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-1) in the absorption spectrum published in ref. 35. As the tail is not recovered in the fluorescence excitation spectra recorded in different solvents, the absorption in this region is probably to be ascribed to impurity traces.
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fl values, obtained by comparing luminescence intensity measured at given temperature with that measured at room temperature were greater than 1.0 despite taking into account solvent contraction with decreasing temperature. The changes in absorption and in refractive index of the solvent with temperature were not, however, accounted for. Intensity ratios greater than 1.0 are probably related to changes of the refractive index with temperature, and especially the difference in n between the liquid and the solid BTN. While temperature dependent absorption was not measured for MGL, the corresponding temperature-dependent measurements for CVL and rhodamine B lactone in BTN yielded only small changes of absorption intensity in their first absorption bands.
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Estimated from the 0-0 band in the phosphorescence spectrum of phthalide.
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75
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Though the present study was basically set to describe the photophysics of MGL in aprotic solvents, some conclusions from MGL behaviour in alcohols may be also helpful in better understanding of excited state processes occurring in MGL in aprotic environment. More detailed study of LTAMs in protic environment will be published elsewhere.
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Estimated as the sum of the transition energy plus the energy of the Franck-Condon ground state.
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