Real-time observation of the self-assembly of hybrid polyoxometalates using mass spectrometry

Angewandte Chemie - International Edition

Volumn 50, Issue 16, 2011, Pages 3720-3724

  Wilson, Elizabeth F ^a,b   Miras, Haralampos N ^a   Rosnes, Mali H ^a   Cronin, Leroy ^a  

^a UNIVERSITY OF GLASGOW   (United Kingdom)

^b UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

Manganese; Mass spectrometry; Polyoxometalates; Self assembly

Indexed keywords

ANDERSONS; ELECTROSPRAY IONIZATION MASS SPECTROMETRY; ORGANIC-INORGANIC; POLYOXOMETALATES; REAL-TIME OBSERVATION; TRISHYDROXYMETHYLAMINOMETHANE;

ELECTROSPRAY IONIZATION; HYBRID SYSTEMS; MANGANESE; MANGANESE COMPOUNDS; METHANOL; OXIDES; SELF ASSEMBLY;

MASS SPECTROMETRY;

EID: 79953708221     PISSN: 14337851     EISSN: 15213773     Source Type: Journal    
DOI: 10.1002/anie.201006938     Document Type: Article

References (50)

1. a) P. Gouzerh, A. Proust, Chem. Rev. 1998, 98, 77;
2. b) J. T. Rhule, C. L. Hill, D. A. Judd, Chem. Rev. 1998, 98, 327.
3. a) A. Müller, E. Beckmann, H. Bügge, M. Schmidtmann, A. Dress, Angew. Chem. 2002, 114, 1210;
4. Angew. Chem. Int. Ed. 2002, 41, 1162;
5. b) D.-L. Long, R. Tsunashima, L. Cronin, Angew. Chem. 2010, 122, 1780;
6. Angew. Chem. Int. Ed. 2010, 49, 1736.
7. a) D. E. Katsoulis, Chem. Rev. 1998, 98, 359;
8. b) T. Yamase, Chem. Rev. 1998, 98, 307;
9. c) I. V. Kozhevnikov, Chem. Rev. 1998, 98, 171.
10. J. T. Rhule, W. A. Neiwert, K. I. Hardcastle, B. T. Do, C. L. Hill, J. Am. Chem. Soc. 2001, 123, 12101.
11. a) H. D. Zeng, G. R. Newkome, C. L. Hill, Angew. Chem. 2000, 112, 1841;
12. Angew. Chem. Int. Ed. 2000, 39, 1771;
13. b) C. Streb, C. Ritchie, D.-L. Long, P. Kögerler, L. Cronin, Angew. Chem. 2007, 119, 7723;
14. Angew. Chem. Int. Ed. 2007, 46, 7579.
15. a) D.-L. Long, E. Burkholder, L. Cronin, Chem. Soc. Rev. 2007, 36, 105;
16. b) H. N. Miras,G. J. T. Cooper,D.-L. Long,H. Bögge,A. Müller, C. Streb, L. Cronin, Science 2010, 327, 72;
17. c) L. Xu, M. Lu, B. Xu, Y. Wei, Z. Peng, D. R. Powell, Angew. Chem. 2002, 114, 4303;
18. Angew. Chem. Int. Ed. 2002, 41, 4129.
19. a) B. Hasenknopf, R. Delmont, P. Herson, P. Gouzerh, Eur. J. Inorg. Chem. 2002, 1081;
20. b) P. R. Marcoux, B. Hasenknopf, J. Vaissermann, P. Gouzerh, Eur. J. Inorg. Chem. 2003, 2406.
21. a) Y. F. Song, H. Abbas, C. Ritchie, N. McMillian, D. L. Long, N. Gadegaard, L. Cronin, J. Mater. Chem. 2007, 17, 1903;
22. b) Y. F. Song, D. L. Long, L. Cronin, Angew. Chem. 2007, 119, 3974;
23. Angew. Chem. Int. Ed. 2007, 46, 3900;
