Surfactants possessing multiple polar heads. A perspective on their unique aggregation behavior and applications

Journal of Physical Chemistry Letters

Volumn 2, Issue 8, 2011, Pages 914-920

  Bhattacharya, Santanu ^a   Samanta, Suman K ^a  

^a INDIAN INSTITUTE OF SCIENCE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

AGGREGATION BEHAVIOR; AGGREGATION NUMBERS; BIOLOGICAL APPLICATIONS; COUNTERION DISSOCIATION; CRITICAL MICELLAR CONCENTRATIONS; FRACTIONAL CHARGES; HEAD GROUPS; INTERFACIAL BEHAVIORS; POLAR HEAD; RECENT TRENDS; STRUCTURE ACTIVITY RELATIONSHIPS; SURFACTANT AGGREGATION;

SURFACE ACTIVE AGENTS;

EID: 79955497912     PISSN: None     EISSN: 19487185     Source Type: Journal    
DOI: 10.1021/jz2001634     Document Type: Review

References (38)

1. Chevalier, Y. New Surfactants: New Chemical Functions and Molecular Architectures Curr. Opin. Colloid Interface Sci. 2002, 7, 3-11 (Pubitemid 34605960)
2. Israelachvili, J. N. Physics of Amphiphiles: Micelles, Vesicles, and Microemulsions. Elsevier: Amsterdam, The Netherlands, 1985; p 24.
3. Menger, F. M.; Shi, L.; Rizvi, S. A. A. Self-Assembling Systems: Mining a Rich Vein J. Colloid Interface Sci. 2010, 344, 241-246
4. Rosen, M. J. Surfactants and Interfacial Phenomena, 3 rd ed.; Wiley: New York, 2004.
5. m Spacers: Pronounced m- Value Dependence of Thermal Properties, Vesicle Fusion, and Cholesterol Complexation Chem.-Eur. J. 1999, 5, 2335-2347 (Pubitemid 129502671)
6. Ewert, K. K.; Evans, H. M.; Zidovska, A.; Bouxsein, N. F.; Ahmad, A.; Safinya, C. R. A Columnar Phase of Dendritic Lipid-Based Cationic Liposome-DNA Complexes for Gene Delivery: Hexagonally Ordered Cylindrical Micelles Embedded in a DNA Honeycomb Lattice J. Am. Chem. Soc. 2006, 128, 3998-4006
7. Jayaprakash, K. N.; Lu, J.; Fraser-Reid, B. Synthesis of a Lipomannan Component of the Cell-Wall Complex of Mycobacterium tuberculosis Is Based on Paulsen's Concept of Donor/Acceptor "Match" Angew. Chem., Int. Ed. 2005, 44, 5894-5898 (Pubitemid 41316866)
8. Haldar, J.; Aswal, V. K.; Goyal, P. S.; Bhattacharya, S. Molecular Modulation of Surfactant Aggregation in Water: Effect of the Incorporation of Multiple head groups on Micellar Properties Angew. Chem., Int. Ed. 2001, 40, 1228-1232 (Pubitemid 32294368)
9. Haldar, J.; Aswal, V. K.; Goyal, P. S.; Bhattacharya, S. Role of Incorporation of Multiple head groups in Cationic Surfactants in Determining Micellar Properties. Small-Angle-Neutron-Scattering and Fluorescence Studies J. Phys. Chem. B 2001, 105, 12803-12808 (Pubitemid 35338278)
10. Haldar, J.; Aswal, V. K.; Goyal, P. S.; Bhattacharya, S. Aggregation Properties of Novel Cationic Surfactants with Multiple Pyridinium Headgroups. Small-Angle Neutron Scattering and Conductivity Studies J. Phys. Chem. B 2004, 108, 11406-11411
