Surface modified, collapsible controlled pore glass materials for sequestration and immobilization of trivalent metal ions

Industrial and Engineering Chemistry Research

Volumn 50, Issue 8, 2011, Pages 4686-4696

  Shkrob, Ilya A ^a   Tisch, Angela R ^a   Marin, Timothy W ^a   Muntean, John V ^a   Kaminski, Michael D ^a   Kropf, A Jeremy ^a  

^a ARGONNE NATIONAL LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACID LEACHING; AQUEOUS COMPLEXES; BOROSILICATE WASTE; CONTROLLED PORE GLASS; DISTRIBUTION COEFFICIENT; FUSED MATERIALS; GLASS MATRICES; GLASS NETWORK; HIGH LEVEL RADIOACTIVE WASTES; HIGH-SILICA GLASS; IONIC RADIUS; LANTHANIDE OXIDE; LANTHANIDES; LONG-TERM DISPOSAL; MASKING AGENTS; MATRIX; NANO-MATERIALS; ONE-POT METHOD; PROCESSING TEMPERATURE; RAFFINATES; SINGLE-STEP; SPENT NUCLEAR FUELS; SURFACE-MODIFIED; TEMPORARY STORAGE; TIME-RESOLVED LUMINESCENCE SPECTROSCOPY; TRIVALENT ACTINIDES; TRIVALENT METAL IONS; WASTE STREAM;

ABSORPTION; ABSORPTION SPECTROSCOPY; ACTINIDES; CALCINATION; CHEMICAL MODIFICATION; LEACHING; MAGNETIC RESONANCE; METAL IONS; PHOSPHORUS; PROCESSING; RADIOACTIVE WASTE STORAGE; RADIOACTIVE WASTE VITRIFICATION; RADIOACTIVE WASTES; RARE EARTH ELEMENTS; SILICA; SINTERING; SOLVENT EXTRACTION; WASTE DISPOSAL; X RAY ABSORPTION;

BOROSILICATE GLASS;

EID: 79954529909     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie102494r     Document Type: Article

References (41)

