Self-assembly of a 2D helical coordination polymer from Keggin-type polyoxoanion and metal-organic fragment by in situ ligand transformation

Inorganic Chemistry Communications

Volumn 14, Issue 5, 2011, Pages 745-748

  Wang, Xiu Li ^a   Gao, Qiang ^a   Liu, Guo Cheng ^a   Lin, Hong Yan ^a   Tian, Ai Xiang ^a   Li, Jin ^a  

^a BOHAI UNIVERSITY   (China)

Author keywords

Coordination polymer; Crystal structure; Helical; In situ ligand transformation; Polyoxometalate

Indexed keywords

EID: 79954416947     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2011.02.026     Document Type: Article

References (37)

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36. Electrochemical measurements were performed with a CHI 440 electrochemical workstation connected to a Digital-586 personal computer. A conventional three-electrode cell was used at room temperature. The modified electrode was used as working electrode. A SCE and a platinum wire were used as reference and auxiliary electrodes, respectively. Complex 1 bulk-modified carbon paste electrode (1-CPE) was fabricated as follows: 500 mg of graphite powder and 30 mg of 1 were mixed and ground together by an agate mortar and pestle to achieve a uniform mixture, and then 0.15 mL of Nujol was added with stirring. The homogenized mixture was packed into a glass tube with a 3 mm inner diameter, and the tube surface was wiped with weighing paper. Electrical contact was established with a copper rod through the back of the electrode. The same procedure was used for preparation of bare CPE without compound 1.
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