11. Willemen, H. M.; de Smet, L. C. P. M.; Koudijs, A.; Stuart, M. C. A.; Heikamp-de Jong, I. G. A. M.; Marcelis, A. T. M.; Sudholter, E. J. R. Micelle Formation and Antimicrobial Activity of Cholic Acid Derivatives with Three Permanent Ionic Head Groups Angew. Chem., Int. Ed. 2002, 41, 4275-4277 (Pubitemid 35398252)
12. Roszak, K. Z.; Torcivia, S. L.; Hamill, K. M.; Hill, A. R.; Radloff, K. R.; Crizer, D. M.; Middleton, A. M.; Caran, K. L. Biscationic Bicephalic (Double-Headed) Amphiphiles with an Aromatic Spacer and a Single Hydrophobic Tail J. Colloid Interface Sci. 2009, 331, 560-564
13. Skrzela, R.; Para, G.; Warszynski, P.; Wilk, K. A. Experimental and Theoretical Approach to Nonequivalent Adsorption of Novel Dicephalic Ammonium Surfactants at the Air/Solution Interface J. Phys. Chem. B 2010, 114, 10471-10480
14. Wang, W.; Lu, W.; Jiang, L. Influence of pH on the Aggregation Morphology of a Novel Surfactant with Single Hydrocarbon Chain and Multi-Amine Headgroups J. Phys. Chem. B 2008, 112, 1409-1413 (Pubitemid 351288206)
15. Gao, N.; Dong, J.; Zhang, G.; Zhou, X.; Eastoe, J.; Mutch, K. J.; Heenan, R. K. Surface and Micelle Properties of Novel Multi-dentate Surfactants J. Colloid Interface Sci. 2007, 314, 707-711 (Pubitemid 47285138)
16. De, S.; Aswal, V. K.; Goyal, P. S.; Bhattacharya, S. Role of Spacer Chain Length in Dimeric Micellar Organization. Small Angle Neutron Scattering and Fluorescence Studies J. Phys. Chem. 1996, 100, 11664-11671 (Pubitemid 126788585)
17. Zana, R.; Talmon, Y. Dependence of Aggregate Morphology on Structure of Dimeric Surfactants Nature 1993, 362, 228-230 (Pubitemid 23638737)
18. See, for instance: Menger, F. M.; Keiper, S. S. Gemini Surfactants Angew. Chem., Int. Ed. 2000, 39, 1907-1920
19. Bhattacharya, S.; De, S. Vesicle Formation from Dimeric Surfactants through Ion-Pairing. Adjustment of Polar Headgroup Separation Leads to Control over Vesicular Thermotropic Properties J. Chem. Soc., Chem. Commun. 1995, 651-652
20. Yan, X.; Han, S.; Hou, W.; Yu, X.; Zeng, C.; Zhao, X.; Che, H. Synthesis of Highly Ordered Mesoporous Silica using Cationic Trimeric Surfactant as Structure-Directing Agent Colloids Surf., A 2007, 303, 219-225 (Pubitemid 46818968)
21. Zana, R.; In, M.; Levy, H.; Duportail, G. Alkanediyl-α,ω- bis(dimethylalkylammonium bromide). 7. Fluorescence Probing Studies of Micelle Micropolarity and Microviscosity Langmuir 1997, 13, 5552-5557 (Pubitemid 127591949)
22. Wu, C; Hou, Y.; Deng, M.; Huang, X.; Yu, D.; Xiang, J.; Liu, Y.; Li, Z.; Wang, Y. Molecular Conformation-Controlled Vesicle/Micelle Transition of Cationic Trimeric Surfactants in Aqueous Solution Langmuir 2010, 26, 7922-7927
23. Wang, Y.; Han, Y.; Huang, X.; Cao, M.; Wang, Y. Aggregation Behavior of a Series of Anionic Sulfonate Gemini Surfactants and their Corresponding Monomeric Surfactant J. Colloid Interface Sci. 2008, 319, 534-541
24. Bhattacharya, S.; Haldar, J. Thermodynamics of Micellization of Multiheaded Single-Chain Cationic Surfactants Langmuir 2004, 20, 7940-7947
