Magnetic extraction, detection, and isotope analysis of metal ions using surface modified microspheres for lab-on-a-chip applications

Separation Science and Technology

Volumn 45, Issue 2, 2010, Pages 186-197

  Shkrob, Ilya A ^a   Kaminski, Michael D ^a   Rahimian, Kamyar ^b   Derzon, Mark S ^b  

^a ARGONNE NATIONAL LABORATORY   (United States)

^b SANDIA NATIONAL LABORATORIES   (United States)

Author keywords

Antenna effect; Fluorometry; Ion exchange chromatography; Isotope analysis; Magnetic separations; Microfluidics

Indexed keywords

ANTENNA EFFECTS; CHEMICAL MANIPULATION; EFFICIENT METHOD; FLUOROMETRIC DETECTION; ION EXCHANGE PROPERTIES; ION-EXCHANGE CHROMATOGRAPHY; ISOTOPE ANALYSIS; LAB-ON-A-CHIP APPLICATIONS; LANTHANIDE ION; LIQUID-LIQUID EXTRACTION; MAGNETIC EXTRACTION; MAGNETIC MICROSPHERES; MIXED LIGAND COMPLEXES; POLYSTYRENE MICRO-SPHERE; RAPID EXTRACTION; SURFACE-MODIFIED;

ANTENNAS; CHEMICAL DETECTION; COMPLEXATION; FLUOROMETERS; ION EXCHANGE; ION EXCHANGERS; ISOTOPES; LIQUID CHROMATOGRAPHY; LIQUIDS; MAGNETIC SEPARATION; METAL ANALYSIS; METAL IONS; METAL RECOVERY; MICROFLUIDICS; MICROSPHERES; POLYSTYRENES; RARE EARTH ELEMENTS; SOLVENT EXTRACTION;

MAGNETIC BUBBLES;

CHROMATOGRAPHY; EXTRACTION METHOD; ION EXCHANGE; METAL; PHASE SEPARATION; POLYSTYRENE; SURFACE MODIFICATION;

EID: 77949394494     PISSN: 01496395     EISSN: 15205754     Source Type: Journal    
DOI: 10.1080/01496390903423733     Document Type: Article

References (42)

