[{(CO)5Cr}6Ge6]2-, a molecular organometallic derivative of the unknown zintl ion [Ge6]2-

Angewandte Chemie - International Edition

Volumn 37, Issue 12, 1998, Pages 1664-1666

  Kircher, Peter ^a   Huttner, Gottfried ^a   Heinze, Katja ^a   Renner, Gerd ^a  

^a UNIVERSITY OF HEIDELBERG   (Germany)

Author keywords

Carbonyl compounds; Chromium; Clusters; Germanium; Zintl ions

Indexed keywords

EID: 79953680828     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980703)37:12<1664::AID-ANIE1664>3.0.CO;2-6     Document Type: Article

References (25)

1. B. Schiemenz, G. Huttner, Angew. Chem. 1993, 105, 295-296; Angew. Chem. Int. Ed. Engl. 1993, 32, 297-298.
2. B. Schiemenz, G. Huttner, Angew. Chem. 1993, 105, 295-296; Angew. Chem. Int. Ed. Engl. 1993, 32, 297-298.
3. a) K. Wade, Adv. Inorg. Chem. Radiochem. 1976, 18, 1-66;
4. b) D. M. P. Mingos, R. L. Johnston, Struct. Bonding (Berlin) 1987, 68, 29-87, and references therein.
5. R. Schaeffer, Q. Johnson, G. S. Smith, Inorg. Chem. 1965, 4, 917-918.
6. J. D. Corbett, Struct. Bonding (Berlin) 1997, 87, 157-193, and references therein.
7. 6N: A. Simon, Coord. Chem. Rev. 1997, 163, 253-270, and references therein.
8. 5) is attributed to a different kind of interaction: O. T. Beachley, R. Blom, M. R. Churchill, K. Faegri, J. C. Fettinger, J. C. Pazik, L. Victoriano, Organometallics 1989, 8, 346-356.
9. P. Kircher, G. Huttner, K. Heinze, B. Schiemenz, L. Zsolnai, M. Büchner, A. Driess, Eur. J. Inorg. Chem., in press.
10. a) F. Ettel, G. Huttner, W. Imhof, J. Organomet. Chem. 1990, 397, 299-307;
11. b) F. Ettel, M. Schollenberger, B. Schiemenz, G. Huttner, L. Zsolnai, ibid. 1994, 476, 153-162.
12. -3. Further details of the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe, D-76344 Eggenstein-Leopoldshafen (Fax: (+49) 7247-808-666: E-mail: crysdata@fiz-karlsruhe.de) on quoting the depository number CSD-408093.
13. Structure solution and refinement: G. M. Sheldrick, SHELXS 86, Universität Göttingen, 1986; SHELXL 93, Universität Göttingen, 1993; graphical data processing: L. Zsolnai, G. Huttner, XPMA, Universität Heidelberg, 1998; http://www.rzuser.uni-heidelberg.de/~ v54/xpm.html.
14. Structure solution and refinement: G. M. Sheldrick, SHELXS 86, Universität Göttingen, 1986; SHELXL 93, Universität Göttingen, 1993; graphical data processing: L. Zsolnai, G. Huttner, XPMA, Universität Heidelberg, 1998; http://www.rzuser.uni-heidelberg.de/~ v54/xpm.html.
15. Structure solution and refinement: G. M. Sheldrick, SHELXS 86, Universität Göttingen, 1986; SHELXL 93, Universität Göttingen, 1993; graphical data processing: L. Zsolnai, G. Huttner, XPMA, Universität Heidelberg, 1998; http://www.rzuser.uni-heidelberg.de/~ v54/xpm.html.
16. a) P. Jutzi, W. Steiner, E. König, G. Huttner, A. Frank, U. Schubert, Chem. Ber. 1978, 111, 606-614;
17. b) A. Castel, P. Rivière, J. Satgé, M. Ahbala, J. Jaud, J. Organomet. Chem. 1986, 307, 205-218.
18. A. Sekiguchi, C. Kabuto, H. Sakurai, Angew. Chem. 1989, 101, 97-98; Angew. Chem. Int. Ed. Engl. 1989, 28, 55-56.
19. A. Sekiguchi, C. Kabuto, H. Sakurai, Angew. Chem. 1989, 101, 97-98; Angew. Chem. Int. Ed. Engl. 1989, 28, 55-56.
20. V. Queneau, S. C. Sevov, Angew. Chem. 1997, 109, 1818-1820; Angew. Chem. Int. Ed. Engl. 1997, 36, 1754-1756.
21. V. Queneau, S. C. Sevov, Angew. Chem. 1997, 109, 1818-1820; Angew. Chem. Int. Ed. Engl. 1997, 36, 1754-1756.
22. a) S. C. Critchlow, J. D. Corbett, J. Chem. Soc. Chem. Commun. 1981, 236-237;
23. b) T. F. Fässler, M. Hunziker, Inorg. Chem. 1994, 33, 5380-5381.
24. D. R. Gardner, J. C. Fettinger, B. W. Eichhorn, Angew. Chem. 1996, 108, 3032-3033; Angew. Chem. Int. Ed. Engl. 1996, 35, 2852-2853.
25. D. R. Gardner, J. C. Fettinger, B. W. Eichhorn, Angew. Chem. 1996, 108, 3032-3033; Angew. Chem. Int. Ed. Engl. 1996, 35, 2852-2853.