Ge4-9: A Deltahedral Zintl Ion Now Made in the Solid-State

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 16, 1997, Pages 1754-1756

  Queneau, Virginie ^a   Sevov, Slavi C ^a  

^a UNIVERSITY OF NOTRE DAME   (United States)

Author keywords

Caesium; Clusters; Germanium; Solid state structures; Zintl phases

Indexed keywords

EID: 0030870703     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199717541     Document Type: Article

References (29)

1. The use of triels, tetrels, and pentels or pnictogens has been suggested by the Commission of Nomenclature of Inorganic Chemistry in the Inorganic Chemistry Division of IUPAC: B. P. Block, W H. Powell, W. C. Fernelius Inorganic Chemical Nomenclature: Principles and Practice, American Chemical Society, Washington, DC, 1990, p. 24.
2. J. D. Corbett, Struct Bonding, (Berlin) 1997, 87, 157, and references therein.
3. J. D. Corbett, Chem. Rev. 1985, 85, 383, and references therein.
4. 2,2,2-crypt is an abbreviation for 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane.
5. W. L. Wilson, R. W Rudolph, L. L. Lohr, R. C. Taylor, P. Pyykkö, Inorg. Chem. 1986, 25, 1535, and references therein.
6. To the best of our knowledge there are no systematic studies on the precursor alloys. Kummer and Diehl (D. Kummer, L. Diehl, Angew. Chem. 1970, 82, 881; Angew. Chem. Int. Ed. Engl. 1970, 9, 895) report mixture of unidentified phases and metallic tin in a Na-Sn precursor.
7. To the best of our knowledge there are no systematic studies on the precursor alloys. Kummer and Diehl (D. Kummer, L. Diehl, Angew. Chem. 1970, 82, 881; Angew. Chem. Int. Ed. Engl. 1970, 9, 895) report mixture of unidentified phases and metallic tin in a Na-Sn precursor.
8. C. H. E. Belin, J. D. Corbett, A. Cisar, J. Am. Chem. Soc. 1977, 99, 7163.
9. B. W. Eichhorn, R. C. Haushalter, W. T. Pennington, J. Am. Chem. Soc. 1988, 110, 8704; B W. Eichhorn, R. C. Haushalter, J. Chem. Soc. Chem. Common. 1990, 937; B. Schiemenz, G. Huttner, Angew. Chem. 1993, 105, 295; Angew. Chem. Int. Ed. Engl. 1993, 32, 297; D. R. Gardner, J. C. Fettinger, B. W. Eichhorn, ibid. 1996, 108, 3032; Angew. Chem. Int. Ed. Engl. 1996, 35, 2852.
10. B. W. Eichhorn, R. C. Haushalter, W. T. Pennington, J. Am. Chem. Soc. 1988, 110, 8704; B W. Eichhorn, R. C. Haushalter, J. Chem. Soc. Chem. Common. 1990, 937; B. Schiemenz, G. Huttner, Angew. Chem. 1993, 105, 295; Angew. Chem. Int. Ed. Engl. 1993, 32, 297; D. R. Gardner, J. C. Fettinger, B. W. Eichhorn, ibid. 1996, 108, 3032; Angew. Chem. Int. Ed. Engl. 1996, 35, 2852.
11. B. W. Eichhorn, R. C. Haushalter, W. T. Pennington, J. Am. Chem. Soc. 1988, 110, 8704; B W. Eichhorn, R. C. Haushalter, J. Chem. Soc. Chem. Common. 1990, 937; B. Schiemenz, G. Huttner, Angew. Chem. 1993, 105, 295; Angew. Chem. Int. Ed. Engl. 1993, 32, 297; D. R. Gardner, J. C. Fettinger, B. W. Eichhorn, ibid. 1996, 108, 3032; Angew. Chem. Int. Ed. Engl. 1996, 35, 2852.
12. B. W. Eichhorn, R. C. Haushalter, W. T. Pennington, J. Am. Chem. Soc. 1988, 110, 8704; B W. Eichhorn, R. C. Haushalter, J. Chem. Soc. Chem. Common. 1990, 937; B. Schiemenz, G. Huttner, Angew. Chem. 1993, 105, 295; Angew. Chem. Int. Ed. Engl. 1993, 32, 297; D. R. Gardner, J. C. Fettinger, B. W. Eichhorn, ibid. 1996, 108, 3032; Angew. Chem. Int. Ed. Engl. 1996, 35, 2852.