24. c) Y. F. Song, D. L. Long, S. E. Kelly, L. Cronin, Inorg. Chem. 2008, 47, 9137.
25. a) M. I. Khan, Q. Chen, J. Zubieta, D. P. Goshorn, Inorg. Chem. 1992, 31, 1556;
26. b) Q. Chen, D. P. Goshorn, C. P. Scholes, X. L. Tan, J. Zubieta, J. Am. Chem. Soc. 1992, 114, 4667;
27. c) A. Müller, J. Meyer, H. Bögge, A. Stammler, A. Botar, Z. Anorg. Allg. Chem. 1995, 621, 1818.
28. a) Y. Q. Hou, C. L. Hill, J. Am. Chem. Soc. 1993, 115, 11823;
29. b) C. P. Pradeep, D.-L. Long, G. N. Newton, Y.-F. Song, L. Cronin, Angew. Chem. 2008, 120, 4460;
30. Angew. Chem. Int. Ed. 2008, 47, 4388.
31. A. J. Wilson, W. T. Robinson, C. J. Wilkins, Acta Crystallogr. Sect. C 1983, 39, 54.
32. a) L. Ma, S. C. Liu, J. Zubieta, Inorg. Chem. 1989, 28, 175;
33. b) S. C. Liu, L. D. Ma, D. Mcgowty, J. Zubieta, Polyhedron 1990, 9, 1541;
34. c) M. I. Khan, J. Zubieta, J. Am. Chem. Soc. 1992, 114, 10058.
35. A. Müller, J. Meyer, H. Bögge, A. Stammler, A. Botar, Chem. Eur. J. 1998, 4, 1388.
36. a) H. N. Miras, D.-L. Long, P. Kögerler, L. Cronin, Dalton Trans. 2008, 214;
37. b) H. N. Miras, D. J. Stone, E. J. L. McInnes, R. G. Raptis, P. Baran, G. I. Chilas, M. P. Sigalas, T. A. Kabanos, L. Cronin, Chem. Commun. 2008, 4703;
38. c) H. N. Miras, J. Yan, D.-L. Long, L. Cronin, Angew. Chem. 2008, 120, 8548;
39. Angew. Chem. Int. Ed. 2008, 47, 8420.
40. H. N. Miras, E. F. Wilson, L. Cronin, Chem. Commun. 2009, 1297.
41. E. F.Wilson, H. Abbas, B. J. Duncombe, C. Streb, D.-L. Long, L. Cronin, J. Am. Chem. Soc. 2008, 130, 13876.
42. W. Henderson, J. S. McIndoe, Mass Spectrometry of Inorganic and Organometallic Compounds, Wiley, Chichester, 2005.
43. Note that observation of reduced POM units at low mass could result from voltage effects (e.g. ion-transfer voltages and high collision energy voltage at low mass) utilized in the MS technique to investigate fragment ion species at low mass.
44. a) M. Bonchio, O. Bortolini, V. Conte, A. Sartorel, Eur. J. Inorg. Chem. 2003, 699;
45. b) D. K. Walanda, R. C. Burns, G. A. Lawrance, E. I. von Nagy-Felsobuki, J. Chem. Soc. Dalton Trans. 1999, 311.
46. a) J. Gun, A. Modestov, O. Lev, D. Saurenx, M. A. Vorotyntsev, R. Poli, Eur. J. Inorg. Chem. 2003, 482;
47. b) F. Sahureka, R. C. Burns, E. I. von Nagy-Felsobuki, Inorg. Chim. Acta 2002, 332, 7.
48. D. L. Long, C. Streb, Y. F. Song, S. Mitchell and L. Cronin, J. Am. Chem. Soc. 2008, 130, 1830-1832.
49. a) M. Filowitz, R. K. C. Ho, W. G. Klemperer, W. Shum, Inorg. Chem. 1979, 18, 93;
50. b) V.W. Day, M. F. Fredrich, W. G. Klemperer, W. Shum, J. Am. Chem. Soc. 1977, 99, 6146.