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Volumn 115, Issue 16, 2011, Pages 3746-3754

Solvent-controlled electron transfer in crystal violet lactone

Author keywords

[No Author keywords available]

Indexed keywords

ADIABATIC POTENTIALS; APROTIC SOLVENTS; CHARGE-TRANSFER REACTIONS; CRYSTAL VIOLET LACTONE; DIELECTRIC CONTINUUM MODEL; ELECTRON TRANSFER; HIGHLY POLAR SOLVENT; KINETIC DATA; NON-POLAR SOLVENTS; PICOSECOND TIME; SOLVATOCHROMIC ANALYSIS; SOLVENT POLARITY; STEADY-STATE EMISSIONS;

EID: 79955396124     PISSN: 10895639     EISSN: 15205215     Source Type: Journal    
DOI: 10.1021/jp106240x     Document Type: Article
Times cited : (18)

References (34)
  • 16
    • 79955405509 scopus 로고    scopus 로고
    • As a check on the present results, we recorded several spectra using a different fluorimeter from the one used to collect the results reported here and obtained nearly identical spectra
    • As a check on the present results, we recorded several spectra using a different fluorimeter from the one used to collect the results reported here and obtained nearly identical spectra.
  • 19
    • 79955406542 scopus 로고    scopus 로고
    • Unpublished calculations, (
    • Jensen, L. Unpublished calculations, (2010.
    • (2010)
    • Jensen, L.1
  • 24
    • 79955454830 scopus 로고    scopus 로고
    • Because the emission quantum yields of CVL in polar solvents are in the range 0.004 to 0.023, solvent impurities and contributions of Raman scattering interfere with decay measurements more than in typical fluorescence probes. In some cases, we subtracted transients obtained from solvent blanks before fitting the emission decays, which tends to reduce but not eliminate the relative magnitude of the intermediate component
    • Because the emission quantum yields of CVL in polar solvents are in the range 0.004 to 0.023, solvent impurities and contributions of Raman scattering interfere with decay measurements more than in typical fluorescence probes. In some cases, we subtracted transients obtained from solvent blanks before fitting the emission decays, which tends to reduce but not eliminate the relative magnitude of the intermediate component.
  • 26
    • 79955455342 scopus 로고    scopus 로고
    • In solvents having slow solvation responses such as ionic liquids, the LE band undergoes a dynamic Stokes shift, which typically spoils this simple behavior. (8) Interestingly, in one ionic liquid, Santhosh and Samanta (6) report a clear isoemissive point despite a significant dynamic Stokes shift of the LE band
    • In solvents having slow solvation responses such as ionic liquids, the LE band undergoes a dynamic Stokes shift, which typically spoils this simple behavior. (8) Interestingly, in one ionic liquid, Santhosh and Samanta (6) report a clear isoemissive point despite a significant dynamic Stokes shift of the LE band.
  • 27
    • 79955438993 scopus 로고    scopus 로고
    • Equation 3.7 of ref 14 is incorrect; Equation 6 is the corrected version
    • Equation 3.7 of ref 14 is incorrect; Equation 6 is the corrected version.
  • 33
    • 79955450843 scopus 로고    scopus 로고
    • Propylene carbonate viscosity data are from refs 28 - 30, which fit to the relation ln(Ε/cP) =  - 2.181 + 456.2/(T /K - 149.03) valid between 205 - 400 K. Butyronitrile viscosities are from ESDU Physical Data, Chemical Engineering Series () which fit to ln(Ε/cP) =  - 3.405 + 644.3/(T /K - 68.33) over the temperature range 175 - 375 K
    • Propylene carbonate viscosity data are from refs 28 - 30, which fit to the relation ln(Ε/cP) =  - 2.181 + 456.2/(T /K - 149.03) valid between 205 - 400 K. Butyronitrile viscosities are from ESDU Physical Data, Chemical Engineering Series (http://www.esdu.com/) which fit to ln(Ε/cP) =  - 3.405 + 644.3/(T /K - 68.33) over the temperature range 175 - 375 K.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.