1. Shkrob, I. A.; Kaminski, M. D.; Rahimian, K.; Derzon, M. S. Magnetic extraction, detection, and isotope analysis of metal ions using surface modified microspheres for lab-on-a-chip applications Sep. Sci. Technol. 2010, 45, 186
2. Shkrob, I. A.; Kaminski, M. D.; Mertz, C. J.; Rickert, P.; Derzon, M. S.; Rahimian, K. Sequestration, fluorometric detection, and mass spectroscopy analysis of lanthanide ions using surface modified magnetic microspheres J. Am. Chem. Soc. 2009, 131, 15705
3. Chen, D.; Hiroshi, M.; Tomoko; Tetsuo, Y. Colorless transparent fluorescence material: Sintered porous glass containing rare-earth and transition-metal ions Appl. Phys. Lett. 2005, 86, 231908
4. Beitz, J. V.; Williams, C. W.; Hong, K.-S.; Liu, G. K. Heavy metal phosphate nanophases in silica J. Solid State Chem. 2005, 178, 511
5. Beitz, J. V.; Skanthakumar, S.; Seifert, S.; Thiyagarajan, P. F-Element influence on the size of nanophase phosphate inclusions in silica. Mater. Res. Soc. Symp. Proc. 2004, 820, DD3.9.1
6. Fryxell, G. E. The synthesis of functional mesoporous materials Inorg. Chem. Commun. 2006, 9, 1141
7. Fryxell, G. E.; Addleman, R. S.; Mattigod, S. V.; Lin, Y.; Zemanian, T. S.; Wu, H.; Birnbaum, J. C.; Liu, J.; Feng, X. Environmental and sensing applications of molecular self-assembly. In Dekker Encyclopedia of Nanoscience and Nanotechnology; Schwarz, J. A.; Contescu, C.; Putyera, K., Ed.; Marcel Dekker: New York, 2004; pp 1135 - 1145.
8. Fryxell, G. E.; Wu, H.; Lin, Y.; Shaw, W. J.; Birnbaum, J. C.; Linehan, J. C.; Nie, Z; Kemner, K. M.; Kelly, S. Lanthanide selective sorbents: self-assembled monolayers on mesoporous supports (SAMMS) J. Mater. Chem. 2004, 14, 3356
9. Fryxell, G. E.; Lin, Y.; Wu, H.; Kemmer, K. M. Environmental applications of self-assembled monolayers on mesoporous supports (SAMMS). In Nanoporous Materials III, Studies in Surface Science and Catalysis; Sayari, A.; Jaroniec, M., Ed.; Elsevier: Amsterdam, Netherlands, 2002; Vol. 141; pp 583 - 590.
10. Fryxell, G. E.; Liu, J. Designing surface chemistry in mesoporous silica. In Adsorption on Silica Surfaces, Surfactant Science Series; Papirer, E., Ed.; Marcel Dekker: New York, 2000; Vol. 90, pp 665 - 687.
11. Feng, X.; Rao, L.; Mohs, T. R.; Xu, J.; Xia, Y.; Fryxell, G. E.; Lu, J.; Raymond, K. N. Self-assembled monolayers on mesoporous silica, a super sponge for actinides. In Environmental Issues and Waste Management Technologies in the Ceramic and Nuclear Industries IV: Ceramic Transactions; Marra, J. C.; Chandler, G. T., Ed.; The American Ceramic Society: Westerville, OH, 1999; Vol. 93, pp 35 - 42.
12. Mattigod, S. V.; Fryxell, G. E.; Feng, X.; Liu, J. Self-assembled monolayers on mesoporous supports for metal separation. In Metal Separation Technologies Beyond 2000: Integrating Novel Chemistry With Processing; Minerals, Metals & Materials Soc.: Warrendale, PA, 1999; pp 71 - 80.
13. Busche, B. J.; Wiacek, R. J.; Davidson, J. D.; Koonsiripaiboon, V.; Yantasee, W.; Addleman, R. S.; Fryxell, G. E. Synthesis of nanoporous iminodiacetic acid sorbents for binding transition metals Inorg. Chem. Commun. 2009, 12, 312
14. Fryxell, G. E. Synthesis of nanostructured hybrid sorbents materials using organosilane self-assembly on mesoporous ceramic oxides. In Environmental Applications of Nanomaterials: Synthesis, Sorbents, and Sensors; Fryxell, G. E.; Cao, G., Ed.; Imperial College Press: London, UK, 2007; pp 159.
15. Bourg, S.; Broudic, J.-C.; Conocar, O.; Moreau, J. J. E.; Meyer, D.; Man, M. W. C. Tailoring of organically modified silicas for the solid-liquid extraction of actinides Chem. Mater. 2001, 13, 491
16. Trens, P.; Russell, M. L.; Spjuth, L.; Hudson, M. J.; Liljenzin, J.-O. Preparation of malonamide - MCM-41 materials for the heterogeneous extraction of radionuclides Ind. Eng. Chem. Res. 2002, 41, 5220
17. Li, H. R.; Lin, J.; Fu, L. S.; Guo, J. F.; Meng, Q. G.; Liu, F. Y.; Zhang, H. J. Phenanthroline-functionalized MCM-41 doped with Europium ions Microporous Mesoporous Mater. 2002, 55, 103
18. Steinbacher, J. L.; Lathrop, S. A.; Cheng, K.; Hillegrass, J. M.; Butnor, K. J.; Kauppinen, R. A.; Mossman, B. T.; Landry, C. C. Gadolinium-labeled microparticles in MRI: In vivo imaging of microparticles after intraperitoneal injection Small 2010, 6, 2678
19. Chen, Y.; Chen, H.; Zeng, D.; Tian, Y.; Chen, F.; Feng, J.; Shi, J. Core/shell structured hollow mesoporous nanocapsules: a potential platform for simultaneous cell imaging and anticancer drug delivery ACS Nano 2010, 4, 6001