13. B. W. Eichhorn, R. C. Haushalter, W. T. Pennington, J. Am. Chem. Soc. 1988, 110, 8704; B W. Eichhorn, R. C. Haushalter, J. Chem. Soc. Chem. Common. 1990, 937; B. Schiemenz, G. Huttner, Angew. Chem. 1993, 105, 295; Angew. Chem. Int. Ed. Engl. 1993, 32, 297; D. R. Gardner, J. C. Fettinger, B. W. Eichhorn, ibid. 1996, 108, 3032; Angew. Chem. Int. Ed. Engl. 1996, 35, 2852.
14. B. W. Eichhorn, R. C. Haushalter, W. T. Pennington, J. Am. Chem. Soc. 1988, 110, 8704; B W. Eichhorn, R. C. Haushalter, J. Chem. Soc. Chem. Common. 1990, 937; B. Schiemenz, G. Huttner, Angew. Chem. 1993, 105, 295; Angew. Chem. Int. Ed. Engl. 1993, 32, 297; D. R. Gardner, J. C. Fettinger, B. W. Eichhorn, ibid. 1996, 108, 3032; Angew. Chem. Int. Ed. Engl. 1996, 35, 2852.
15. F. Teixidor, M. L. Luetkens, Jr., R. W. Rudolph, J. Am. Chem. Soc. 1983, 105, 149.
16. The use of "neat" here (after J. D. Corbett in ref. [2]) is to distinguish solids made by solid-state reactions from "molecular" solids crystallized from solution.
17. 5 (P. A. Edwards, J. D. Corbett, Inorg. Chem. 1977, 16, 903), respectively.
18. 5 (P. A. Edwards, J. D. Corbett, Inorg. Chem. 1977, 16, 903), respectively.
19. 5 (P. A. Edwards, J. D. Corbett, Inorg. Chem. 1977, 16, 903), respectively.
20. 5 (P. A. Edwards, J. D. Corbett, Inorg. Chem. 1977, 16, 903), respectively.
21. K. Wade, Adv. Inorg. Chem. Radiochem. 1976, 18, 1.
22. T. F. Fässler, M. Hunziker, Z. Anorg. Allg. Chem. 1996, 622, 837; V. Angilella, C. Belin, J. Chem. Soc. Faraday Trans. 1991, 87, 203; C. Belin, H. Mercier, V. Angilella, New J. Chem. 1991, 15, 931; T. F. Fässler, M. Hunziker, Inorg. Chem. 1994, 33, 5380.
23. T. F. Fässler, M. Hunziker, Z. Anorg. Allg. Chem. 1996, 622, 837; V. Angilella, C. Belin, J. Chem. Soc. Faraday Trans. 1991, 87, 203; C. Belin, H. Mercier, V. Angilella, New J. Chem. 1991, 15, 931; T. F. Fässler, M. Hunziker, Inorg. Chem. 1994, 33, 5380.
24. T. F. Fässler, M. Hunziker, Z. Anorg. Allg. Chem. 1996, 622, 837; V. Angilella, C. Belin, J. Chem. Soc. Faraday Trans. 1991, 87, 203; C. Belin, H. Mercier, V. Angilella, New J. Chem. 1991, 15, 931; T. F. Fässler, M. Hunziker, Inorg. Chem. 1994, 33, 5380.
25. T. F. Fässler, M. Hunziker, Z. Anorg. Allg. Chem. 1996, 622, 837; V. Angilella, C. Belin, J. Chem. Soc. Faraday Trans. 1991, 87, 203; C. Belin, H. Mercier, V. Angilella, New J. Chem. 1991, 15, 931; T. F. Fässler, M. Hunziker, Inorg. Chem. 1994, 33, 5380.
26. M. E. Drits, V. F. Potemkin, L. L. Zusman, Inorg. Mater. 1982, 18, 969; A. N. Orlov, K. A. Chuntonov, L. Z. Melkhov, A. A. Semyannikov, Russ. Metall. 1987, 6, 176; In Binary Alloy Phase Diagrams (Ed: T. B. Massalski), ASM International, Materials Park, Ohio, 1990) the area of uncertainty is erroneously shown at the Ge-rich side rather than the Cs-rich side.
27. M. E. Drits, V. F. Potemkin, L. L. Zusman, Inorg. Mater. 1982, 18, 969; A. N. Orlov, K. A. Chuntonov, L. Z. Melkhov, A. A. Semyannikov, Russ. Metall. 1987, 6, 176; In Binary Alloy Phase Diagrams (Ed: T. B. Massalski), ASM International, Materials Park, Ohio, 1990) the area of uncertainty is erroneously shown at the Ge-rich side rather than the Cs-rich side.
28. M. E. Drits, V. F. Potemkin, L. L. Zusman, Inorg. Mater. 1982, 18, 969; A. N. Orlov, K. A. Chuntonov, L. Z. Melkhov, A. A. Semyannikov, Russ. Metall. 1987, 6, 176; In Binary Alloy Phase Diagrams (Ed: T. B. Massalski), ASM International, Materials Park, Ohio, 1990) the area of uncertainty is erroneously shown at the Ge-rich side rather than the Cs-rich side.
29. N. W. Ashcroft, D. N. Mermin, Solid State Physics, Holt, Reinhart and Wilson, Philadelphia, 1976, p. 649.