The presence of carbonic-dominant volatiles during the crystallization of sulfide-bearing mafic pegmatites in the North Roby zone, Lac des Iles Complex, Ontario

Economic Geology

Volumn 106, Issue 1, 2011, Pages 33-54

  Hanley, Jacob J ^a   Gladney, Evan R ^a  

^a SAINT MARY S UNIVERSITY   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS FLUIDS; BASE METALS; COARSE-GRAINED; CONFINING PRESSURES; CONSTRAIN CONDITION; FLUID INCLUSION; GABBROIC ROCKS; INTERGROWTH; ONTARIO; ONTARIO , CANADA; ORE METALS; PLATINUM GROUP ELEMENTS; QUARTZ CRYSTAL; REMOBILIZATION; TI OXIDES; TWO STAGE;

APATITE; BISMUTH; CRYSTALLIZATION; FLUIDS; GRANITE; MICA; MINERALOGY; PALLADIUM; PALLADIUM COMPOUNDS; PHOSPHATE MINERALS; PLATINUM; PLATINUM COMPOUNDS; PRECIPITATION (CHEMICAL); QUARTZ; SILICATE MINERALS; SINGLE CRYSTALS; TITANIUM COMPOUNDS;

TRANSPORT PROPERTIES;

BASE METAL; CARBONATE; CHEMICAL COMPOSITION; CRYSTALLIZATION; DIKE; ECONOMIC GEOLOGY; EMPLACEMENT; LABRADORITE; LIGAND; MAFIC ROCK; ORE DEPOSIT; PEGMATITE; PLATINUM GROUP ELEMENT; PYROXENE; QUARTZ; REMOBILIZATION; SULFIDE; VEIN (GEOLOGY);

CANADA; LAC DES ILES MINE; ONTARIO [CANADA];

EID: 79953319205     PISSN: 03610128     EISSN: None     Source Type: Journal    
DOI: 10.2113/econgeo.106.1.33     Document Type: Article

References (126)

