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As a check on the present results, we recorded several spectra using a different fluorimeter from the one used to collect the results reported here and obtained nearly identical spectra
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As a check on the present results, we recorded several spectra using a different fluorimeter from the one used to collect the results reported here and obtained nearly identical spectra.
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Because the emission quantum yields of CVL in polar solvents are in the range 0.004 to 0.023, solvent impurities and contributions of Raman scattering interfere with decay measurements more than in typical fluorescence probes. In some cases, we subtracted transients obtained from solvent blanks before fitting the emission decays, which tends to reduce but not eliminate the relative magnitude of the intermediate component
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Because the emission quantum yields of CVL in polar solvents are in the range 0.004 to 0.023, solvent impurities and contributions of Raman scattering interfere with decay measurements more than in typical fluorescence probes. In some cases, we subtracted transients obtained from solvent blanks before fitting the emission decays, which tends to reduce but not eliminate the relative magnitude of the intermediate component.
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In solvents having slow solvation responses such as ionic liquids, the LE band undergoes a dynamic Stokes shift, which typically spoils this simple behavior. (8) Interestingly, in one ionic liquid, Santhosh and Samanta (6) report a clear isoemissive point despite a significant dynamic Stokes shift of the LE band
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In solvents having slow solvation responses such as ionic liquids, the LE band undergoes a dynamic Stokes shift, which typically spoils this simple behavior. (8) Interestingly, in one ionic liquid, Santhosh and Samanta (6) report a clear isoemissive point despite a significant dynamic Stokes shift of the LE band.
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Equation 3.7 of ref 14 is incorrect; Equation 6 is the corrected version.
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Propylene carbonate viscosity data are from refs 28 - 30, which fit to the relation ln(Ε/cP) =  - 2.181 + 456.2/(T /K - 149.03) valid between 205 - 400 K. Butyronitrile viscosities are from ESDU Physical Data, Chemical Engineering Series () which fit to ln(Ε/cP) =  - 3.405 + 644.3/(T /K - 68.33) over the temperature range 175 - 375 K
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Propylene carbonate viscosity data are from refs 28 - 30, which fit to the relation ln(Ε/cP) =  - 2.181 + 456.2/(T /K - 149.03) valid between 205 - 400 K. Butyronitrile viscosities are from ESDU Physical Data, Chemical Engineering Series (http://www.esdu.com/) which fit to ln(Ε/cP) =  - 3.405 + 644.3/(T /K - 68.33) over the temperature range 175 - 375 K.
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