-
3
-
-
61349093529
-
-
Lafferentz, L.; Ample, F.; Yu, H.; Hecht, S.; Joachim, C.; Grill, L. Science 2009, 323 (5918) 1193-1197
-
(2009)
Science
, vol.323
, Issue.5918
, pp. 1193-1197
-
-
Lafferentz, L.1
Ample, F.2
Yu, H.3
Hecht, S.4
Joachim, C.5
Grill, L.6
-
4
-
-
37549025069
-
-
Park, Y. S.; Whalley, A. C.; Kamenetska, M.; Steigerwald, M. L.; Hybertsen, M. S.; Nuckolls, C.; Venkataraman, L. J. Am. Chem. Soc. 2007, 129 (51) 15768-15769
-
(2007)
J. Am. Chem. Soc.
, vol.129
, Issue.51
, pp. 15768-15769
-
-
Park, Y.S.1
Whalley, A.C.2
Kamenetska, M.3
Steigerwald, M.L.4
Hybertsen, M.S.5
Nuckolls, C.6
Venkataraman, L.7
-
5
-
-
0000034952
-
-
Knoll, K.; Krouse, S. A.; Schrock, R. R. J. Am. Chem. Soc. 1988, 110 (13) 4424-4425
-
(1988)
J. Am. Chem. Soc.
, vol.110
, Issue.13
, pp. 4424-4425
-
-
Knoll, K.1
Krouse, S.A.2
Schrock, R.R.3
-
6
-
-
21244450344
-
-
Catalan, J.; Hopf, H.; Mlynek, C.; Klein, D.; Kilickiran, P. Chem.-Eur. J. 2005, 11 (13) 3915-3920
-
(2005)
Chem.-Eur. J.
, vol.11
, Issue.13
, pp. 3915-3920
-
-
Catalan, J.1
Hopf, H.2
Mlynek, C.3
Klein, D.4
Kilickiran, P.5
-
7
-
-
0042322640
-
-
Xu, B. Q.; Tao, N. J. J. Science 2003, 301 (5637) 1221-1223
-
(2003)
Science
, vol.301
, Issue.5637
, pp. 1221-1223
-
-
Xu, B.Q.1
Tao, N.J.J.2
-
8
-
-
33747843929
-
-
Venkataraman, L.; Klare, J. E.; Nuckolls, C.; Hybertsen, M. S.; Steigerwald, M. L. Nature 2006, 442 (7105) 904-907
-
(2006)
Nature
, vol.442
, Issue.7105
, pp. 904-907
-
-
Venkataraman, L.1
Klare, J.E.2
Nuckolls, C.3
Hybertsen, M.S.4
Steigerwald, M.L.5
-
9
-
-
79954563184
-
-
0. No bias dependence was found within this bias range.
-
0. No bias dependence was found within this bias range.
-
-
-
-
10
-
-
68249159436
-
-
Park, Y. S.; Widawsky, J. R.; Kamenetska, M.; Steigerwald, M. L.; Hybertsen, M. S.; Nuckolls, C.; Venkataraman, L. J. Am. Chem. Soc. 2009, 131 (31) 10820-10821
-
(2009)
J. Am. Chem. Soc.
, vol.131
, Issue.31
, pp. 10820-10821
-
-
Park, Y.S.1
Widawsky, J.R.2
Kamenetska, M.3
Steigerwald, M.L.4
Hybertsen, M.S.5
Nuckolls, C.6
Venkataraman, L.7
-
11
-
-
13444262007
-
-
He, J.; Chen, F.; Li, J.; Sankey, O. F.; Terazono, Y.; Herrero, C.; Gust, D.; Moore, T. A.; Moore, A. L.; Lindsay, S. M. J. Am. Chem. Soc. 2005, 127 (5) 1384-1385
-
(2005)
J. Am. Chem. Soc.
, vol.127
, Issue.5
, pp. 1384-1385
-
-
He, J.1
Chen, F.2
Li, J.3
Sankey, O.F.4
Terazono, Y.5
Herrero, C.6
Gust, D.7
Moore, T.A.8
Moore, A.L.9
Lindsay, S.M.10
-
12
-
-
64449083038
-
-
Quek, S. Y.; Kamenetska, M.; Steigerwald, M. L.; Choi, H. J.; Louie, S. G.; Hybertsen, M. S.; Neaton, J. B.; Venkataraman, L. Nat. Nanotechnol. 2009, 4 (4) 230-234
-
(2009)
Nat. Nanotechnol.