1. 2 fluids at Mount Etna: Chemical Geology, v. 263, p. 37-50.
2. O2 on the Al-in-hornblende barometer: American Mineralogist, v. 80, p. 549-559.
3. Anderson, A.J., Clark, A.H., Ma, X.-P., Palmer, G.R., MacArthur, J.D., and Roedder, E., 1989, Proton-induced X-ray and gamma-ray emission analysis of unopened fluid inclusions: ECONOMIC GEOLOGY, v. 84, p. 924-939. (Pubitemid 20597432)
4. 2, Cl and gas in Plinian and ash flow bishop rhyolite: Geology, v. 17, p. 221-225.
5. O2 on the Al-in-hornblende barometer: American Mineralogist, v. 80, p. 549-559.
6. Bakker, R.J., 2003, Package FLUIDS 1: Computer programs for analysis of fluid inclusion data and for modelling bulk fluid properties: Chemical Geology, v. 194, p. 3-23.
7. 2O inclusions in natural quartz: Geochimica et Cosmochimica Acta, v. 55, p. 2215-2230.
8. Ballhaus, C., and Stumpfl, E.F., 1986, Sulfide and platinum mineralization in the Merensky reef: Evidence from fluid inclusions: Contributions to Mineralogy and Petrology, v. 94, p. 193-204.
9. 2-CO fluid inclusions in a composite peridotite xenolith: Implications for upper mantle oxygen fugacity: Contributions to Mineralogy and Petrology, v. 85, p. 1-13.
10. Bhanage, B.M., Ikushima, Y., Shirai, M., and Arai, M., 1999, Multiphasecatalysis using water-soluble metal complexes in supercritical carbon dioxide: Chemical Communications 1999, p. 1277-1278. (Pubitemid 29355444)
11. Blundy, J.D., and Holland, T.J.B., 1990, Calcic amphibole equilibria and a new amphibole-plagioclase geothermometer: Contributions to Mineralogy and Petrology, v. 104, p. 208-224.
12. 2O-NaCl solution: Geochimica et Cosmochimica Acta, v. 58, p. 1053-1063.
13. Boggs, S., Jr., Young-Ihn, K., Goles, G.G., Rusk, B.G., Krinsley, D., and Seyedolali, A., 2002, Is quartz cathodoluminescence color a reliable provenance tool? A quantitative examination: Journal of Sedimentary Research, v. 72, p. 408-415.
14. 2O on phase relations during crystallization of gabbros in the Kap Edvard Holm Complex, East Greenland: Journal of Petrology, v. 40, p. 1037-1064. (Pubitemid 29432714)
15. Brügmann, G.E., and Naldrett, A.J., 1989, Magma mixing and constitutional zone refining in the Lac des Iles Complex, Ontario: Genesis of platinum group element mineralization: ECONOMIC GEOLOGY, v. 84, p. 1557-1573.
16. - 1990, Origin of copper-nickel-platinum group element mineralization in the ultramafic part of the Lac des Iles Complex, Ontario: Geological Survey of Canada, Paper 90-IC, p. 293-303.
17. Burnham, C.W., 1979, The importance of volatile constituents, in Yoder, H.S., Jr., ed., The evolution of the igneous rocks: Princeton, Princeton University Press, p. 439-482.
18. Craw, D., and Norris, R.J., 1993, Grain boundary migration of water and carbon dioxide during uplift of garnet-zone Alpine Schist, New Zealand: Journal of Metamorphic Petrology, v. 11, p. 371-378. (Pubitemid 23392883)
19. Dixon, J.E., 1997, Degassing of alkalic basalts: American Mineralogist, v. 82, p. 368-378.
20. Drummond, S.E., and Palmer, D.A., 1986, Thermal decarboxylation of acetate: Part II: Boundary conditions for the role of acetate in the primary migration of natural gas and the transportation of metals in hydrothermal systems: Geochimica et Cosmochimica Acta, v. 50, p. 825-833.
21. 2 solubility in pure water and aqueous NaCl solutions from 273 to 533K and from 0 to 2,000 bar: Chemical Geology, v. 193, p. 257-271. (Pubitemid 35420207)
22. 2O system: I: Pure systems from 0° to 1,000°C and 0 to 8,000 bar: Geochimica et Cosmochimica Acta, v. 56, p. 2605-2617.
23. 2O system: II: Mixtures from 50° to 1,000°C and 0 to 1,000 bar: Geochimica et Cosmochimica Acta, v. 56, p. 2619-2631.
24. 2-: Marine Chemistry, v. 98, p. 131-139. (Pubitemid 43050952)
25. Dunning, G.R., 1979, The geology and platinum group mineralization of the Roby zone, Lac des Iles Complex, Northwestern Ontario: Unpublished M.Sc. thesis, Ottawa, Ontario, Carleton University, 129 p.
26. Ernst, W.G., and Liu, J., 1998, Experimental phase equilibrium study of Al and Ti contents of calcic amphibole in MORB: A semiquantitative thermobarometer. American Mineralogist, v. 83, p. 952-969. (Pubitemid 29112223)
27. Flynn, R.T., and Burnham, C.W., 1978, An experimental determination of rare earth partition coefficients between a chloride containing vapor phase and silicate melts: Geochimica et Cosmochimica Acta, v. 42, p. 685-701.
