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This structure was earlier reported in. Data from the more recent structure, which gave a reduced R -factor, are included in Table 2
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(-)-Menthyl chloride is commercially available (Aldrich), and neomenthyl chloride was prepared by a literature method
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2-Menthene is commercially available (Aldrich), and 3-menthene was prepared by a literature method
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Reflux of neomenthyl tosylate with 4 equiv of LiCl in acetone provided a mixture of 3-menthene and neomenthol, which was used without further workup (ref 34). Neomenthyl tosylate was synthesized following the procedure from Treatment of (+)-neomenthol (Sigma-Aldrich) with butyllithium followed by tosyl chloride gave the desired tosylate in 60% yield.
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