, vol.4
, Issue.4
, pp. 230-234
-
-
Quek, S.Y.1
Kamenetska, M.2
Steigerwald, M.L.3
Choi, H.J.4
Louie, S.G.5
Hybertsen, M.S.6
Neaton, J.B.7
Venkataraman, L.8
-
13
-
-
53549108072
-
-
Martin, C. A.; Ding, D.; Sorensen, J. K.; Bjornholm, T.; van Ruitenbeek, J. M.; van der Zantt, H. S. J. J. Am. Chem. Soc. 2008, 130 (40) 13198-13199
-
(2008)
J. Am. Chem. Soc.
, vol.130
, Issue.40
, pp. 13198-13199
-
-
Martin, C.A.1
Ding, D.2
Sorensen, J.K.3
Bjornholm, T.4
Van Ruitenbeek, J.M.5
Van Der Zantt, H.S.J.6
-
14
-
-
0041904379
-
-
The rotational barrier about the single bond in a conjugated diene is ∼6 kcal/mol, where the local minima of the s-cis conformer lies ∼2 kcal/mol higher in energy (see, ()). Time-dependent DFT calculations on a D3 (all s-trans) estimates the rotation about the a single bond at 4 kcal/mol. Calculations suggest that orbitals energies of these conformers are similar and also that molecular length is does not change significantly before and after rotation The s-trans/s-cis conformers are not expected to account for the dramatic difference between the high- and low-conductance states in our break junction measurements but may contribute to peak broadening
-
The rotational barrier about the single bond in a conjugated diene is ∼6 kcal/mol, where the local minima of the s-cis conformer lies ∼2 kcal/mol higher in energy (see Carriera, L. A. J. Chem. Phys. 1975, 62 (10) 3851-3854). Time-dependent DFT calculations on a D3 (all s-trans) estimates the rotation about the a single bond at 4 kcal/mol. Calculations suggest that orbitals energies of these conformers are similar and also that molecular length is does not change significantly before and after rotation The s-trans/s-cis conformers are not expected to account for the dramatic difference between the high- and low-conductance states in our break junction measurements but may contribute to peak broadening
-
(1975)
J. Chem. Phys.
, vol.62
, Issue.10
, pp. 3851-3854
-
-
Carriera, L.A.1
-
15
-
-
0032558827
-
-
Yanson, A. I.; Bollinger, G. R.; van den Brom, H. E.; Agrait, N.; van Ruitenbeek, J. M. Nature 1998, 395 (6704) 783-785
-
(1998)
Nature
, vol.395
, Issue.6704
, pp. 783-785
-
-
Yanson, A.I.1
Bollinger, G.R.2
Van Den Brom, H.E.3
Agrait, N.4
Van Ruitenbeek, J.M.5
-
16
-
-
63649150380
-
-
Kamenetska, M.; Koentopp, M.; Whalley, A.; Park, Y. S.; Steigerwald, M.; Nuckolls, C.; Hybertsen, M.; Venkataraman, L. Phys. Rev. Lett. 2009, 102 (12) 126803
-
(2009)
Phys. Rev. Lett.
, vol.102
, Issue.12
, pp. 126803
-
-
Kamenetska, M.1
Koentopp, M.2
Whalley, A.3
Park, Y.S.4
Steigerwald, M.5
Nuckolls, C.6
Hybertsen, M.7
Venkataraman, L.8
-
17
-
-
79954542507
-
-
2. This model offers the empty orbital space (Lewis acidity) into which the S lone pair can delocalize to form the donor-acceptor bond that initiates the molecular-bridge-forming process.
-
2. This model offers the empty orbital space (Lewis acidity) into which the S lone pair can delocalize to form the donor-acceptor bond that initiates the molecular-bridge-forming process.
-
-
-
-
21
-
-
0033579180
-
-
Murahashi, T.; Mochizuki, E.; Kai, Y.; Kurosawa, H. J. Am. Chem. Soc. 1999, 121 (45) 10660-10661
-
(1999)
J. Am. Chem. Soc.
, vol.121
, Issue.45
, pp. 10660-10661
-
-
Murahashi, T.1
Mochizuki, E.2
Kai, Y.3
Kurosawa, H.4
-
22
-
-
61449267482
-
-
Xia, J. L.; Diez-Perez, I.; Tao, N. J. Nano Lett. 2008, 8 (7) 1960-1964
-
(2008)
Nano Lett.
, vol.8
, Issue.7
, pp. 1960-1964
-
-
Xia, J.L.1
Diez-Perez, I.2
Tao, N.J.3
-
23
-
-
33751557953
-
-
Haiss, W.; Wang, C.; Grace, I.; Batsanov, A. S.; Schiffrin, D. J.; Higgins, S. J.; Bryce, M. R.; Lambert, C. J.; Nichols, R. J. Nat. Mater. 2006, 5, 995-1002
-
(2006)
Nat. Mater.
, vol.5
, pp. 995-1002
-
-
Haiss, W.1
Wang, C.2
Grace, I.3
Batsanov, A.S.4
Schiffrin, D.J.5
Higgins, S.J.6
Bryce, M.R.7
Lambert, C.J.8
Nichols, R.J.9
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