28. 2 as determined with the use of synthetic fluid inclusions in conjunction with mass spectrometry: Chemical Geology, v. 98, p. 237-255.
29. Gaetani, G.A., Grove, T.L., and Bryan, W.B., 1994, Experimental phase relations of basaltic andesite from Hole 839B under hydrous and anhydrous conditions: Ocean Drilling Program, Scientific Results 135, p. 557-563.
30. 4-rich fluid inclusions in alkaline rocks: Journal of Volcanology and Geothermal Research, v. 8, p. 177-189.
31. Giggenbach, W.F., 1997, The origin and evolution of fluids in magmatic-hydrothermal systems: 3rd edition, in Barnes, H.L. ed., Geochemistry of hydrothermal ore deposits: New York, John Wiley and Sons, p. 737-796.
32. Giordano, T.H., 2002, Transport of Pb and zn by carboxylate complexes in basinal ore fluids and related petroleum-field brines at 100°C: The influence of pH and oxygen fugacity: Geochemical Transactions 3:56.
33. Glebovitsky, V.A., Semenov, V.S., Belyatsky, B.V., Koptev-Dvornikov, E.V., Pchelintseva, N.F., Kireev, B.S., and Koltsov, A.B., 2001, The structure of the Lukkulaisvaara intrusion, Oulanka group, northern Karelia: petrological implications: Canadian Mineralogist, v. 39, p. 607-637. (Pubitemid 32774385)
34. 2: Gold Bulletin, v. 32, p. 52-58.
35. Götze, J., 2009, Chemistry, textures and physical properties of quartz-geological interpretation and technical application: Mineralogical Magazine, v. 73, p. 645-671.
36. Guillong, M., Meier, D.L., Allan, M.M., Heinrich, C.A., and Yardley, B.W.D., 2008, SILLS: A MATLAB-based program for the reduction of laser ablation ICP-MS data of homogeneous materials and inclusions: Mineralogical Association of Canada Short Course, v. 40, p. 328-333.
37. Günther, D., Audétat, A., Frischknecht, R., and Heinrich, C.A., 1998, Quantitative analysis of major, minor, and trace elements in fluid inclusions using laser ablation inductively coupled plasma mass spectrometry: Journal of Analytical Atomic Spectrometry, v. 13, p. 236-270.
38. Györyová, K. and Balek, V., 1993, Thermal stability of new zinc acetate-based complex compounds: Journal of Thermal Analysis, v. 40, p. 519-532.
39. Hanley, J.J., 2005, The aqueous geochemistry of the platinum-group elements (PGE) in surficial, low-T hydrothermal and high-T magmatic-hydrothermal environments: Mineralogical Association of Canada, Short Course Volume, v. 35, p. 35-56.
40. - 2008, Salt melts, sulfide melts, and silicate melts: The origin of the Merensky reef and other platinum group element deposits in mafic magma systems: Oral presentation at the Gordon Conference on the Geochemistry of Ore Deposits, Lucca, Italy.
41. Hanley, J.J., Mungall, J.E., Pettke, T., Spooner, E.T.C., and Bray, C.J., 2005, Ore metal redistribution by hydrocarbon-brine and hydrocarbon-halide melt phases, North Range footwall of the Sudbury Igneous Complex, Ontario, Canada: Mineralium Deposita, v. 40, p. 237-256. (Pubitemid 41645413)
42. - 2008, Fluid and melt inclusions of magmatic origin in the ultramafic and lower banded series, Stillwater Complex, Montana, U.S.A.: Journal of Petrology, v. 49, p. 1133-1160.
43. Heinrich, C.A., Ryan, C.G., Mernagh, T.P., and Eadington, P.J., 1992, Segregation of ore metals between magmatic brine and vapor: A fluid inclusion study using PIXE microanalysis: ECONOMIC GEOLOGY, v. 87, p. 1566-1583. (Pubitemid 23390816)
44. Heinrich, C.A., Günther, D., Audétat, A., Ulrich, T., and Frischknecht, R., 1999, Metal fractionation between magmatic brine and vapor, determined by microanalysis of fluid inclusions: Geology, v. 27, p. 755-758. (Pubitemid 30005589)
45. H2O = 5 kb: Part II: Melt compositions: Journal of Petrology, v. 17, p. 139-193.
46. 4 below 50°C and 100 bar: Application to fluid inclusions: Proceedings of the Academy of Sciences (Paris), v. 294, p. 203-206.
47. Higgins, N.C., 1980, Fluid inclusion evidence for the transport of tungsten by carbonate complexes in hydrothermal solutions: Canadian Journal of Earth Sciences, v. 17, p. 823-830. (Pubitemid 11440463)
48. Hinchey, J.G., and Hattori, K.H., 2005, Magmatic mineralization and hydrothermal enrichment of the high-grade zone at the Lac des Iles Palladium mine, northern Ontario, Canada: Mineralium Deposita, v. 40, p. 13-23. (Pubitemid 41001533)