20. Anspach, F. B. Silica-based metal chelate affinity sorbents I. Preparation and characterization of iminodiacetic acid affinity sorbents prepared via different immobilization techniques J. Chromatogr. A 1994, 672, 35
21. Ma, Z.; Guan, Y.; Liu, H. Superparamagnetic silica nanoparticles with immobilized metal affinity ligands for protein adsorption J. Magn. Magn. Mater. 2006, 301, 469
22. Meyer, D.; Schaefer, M.; Bonnemain, B. Gd-DOTA, a potential MRI contrast agent. Current status of physicochemical knowledge Invest. Radiol. 1988, 23, S232
23. Tian, G.; Martin, L. R.; Rao, L. Complexation of lactate with neodymium (III) and europium (III) at variable temperatures: Studies by potentiometry, microcalorimetry, optical absorption, and luminescence spectroscopy Inorg. Chem. 2010, 49, 10598
24. Herlinger, A. W.; Ferraro, J. R.; Chiarizia, R.; Horwitz, E. P. An investigation of P, P ′-di(2-ethylhexyl)methanediphosphonic acid and some of its metal complexes Polyhedron 1997, 16, 1843
25. Nash, K. L.; Jensen, M. P. Analytical separations of the lanthanides: Basic chemsitry and methods. In Handbook on the Physics and Chemsitry of Rare Earths; Elsevier: Amsterdam, 2000; Vol. 28, pp 311.
26. Nilsson, M.; Nash, K. L. Review article: A review of the development and operational characteristics of the TALSPEAK process Solv. Extr. Ion Exch. 2007, 25, 665
27. Liljenzin, J. O.; Persson, G.; Svantesson, I.; Wingefors, S. The CHT-process for HLLW treatment, Part I. General description and process design Radiochim. Acta. 1984, 35, 155
28. Persson, G.; Svantesson, I.; Wingefors, S.; Liljenzin, J. O. Hot test of a TALSPEAK procedure from separation of actinides and lanthanides using recirculating DTPA-lactic acid solution Solvent Extr. Ion Exch. 1984, 2, 89
29. Crawford, C. L.; Marra, J. C.; Bibler, N. E. Glass fabrication and product consistency testing of lanthanide borosilicate glass for plutonium disposition J. Alloys Compounds 2007, 444-445, 569
30. Zachariasen., W. H. The crystal structure of the modification of the sesquioxides of the rare earth metals, and of indium and thallium Norsk Geologisk Tidsskrift 1927, 9, 310
31. Yakel, H. L., Jr. A refinement of the crystal structure of monoclinic europium sesquioxide Acta Crystallographica B 1979, 35, 564
32. Albin, M.; Whittle, R. R.; Horrocks, W. D., Jr. Laser spectroscopic and X-ray structural investigation of europium(III)-oxydiacetate complexes in solution and in the solid state Inorg. Chem. 1985, 24, 4591
33. Antonio, M. R.; Soderholm, L.; Ellison, A. J. G. Local environment of erbium and lutetium in sodium silica glasses J. Alloys Comp. 1997, 250, 536
34. 2- complexes: Solid state and solution structures Inorg. Chem. 1998, 37, 3667
35. Borel, A.; Helm, L.; Merbach, A. E. Molecular dynamics of Gd(III) complexes in aqueous solutions by high-field EPR. In Very High Frequency ESR/EPR; Grinberg, O. Y.; Berliner, L. J., Ed.; Kluwer Academic: New York, 2004; p 207.
36. Reuben, J. Electron spin relaxation in aqueous solution of Gd(III). Aquo, cacodylate, and bovine serum albumin complexes J. Phys. Chem. 1971, 75, 3164
37. Rast, S.; Borel, A.; Helm, L.; Belorizky, E.; Fries, P. H.; Merbach, A. E. EPR spectroscopy of MRI-related Gd(III) complexes: Simultaneous analysis of multiple frequency and temperature spectra, including static and transient crystal field effects J. Am. Chem. Soc. 2001, 123, 2673
38. Benmelouka, M.; Van Tol, J.; Borel, A.; Nellutla, S.; Port, M.; Helm, L.; Brunel, L.-C.; Merbach, A. E. Multiple-frequency and variable-temperature EPR study of gadolinium (III) complexes with polyaminocarboxylates: analysis and comparison of the magnetically dilute powder and the frozen-solution spectra Helv. Chim. Acta 2009, 92, 2173
39. Kliava, J.; Edelman, I. S.; Potseluyko, A. M.; Petrakovskaja, E. A.; Berger, R.; Bruckental, I.; Yeshurun, Y.; Malakhovski, A. V.; Zarubina, T. V. Magnetic and optical properties and EPR of gadolinium-containing oxide glasses J. Phys.: Condens. Matter 2003, 15, 6671
40. Kliava, J.; Malakhovskii, A.; Edelman, I.; Potseluyko, A.; Petrakovskaya, E.; Melnikova, S.; Zarubina, T.; Petrosvskii, G.; Bruckental, Y.; Yeshurun, Y. Unusual magnetic transitions and nature of magnetic resonance spectra in oxide glasses containing gadolinium Phys. Rev. B 2005, 71, 104406
41. Caravajal, G. S.; Leyden, D. E.; Quinting, G. R.; Maciel, G. E. Structural characterization of (3-aminopropyl)triethoxysilane-modified silicas by silicon-29 and carbon-13 nuclear magnetic resonance Anal. Chem. 1988, 60, 1776-1786