Synthesis, characterization of hetero-bimetallic complex and application in the polymerization of ε-caprolactone

Inorganic Chemistry Communications

Volumn 14, Issue 5, 2011, Pages 763-766

  Pan, Xiaobo ^a,b   Liu, Ai ^b   Yao, Lihui ^b   Wang, Lei ^b   Zhang, Jinfeng ^b   Wu, Jincai ^b   Zhao, Xuebo ^a   Lin, Chu Chieh ^c  

^a QINGDAO INSTITUTE OF BIOENERGY AND BIOPROCESS TECHNOLOGY   (China)

^b LANZHOU UNIVERSITY   (China)

^c NATIONAL CHUNG HSING UNIVERSITY   (Taiwan)

Author keywords

Caprolactone; Catalyst; Hetero bimetallic complex; Ring opening polymerization

Indexed keywords

EID: 79954422648     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.03.003     Document Type: Article

References (29)

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29. A typical procedure of the polymerization: Compared to complex 1, it does use additional one equiv. BnOH as an initiator for complexes 2 and 3, and other reaction conditions same to complex 1. While complex 4 does not use additional BnOH as an initiator in ROP of ε-caprolactone with same reaction conditions to complex 1. The final experimental results show complexes 2-4 are not efficient catalyst for ROP of ε-caprolactone.