1. Horwitz, E.P.; McAlister, D.R.; Bond, A.H.; Barrans, R.E. (2005) Novel extraction of chromatographic resins based on tetraalkyldigly- colamides: Characterization and potential applications. Solvent Extraction Ion Exch., 23: 9.
2. Horwitz, E.P.; Chiarizia, R.; Dietz, M.L.; Diamond, H.; Nelson, D. (1993) Separation and preconcentration of actinides from acidic media by extraction chromatography. Anal. Chimica Acta, 281: 361.
3. Ugaz, V.M.; Christensen, J.L. (2007) In: Microfluidic Technologies for Miniaturized Analysis Systems, Hardt, S.; Schonfeld, F., eds.; Springer: New York, 393.
4. Smistrup, K.; Lund-Olsen, T.; Hansen, M.F.; Tang, P.T. (2006) Microfluidic magnetic separator using an array of soft magnetic elements. J. Appl. Phys., 99: 08P102.
5. Deng, T.; Prentiss, M.; Whitesides, G.M. (2002) Fabrication of magnetic microfiltration systems using soft lithography. Appl. Phys. Lett., 80: 461.
6. Morozov, V.N.; Groves, S.; Turell, M.J.; Bailey, C. (2006) Three minutes-long electrophoretically assisted zeptomolar microfluidic immunoassay with magnetic-beads detection. J. Am. Chem. Soc., 129: 12628.
7. Nunez, L.; Kaminski, M.D. (1998) Separating metals using coated magnetic particles. CHEMTECH, 28: 41.
8. Buchholz, B.A.; Tuazon, H.E.; Kaminski, M.D.; Aase, S.B.; Nunez, L.; Vandegrift, G.F. (1997) Optimizing the coating process of organic actinide extractant on magnetically assisted chemical separation particles. Separ. Purif. Techn., 11: 211.
9. Nunez, L.; Buchholz, B.A.; Kaminski, M.D.; Aase, S.B.; Brown, N.R.; Vandegrift, G.F. (1996) Actinide separation of high-level waste using solvent extractants on magnetic microparticles. Sep. Sci. Technol., 31: 1393.
10. Kaminski, M.D.; Nunez, L.; Visser, A.E. (1999) Evaluation of extractant-coated ferromagnetic microparticles for the recovery of hazardous metals from waste solutions. Sep. Sci. Technol., 34: 1103.
11. 0-dibutyl tetradecyl mal- onamide impregnated magnetic particles for the extraction and separation of radionuclides from nuclear waste streams. Radiochim. Acta, 94: 267.
12. Bohmer, V.; Dozol, J.-F.; Gruttner, C.; Liger, K.; Matthews, S.E.; Rudershausen, S.; Saadioui, M.; Wang, P. (2004) Separation of lanthanides and actinides using magnetic silica particles bearing covalently attached tetra-CMPO-calix[4]arenas. Org. Biomol. Chem., 2: 2372.
13. Gruttner, C.; Rudershausen, S.; Matthews, S.E.; Wang, P.; Bohmer, V.; Dozol, J.-F. (2002) Selective extraction of lanthanides and actinides by magnetical silica particles with CMPO-modified calix[4]- arenes on the surface. Eur. Cell. Mater., 3: 48.
14. Matthews, S.E.; Parzuchowski, P.; Garcia-Carrera, A.; Gruttner, C. (2001) Extraction of lanthanides and actinides by a magnetically assisted chemical separation technique based on CMPO- calix[4]arenes. Chem. Comm., 417.
15. Gruttner, C.; Bohmer, V.; Casnati, A.; Dozol, J.-F.; Reinhoudt, D.N.; Reinoso-Garcia, M.M.; Rudershausen, S.; Teller, J.; Ungaro, R.; Verboom, W.; Wang, P. (2005) Dendrimer-coated magnetic particles for radionuclide separation. J. Magn. Magn. Mater., 293: 559.
16. Hemila, I. (1995) Luminescent lanthanide chelates - a way to more sensitive diagnostic methods. J. Alloys Comp., 225: 480.
17. Keelan, J.A.; France, J.T.; Barling, P.M. (1987) An alternative fluorescence enhancement solution for use in lanthanide-based time- resolved fluoroimmunoassays. Clin. Chem., 33: 2292.
18. Shirakawa, E.; Honjo, T.; Terada, K. (1989) Highly sensitive spectrofluorometry of europium(III) as its benzoyltrifluoroacetone complex with trioctylphosphine oxide by means of solvent extraction and vacuum sublimation Fresenius Z. Anal. Chem., 334: 37.
19. Arnaud, N.; Georges, J. (1997) Fluorimetric determination of europium over a large dynamic range using its ternary complex with thenoyltrifluoroacetone and trioctylphosphine oxide in a micellar solution of triton X-100. Analyst, 122: 143.
20. Diamandis, E.P.; Christopoulos, T.K. (1990) Europium chelate labels in time-resolved fluorescence immunoassays and DNA hybridization assays. Anal. Chem., 62: 1149A.
21. Oliva, M.A.; Olsina, R.A.; Masi, A.N. (2005) Sensitive detection of salbutamol using europium-enhanced fluorescence with trioctylpho- sphine oxide. Analyst, 130: 1312.
22. Sabbatini, N.; Guadigli, M.; Lehn, J.-P. (1993) Luminescent lanthanide complexes as photochemical supramolecular devices. Coord. Chem. Rev., 123: 201.