25. Bhattacharya, S.; Haldar, J. Microcalorimetric and Conductivity Studies with Micelles Prepared from Multi-Headed Pyridinium Surfactants Langmuir 2005, 21, 5747-5751 (Pubitemid 40925817)
26. Samanta, S. K.; Bhattacharya, S.; Maiti, P. K. Coarse-Grained Molecular Dynamics Simulation of the Aggregation Properties of Multiheaded Cationic Surfactants in Water J. Phys. Chem. B 2009, 113, 13545-13550
27. Haldar, J.; Aswal, V. K.; Goyal, P. S.; Bhattacharya, S. Unusual Micellar Properties of Multiheaded Cationic Surfactants in the Presence of Strong Charge Neutralizing Salts J. Colloid Interface Sci. 2005, 282, 156-161 (Pubitemid 39575242)
28. Haldar, J.; Kondaiah, P.; Bhattacharya, S. Synthesis and Antibacterial Properties of Novel Hydrolyzable Cationic Amphiphiles. Incorporation of Multiple Head Groups Leads to Impressive Antibacterial Activity J. Med. Chem. 2005, 48, 3823-3831 (Pubitemid 40776857)
29. Bhattacharya, S.; Bajaj, A. Advances in Gene Delivery through Molecular Design of Cationic Lipids Chem. Commun 2009, 4632-4656
30. Unciti-Broceta, A.; Holder, E.; Jones, L. J.; Stevenson, B.; Turner, A. R.; Porteous, D. J.; Boyd, A. C.; Bradley, M. Tripod-like Cationic Lipids as Novel Gene Carriers J. Med. Chem. 2008, 51, 4076-4084 (Pubitemid 352032435)
31. Farago, O.; Ewert, K.; Ahmad, A.; Evans, H. M.; Gronbech-Jensen, N.; Safinya, C. R. Transitions between Distinct Compaction Regimes in Complexes of Multivalent Cationic Lipids and DNA Biophys. J. 2008, 95, 836-846
32. Murguia, M. C.; Cristaldi, M. D.; Porto, A.; Conza, J. D.; Grau, R. J. Synthesis, Surface-Active Properties, and Antimicrobial Activities of New Neutral and Cationic Trimeric Surfactants J. Surfact. Deterg. 2008, 11, 41-48
33. Zhang, J. Z. Biomedical Applications of Shape-Controlled Plasmonic Nanostructures: A Case Study of Hollow Gold Nanospheres for Photothermal Ablation Therapy of Cancer J. Phys. Chem. Lett. 2010, 1, 686-695
34. Salzemann, C.; Zhai, W.; Goubet, N.; Pileni, M.-P. How to Tune the Au Internanocrystal Distance in Two-Dimensional Self-Ordered Superlattices J. Phys. Chem. Lett. 2010, 1, 149-154
35. Morris-Cohen, A. J.; Frederick, M. T.; Lilly, G. D.; McArthur, E. A.; Weiss, E. A. Organic Surfactant-Controlled Composition of the Surfaces of CdSe Quantum Dots J. Phys. Chem. Lett. 2010, 1, 1078-1081
36. Wang, Y.; DePrince, A. E.; Gray, S. K.; Lin, X.-M.; Pelton, M. Solvent-Mediated End-to-End Assembly of Gold Nanorods J. Phys. Chem. Lett. 2010, 1, 2692-2698
37. Bhattacharya, S.; De, S.; Subramanian, M. Synthesis and vesicle formation from hybrid bolaphile/amphiphile ion-pairs. Evidence of membrane property modulation by molecular design J. Org. Chem. 1998, 63, 7640-7651 (Pubitemid 128723011)
38. Murphy, C. J.; Thompson, L. B.; Alkilany, A. M.; Sisco, P. N.; Boulos, S. P.; Sivapalan, S. T.; Yang, J. A.; Chernak, D. J.; Huang, J. The Many Faces of Gold Nanorods J. Phys. Chem. Lett. 2010, 1, 2867-2875