49. - 2007, Lead isotope study of the late Archean Lac des Iles palladium deposit, Canada: enrichment of platinum group elements by ponded sulfide melt: Mineralium Deposita, v. 42, p. 1432-1866.
50. Hinchey, J.G., Hattori, K.H., and Lavigne, M.J., 2005, Geology, petrology, and controls on PGE mineralization of the southern Roby and Twilight zones, Lac des Iles Mine, Canada. ECONOMIC GEOLOGY, v. 100, p. 43-61. (Pubitemid 40599488)
51. 2O during crystal-plastic deformation: Journal of Structural Geology, v. 12, p. 895-901.
52. 2 solubility: Geological Society of America Bulletin, v. 87, p. 1513-1518.
53. Holloway, J.R., and Blank, J.G., 1994, Application of experimental results to C-O-H species in natural melts: Mineralogical Society of America Reviews in Mineralogy, v. 30, p. 187-230.
54. Hummel, W., and Curti, E., 2003, Nickel aqueous speciation and solubility at ambient conditions: A thermodynamic elegy: Monatshefte für Chemie, v. 134, p. 941-973. (Pubitemid 38005198)
55. Huraiová, M., Dubessy, J., and Konečný, P., 1991, Composition and oxidation state of upper mantle fluids from southern Slovakia: Plinius, v. 5, p. 110-111.
56. 2 fluid inclusions during grain-boundary migration: Journal of Metamorphic Petrology, v. 13, p. 239-249.
57. 2-NaCl fluid at high pressures and temperatures: Geochimica et Cosmochimica Acta, v. 57, p. 733-746. (Pubitemid 23389983)
58. Keppler, H., and Wyllie, P.J., 1990, Role of fluids in transport and fractionation of uranium and thorium in magmatic processes: Nature, v. 348, p. 531-533. (Pubitemid 120015100)
59. Kharaka, Y.K, Carothers, W.W., and Rosenbauer, R.J., 1983, Thermal decarboxylation of acetic acid: Implications for the origin of natural gas: Geochimica et Cosmochimica Acta, v. 47, p. 397-402.
60. 2-only fluid inclusions in the Palaeoproterozoic Carara vein-quartz gold deposit, Ipitinga auriferous district, Southeast Guiana Shield, Brazil: Implications for orogenic gold mineralisation: Ore Geology Reviews, v. 37, p. 31-40.
61. Klemd, R., 1997, Comment on the paper by Schmidt Mumm et al.: High CO2 content of fluid inclusions in gold mineralisations in the Ashanti Belt, Ghana: A new category of ore forming fluids?: Mineralium Deposita, v. 33, p. 317-319.
62. (Mineralium Deposita, v. 32, p. 107-118)
63. Lambert, I.B., and Wyllie, P.J., 1972, Melting of gabbro (quartz eclogite) with excess water to 35 kilobars, with geological applications: Journal of Geology, v. 80, p. 693-708.
64. Lang, J.R., and Baker, T., 2001, Intrusion-related gold systems: The present level of understanding: Mineralium Deposita, v. 36, p. 477-489. (Pubitemid 32914268)
65. Larsen, R.B., Brooks, C.K., and Bird, D.K., 1992, Methane bearing aqueous saline solutions in the Skaergaard intrusion, East Greenland: Contributions to Mineralogy and Petrology, v. 112, p. 428-437. (Pubitemid 23389923)
66. Lechler, P.J., Arehart, G.B., and Knight, M., 2002, Multielement and isotopic geochemistry of the J-M reef, Stillwater intrusion, Montana: 9th International Platinum Symposium, Billings, Montana, 21-25 July 2002, Abstract with Program, p. 245-248.
67. Li, C., and Ripley, E.M., 2006, Formation of isoferroplatinum by desulfurization of braggite and cooperite in the J-M reef of the Stillwater Complex, Montana: Canadian Mineralogist, v. 44, p. 895-903. (Pubitemid 44382238)
68. Li, C., Ripley, E.M., Merino, E., and Maier, W.D., 2004, Replacement of base metal sulfides by actinolite, epidote, calcite, and magnetite in the UG2 and Merensky reef of the Bushveld Complex, South Africa: ECONOMIC GEOLOGY, v. 99, p. 173-184. (Pubitemid 38884208)
69. Lin, D.C.K., and Westmore, J.B., 1973, Mass spectral studies of binuclear metal complexes: Copper (I) carboxylates: Canadian Journal of Chemistry, v. 51, p. 2999-3005.
70. Linhardt, E., and Bues, C.C., 1987, Geology of the northern Lac des Iles Complex, district of Thunder Bay: Ontario Geological Survey, Miscellaneous Paper 137.
71. Liu, W., McPhail, D.C., and Brugger, J., 2001, An experimental study of copper (I)-chloride and copper (I)-acetate complexing in hydrothermal solutions between 50°C and 250°C and vapor-saturated pressure: Geochimica et Cosmochimica Acta, v. 65, p. 2937-2948. (Pubitemid 32931503)
72. Lowenstern, J.B., 1994, Dissolved volatile concentrations in an ore-forming magma: Geology, v. 22, p. 893-896.
73. - 2001, Carbon dioxide in magmas and implications for hydrothermal systems: Mineralium Deposita, v. 36, p. 490-502. (Pubitemid 32914269)