23. Leonard, J.P.; Gunnlaugsson, T. (2005) Luminescent Eu(III) and Tb(III) complexes: Developing lanthanide luminescent-based devices. J. Fluor., 15: 585.
24. Nishioka, T.; Fukui, K.; Matsumoto, K. (2007) In: Handbook on the Physics and Chemistry of Rare Earths, Volume 27, Gschneidener, Jr., K.A.; Bunzli, J.-C.; Pecharsky, V.K., eds.; Elsevier: Amsterdam, The Netherlands, 171.
25. Sasaki, Y.; Choppin, G.R. (1996) Extraction behaviors of Eu, Th, U and Am with diamides{thorn}thenoyltrifluoroacetone. Radioanal. Nucl. Chem., 207: 383.
26. The parameters of the microspheres can be found on http://www.spherotech.com/coa_pol_par.htm
27. Baes, C.F., Jr.; Mesmer, R.E. (1976) The Hydrolysis of Cations; Wiley-Interscience: New York, New York.
28. Arnaud-Neu, F.; Böhmer, V.; Dozol, J.-F.; Grü ttner, C.; Jakobi, R. A.; Kraft, D.; Mauprivez, O.; Rouquette, H.; Schwing-Weill, M.-J.; Simon, N.; Vogt, W. (1996) Calixarenes with diphenylphosphoryl acetamide functions at the upper rim. A new class of highly efficient extractants for lanthanides and actinides. J. Chem. Soc., Perkin Trans. 2, 1175.
29. Jańczewski, D.; Reinhoudt, D.N.; Verboom, W.; Hill, C.; Allignol, C.; Duchesne, M.T. (2007) Tripodal diglycolamides as highly efficient extractants for f-elements. New J. Chem., 32: 490.
30. Jańczewski, D.; Rawdanowicz, M.; Hill, C.; Martinez, I.; Reinhoudt, D.N.; Verboom, W. (2008) Novel types of tripodal CMPO ligands: Synthesis and extraction. Radiochim. Acta, 96: 199.
31. Matloka, K.; Regalbuto, M.; Guelis, A.; Vandergrift, G.F.; Scott, M.J. (2005) Highly efficient binding of trivalent f-elements from acidic media with a C3-symmetric tripodal ligand containing diglycolamide arms. J. Chem. Soc. Dalton Trans., 3719.
32. Taki, M.; Murakami, H.; Sisido, M. (2000) A chiral Eu-thienoyltrifluoroacetone complex on an avidin tetramer: Luminescence and CD studies on the supramolecular protein-metal chelate complex. Chem. Comm., 1199.
33. Arduini, A. Pochini, A.; Secchi, A.; Ugozzoli, F. (2003) Chlorosulfonation of 2-acylthiophenes: An examination on the reaction regiochemistry. Tetrahedron Lett., 44: 5755.
34. The amide conjugation protocol adapted for magnetic microspheres that we used is described on http://www.bioclon.com/BcMag-Carboxyl-Terminated-Magnetic-Beads.pdf.
35. Nave, S.; Mandin, C.; Martinet, L.; Berthon, L.; Testard, F.; Madic, C.; Zemb, Th (2004) Supramolecular organization of tri-n-butyl phosphate in organic diluent on approaching third phase transition. Phys. Chem. Chem. Phys., 6: 799.
36. Delmau, L.H.; Simon, N.; Dozol, J.-F.; Eymard, S.; Tournois, B.; Schwing-Weill, M.-J.; Arnaud-Neu, F.; Böhmer, V.; Grü ttner, C.; Musigmann, C.; Tunayar, A. (1998) CMPO-substituted calix[4]arenes, extractants with selectivity among trivalent lanthanides and between trivalent actinides and lanthanides. Chem. Comm., 1627.
37. Herschbach, H.; Brisach, F.; Haddaoui, J.; Saadioui, M.; Leize, E.; Van Dorsselaer, A.; Arnaud-Neu, F.; Böhmer, V. (2007) Lanthanide complexation with CMPO and CMPO-calix[4]arenes in solution: Spectrophotometric and electrospray mass spectrometric approaches. Talanta, 74: 39.
38. Babain, V.A.; Alyapyshev, M.Yu.; Karavan, M.D.; Böhmer, V.; Wang, L.; Sokolova, E.A.; Motornaya, A.E.; Vatsouro, I.M.; Kovalev, V.V. (2005) Extraction of americium and europium by CMPO-substituted adamantylcalixarenes. Radiochem. Acta, 93: 749.
39. Arduini, A.; Böhmer, V.; Delmau, L.H.; Desreux, J.F.; Dozol, J.-F.; Garcia Carrera, M.A.; Lambert, B.; Musigmann, C.; Pocini, A.; Shivanyauk, A.; Ugozzoli, F. (2000) Rigidified calixarenes bearing four carbamoylmethylphosphine oxide or carbamoylmethyl phosphoryl functions at the wide rim. Chem. Eur. J., 6: 2135.
40. Schmidt, C.; Saadioui, M.; Böhmer, V.; Host, V.; Spirlet, M.-R.; Desreux, J. F.; Brisach, F.; Arnaud-Neu, F.; Dozol, J.-F. (2003) Modification of calix[4]arenes with CMPO-functions at the wide rim. Synthesis, solution behavior, and separation of actinides from lanthanides. Org. Biomol. Chem., 1: 4089.
41. Peters, M.W.; Werner, E.J.; Scott, M.J. (2002) Enhanced selectivity for actinides over lanthanides with CMPO ligands secured to a C3-symmetric triphenoxymethane platform. Inorg. Chem., 41: 1707.
42. Nwe, K.; Richard, J.P.; Morrow, J.R. (2007) Direct excitation luminescence spectroscopy of Eu(III) complexes of 1,4,7-tris-(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane derivatives and kinetic studies of their catalytic cleavage of an RNA analog. J. Chem. Soc., Dalton Trans., 5171.