid proton to the nitrogen rendering lone pair of electrons on the latter not available for donation. The cif file as deposited in the Cambridge database, gives only the coordinates of all the atoms and the final R values are not available.
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24
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79955513963
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We are also exploring the use of BiCl3 as the precursor, but the success has been rather limited
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We are also exploring the use of BiCl3 as the precursor, but the success has been rather limited: Srinivasa Rao A, Sunil Babu E, Kumara Swamy K C and Das S K 2010 Polyhedron 29 1706.
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Polyhedron
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Srinivasa, R.A.1
Sunil, B.E.2
Kumara, S.K.C.3
Das, S.K.4
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