Extent of M2 δ to ligand π-conjugation in neutral and mixed valence states of bis(4-isonicotinate)-bis(2,4,6-triisopropylbenzoate) dimetal complexes (MM), where M = Mo or W, and their adducts with tris(pentafluorophenyl)boron

Journal of the American Chemical Society

Volumn 133, Issue 15, 2011, Pages 5873-5881

  Bunting, Philip ^a   Chisholm, Malcolm H ^a   Gallucci, Judith C ^a   Lear, Benjamin J ^a  

^a OHIO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE RESONANCES; ELECTRON LIGANDS; ELECTRON PARAMAGNETIC RESONANCE; ELECTRONIC SPECTRUM; ELECTRONIC STRUCTURE CALCULATIONS; EPR SPECTRA; ISONICOTINIC ACID; LOW ENERGIES; LOWER ENERGIES; MIXED VALENCE; MIXED VALENCE STATE; MIXED VALENCE SYSTEMS; N-HEXANE; ORBITAL MIXING; PENTAFLUOROPHENYL; RADICAL ANIONS; RADICAL CATIONS; SPECTRAL FEATURE; UV-VIS-NIR ABSORPTION;

ABSORPTION SPECTROSCOPY; BORON; BORON COMPOUNDS; CARBOXYLIC ACIDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; HEXANE; LIGANDS; MOLYBDENUM; MOLYBDENUM COMPOUNDS; PARAMAGNETIC RESONANCE; PARAMAGNETISM; RESONANCE; TRANSITION METAL COMPOUNDS; TUNGSTEN;

TUNGSTEN COMPOUNDS;

BORON; LIGAND; METAL COMPLEX; MOLYBDENUM;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONJUGATION; CRYSTALLOGRAPHY; ELECTROCHEMISTRY; PHASE TRANSITION; SYNTHESIS;

EID: 79954493005     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja109522b     Document Type: Article

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