Methanol oxidation on MoO3 promoted Pt/C electrocatalyst

International Journal of Hydrogen Energy

Volumn 36, Issue 10, 2011, Pages 5875-5884

  Justin, P ^a   Ranga Rao, G ^a  

^a INDIAN INSTITUTE OF TECHNOLOGY MADRAS   (India)

Author keywords

Direct methanol fuel cell; Electrocatalyst; Methanol oxidation; Molybdenum oxide

Indexed keywords

ACIDIC SOLUTIONS; C-V MEASUREMENT; ELECTROCONDUCTIVE; ELECTRODE RESPONSE; HYDROGEN MOLYBDENUM BRONZE; INTERMITTENT MICROWAVE HEATING; METHANOL ELECTROOXIDATION; METHANOL OXIDATION; MICROWAVE-ASSISTED POLYOL PROCESS; NONSTOICHIOMETRIC; OXIDE MATERIALS; PEAK CURRENTS; PHYSICO-CHEMICAL CHARACTERIZATION; PT NANOPARTICLES; STABILITY TESTS; VULCAN XC72; PT/C ELECTROCATALYSTS;

BRONZE; DIRECT METHANOL FUEL CELLS (DMFC); ELECTRIC CONDUCTIVITY; ELECTROCATALYSTS; ELECTROOXIDATION; HEATING; HYDROGEN; METHANOL; METHANOL FUELS; MICROWAVE HEATING; MOLYBDENUM; NANOPARTICLES; PLATINUM; CARBON; CARBON DIOXIDE; ELECTRODES; METAL NANOPARTICLES; SOLID STATE REACTIONS;

MOLYBDENUM OXIDE;

EID: 79955477784     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2011.01.122     Document Type: Article

References (50)

1. B.C.H. Steele, and A. Heinzel Materials for fuel-cell technologies Nature 414 2001 345 352 (Pubitemid 33097817)
2. M. Winter, and R.J. Brodd What are batteries, fuel cells, and supercapacitors? Chem Rev 104 2004 4245 4269
3. E. Antolini, J.R.C. Salgado, and E.R. Gonzalez The methanol oxidation reaction on platinum alloys with the first row transition metals: the case of Pt-Co and -Ni alloy electrocatalysts for DMFCs: a short review Appl Catal B Environ 63 2006 137 149 (Pubitemid 43247437)
4. S.K. Kamarudin, F. Achmad, and W.R.W. Daud Overview on the application of direct methanol fuel cell (DMFC) for portable electronic devices Int J Hydrogen Energy 34 2009 6902 6916
5. 2 electrodes prepared by thermal decomposition of polymeric precursors as catalysts for direct methanol fuel cell applications Int J Hydrogen Energy 34 2009 2747 2757
6. R. Basnayake, Z. Li, S. Katar, W. Zhou, H. Rivera, and E.S. Smotkin PtRu nanoparticle electrocatalyst with bulk alloy properties prepared through a sonochemical method Langmuir 22 2006 10446 10450 (Pubitemid 46051723)
7. K. Koczkur, Q. Yi, and A. Chen Nanoporous Pt-Ru networks and their electrocatalytical properties Adv Mater 19 2007 2648 2652 (Pubitemid 47481830)
8. D.R.M. Godoi, J. Perez, and H.M. Villullas Effects of alloyed and oxide phases on methanol oxidation of Pt-Ru/C nanocatalysts of the same particle size J Phys Chem C 113 2009 8518 8525
9. 12 electrocatalysts for methanol electro-oxidation Int J Hydrogen Energy 34 2009 2426 2434
10. M. Umeda, H. Ojima, M. Mohamedi, and I. Uchida Methanol electrooxidation at Pt-Ru-W sputter deposited on Au substrate J Power Sources 136 2004 10 15
11. S. Mukerjee, and R.C. Urian Bifunctionality in Pt alloy nanocluster electrocatalysts for enhanced methanol oxidation and CO tolerance in PEM fuel cells: electrochemical and in situ synchrotron spectroscopy Electrochim Acta 47 2002 3219 3231 (Pubitemid 34862818)
12. J.H. Choi, K.W. Park, I.S. Park, W.H. Nam, and Y.E. Sung Methanol electrooxidation and direct methanol fuel cell using Pt/Rh and Pt/Ru/Rh alloy catalysts Electrochim Acta 50 2004 787 790
13. J.T. Moore, D. Chu, R. Jiang, G.A. Deluga, and C.M. Lukehart Synthesis and characterization of Os and Pt-Os/Carbon nanocomposites and their relative performance as methanol electrooxidation catalysts Chem Mater 15 2003 1119 1124
14. Y.Q. Wang, Z.D. Wei, L. Li, M.B. Ji, Y. Xu, and P.K. Shen Methanol electrochemical oxidation on Au/Pt electrode enhanced by phosphomolybdic acid J Phys Chem C 112 2008 18672 18676
15. M. Watanabe, and S. Motoo Electrocatalysis by ad-atoms part II. Enhancement of the oxidation of methanol on platinum by ruthenium ad-atoms J Electroanal Chem 60 1975 267 273
16. T. Frelink, W. Visscher, and J.A.R. van Veen On the role of Ru and Sn as promotors of methanol electrooxidation over Pt Surf Sci 335 1995 353 360
17. 2/CNTs for methanol electro-oxidation J Power Sources 164 2007 555 560 (Pubitemid 46109219)
18. 5/C electrocatalysts for methanol electrooxidation in acidic media Appl Catal B Environ 100 2010 510 515
19. 5/C catalysts Catal Today 141 2009 138 143
20. 2O/Carbon nanotube catalysts for direct ethanol fuel cells Angew Chem Int Ed 45 2006 5315 5319 (Pubitemid 44289368)
21. 3 as methanol oxidation catalysts for fuel cells J Phys Chem C 109 2005 22958 22966 (Pubitemid 43010724)
22. Y. Wang, E.R. Fachini, G. Cruz, Y. Zhu, Y. Ishikawa, and J.A. Colucci Effect of surface composition of electrochemically codeposited platinum/molybdenum oxide on methanol oxidation J Electrochem Soc 148 2001 C222 C226
23. 2 nanocatalysts Chem Commun 46 2010 794 796
24. 2 nanowire-based electrodes Electrochem Solid-State Lett 10 2007 B130 B133
25. 2/CNT supported Pt and PtRu nanocatalysts for direct methanol fuel cells Langmuir 25 2009 7711 7717
26. x prepared by cyclic voltammetry with different scanning potential ranges J Appl Electrochem 39 2009 1053 1058
27. x-carbon nanotube redox couple based electrocatalyst as a potential partner with polybenzimidazole membrane for high temperature polymer electrolyte membrane fuel cell applications Electrochim Acta 55 2010 2878 2887
28. x/C J Electrochem Soc 152 2005 A1870 A1873
29. x nanoparticles: structural characteristics and performance for methanol electrooxidation Chem Mater 20 2008 4249 4259
30. x nanoparticles supported on carbon nanofibers for direct methanol fuel cells J Power Sources 186 2009 299 304
31. x in sulfuric acid solution Electrochem Commun 7 2005 406 410 (Pubitemid 40381239)
32. x as electrocatalyst for methanol oxidation Int J Hydrogen Energy 35 2010 936 941
33. W. Yu, W. Tu, and H. Liu Synthesis of nanoscale platinum colloids by microwave dielectric heating Langmuir 15 1999 6 9
34. Z. Zhou, S. Wang, W. Zhou, G. Wang, L. Jiang, and W. Li Novel synthesis of highly active Pt/C cathode electrocatalyst for direct methanol fuel cell Chem Commun 2003 394 395 (Pubitemid 36207730)
35. x anode catalysts for a polymer electrolyte fuel cell J Electrochem Soc 156 2009 B1361 B1368
36. W. Chrzanowski, H. Kim, and A. Wieckowski Enhancement in methanol oxidation by spontaneously deposited ruthenium on low-index platinum electrodes Catal Lett 50 1998 69 75 (Pubitemid 128482701)
37. S. Hüfner Photoelectron spectroscopy: principles and applications 1996 Springer Heidelberg
38. B.A. Pereira, F. Laplante, M. Chaker, and D. Guay Functionally modified macroporous membrane prepared by using pulsed laser deposition Adv Funct Mater 17 2007 443 450
39. H. Sakagami, Y. Asano, T. Ohno, N. Takahashi, H. Itoh, and T. Matsuda Appl Catal A Gen 297 2006 189 197
40. 3 composites J Phys Chem B 108 2004 310 319
41. x catalysts prepared from Pt-Mo alloy precursors J Phys Chem C 111 2007 14790 14798 (Pubitemid 350017508)
42. 3 J Phys Chem C Lett 112 2008 1755 1758 (Pubitemid 351322038)
43. G. Samjeské, H. Wang, T. Löffler, and H. Baltruschat CO and methanol oxidation at Pt-electrodes modified by Mo Electrochim Acta 47 2002 3681 3692 (Pubitemid 34974775)
44. S. Martínez, M.E. Martins, and C.F. Zinola Surface metal modifiers for methanol electrooxidation on platinum, molybdenum and tungsten Int J Hydrogen Energy 35 2010 5343 5355
45. N. Tsiouvaras, M.V. Martínez-Huerta, O. Paschos, U. Stimming, J.L.G. Fierro, and M.A. Peña PtRuMo/C catalysts for direct methanol fuel cells: effect of the pretreatment on the structural characteristics and methanol electrooxidation Int J Hydrogen Energy 35 2010 11478 11488
46. M. Krausa, and W. Vielstich Potential oscillations during methanol oxidation at Pt-electrodes part 1: experimental conditions J Electroanal Chem 399 1995 7 12
47. J. Chen, M. Wang, B. Liu, Z. Fan, K. Cui, and Y. Kuang Platinum catalysts prepared with functional carbon nanotube defects and its improved catalytic performance for methanol oxidation J Phys Chem B 110 2006 11775 11779 (Pubitemid 44024792)
48. W.B. Kim, T. Voitl, G.J. Rodriguez-Rivera, and J.A. Dumesic Powering fuel cells with CO via aqueous polyoxometalates and gold catalysts Science 305 2004 1280 1283 (Pubitemid 39129230)
49. J. Jiang, and A. Kucernak Electrooxidation of small organic molecules on mesoporous precious metal catalysts II: CO and methanol on platinum-ruthenium alloy J Electroanal Chem 543 2003 187 199
50. L.C. Ordóñez, P. Roquero, P.J. Sebastian, and J. Ramírez CO oxidation on carbon-supported PtMo electrocatalysts: effect of the platinum particle size Int J Hydrogen Energy 32 2007 3147 3153 (Pubitemid 47562178)