74. MacDonald, A.J., 1985, The Lac des Iles platinum group metals deposit, Thunder Bay district, Ontario: Ontario Geological Survey Miscellaneous Paper 126, p. 235-241.
75. Macdonald, A.J., Brugmann, G.E., and Naldrett, A.J., 1989, Preliminary results of investigations into magma mixing, fractionation and deuteric alteration during formation of PGE-rich Ni-Cu mineralization in the Lac des Iles gabbroic complex, Ontario, Canada, in Prendergast, M.D., and Jones, M.J., eds., Magmatic sulfides-the Zimbabwe volume: London, Institute of Mining and Metallurgy, p. 139-150.
76. Mathez, E.A, 1989, The nature of vapor associated with mafic magma and controls on its composition: Reviews in Economic Geology, v. 4, p. 21-31.
77. Mathez, E.A., and Waight, T.E., 2003, Lead isotopic disequilibrium between sulfide and plagioclase in the Bushveld Complex and the chemical evolution of large layered intrusions: Geochimica et Cosmochimica Acta, v. 67, p. 1875-1888. (Pubitemid 36678748)
78. Mathez, E.A., and Webster, J.D., 2005, Partitioning behavior of chlorine and fluorine in the system apaite-silicate melt-fluid: Geochimica et Cosmochimica Acta, v. 69, p. 1275-1286. (Pubitemid 40350716)
79. McCallum, I.S., Thurber, D.W., O'Brien, H.E., and Nelson, B.K., 1999, Lead isotopes in sulfides from the Stillwater Complex, Montana: Evidence for subsolidus remobilization: Contributions to Mineralogy and Petrology, v. 137, p. 206-219. (Pubitemid 30063544)
80. McCombe, D.A., Blakley, I.T., Routledge, R.E., and Cox, J.J., 2009, Technical report on the Lac des Iles mine, Thunder Bay, Ontario, Canada: Scott Wilson Roscoe Postle Associates Inc., 130 p.
81. Michaud, M.J., 1998, The geology, petrology, geochemistry and platinum group element-gold-copper-nickel ore assemblage of the Roby Zone, Lac des Iles Mafic-Ultramafic Complex, Northwestern Ontario. Unpublished M.Sc. thesis, Lakehead University, Ontario, 183 p.
82. Mond, L., Langer, K., and Quincke, F., 1890, Action of carbon monoxide on nickel: Journal of the Chemical Society, v. 57, p. 749-753.
83. 2 fluid inclusions at controlled hydrogen fugacities: Journal of Metamorphic Geology, v. 11, p. 155-164. (Pubitemid 23388008)
84. Müller, A., and Williamson, B.J., 2008, Cathodoluminescent quartz textures in transitional magmatic-hydrothermal systems: 33rd International Geological Congress, Oslo.
85. Naden, J., and Shepherd, T.J., 1989, Role of methane and carbon dioxide in gold deposition: Nature, v. 342, p. 793-795. (Pubitemid 20411304)
86. 2 solutions at deep crust-upper mantle pressures and temperatures: 2-15 kbar and 500°-900°C: Geochimica et Cosmochimica Acta, v. 64, p. 2993-3005.
87. Palmer, D.A., and Drummond, S.E., 1986, Thermal decarboxylation of acetate: Part I: The kinetics and mechanism of reaction in aqueous solution: Geochimica et Cosmochimica Acta, v. 50, p. 813-823.
88. Perisanu, S.T., 2001, Estimation of solubility of carbon dioxide in polar solvents: Journal of Solution Chemistry, v. 30, p. 183-192.
89. Pettke, T., Heinrich, C.A., Ciocan, A.C., and Günther, D., 2004, Quadrupole mass spectrometry and optical emission spectroscopy: Detection capabilities and representative sampling of short transient signals from laser ablation: Journal of Analytical Atomic Spectrometry, v. 9, p. 1149-1155.
90. Pokrovski, G.S., Borisova, A.Y., and Harrichoury, J.C., 2008, The effect of sulfur on vapor-liquid fractionation of metals in hydrothermal systems: Earth and Planetary Science Letters, v. 266, p. 345-362.
91. Pokrovski, G.S., Tagirov, B.R., Schott, J., Hazemann, J-L., and Proux, O., 2009, A new view on gold speciation in sulfur-bearing hydrothermal fluids from in situ X-ray absorption spectroscopy and quantum-chemical modeling: Geochimica et Cosmochimica Acta, v. 73, p. 5406-5427.
92. Polovina, J.S., Hudson, D.M., and Jones, R.E., 2004, Petrographic and geochemical characteristics of postmagmatic hydrothermal alteration and mineralization in the J-M reef, Stillwater Complex, Montana: Canadian Mineralogist, v. 42, p. 261-278.
93. Propp, W.A., Carleson, T.E., Wai, C.M., and Huang, S., 1996, Transport of metal sulfides in supercritical carbon dioxide: Idaho National Engineering Laboratory, for the U.S. Department of the Interior: U.S. Bureau of Mines and the U.S. Department of Energy, Technical Report INEL-96/-179, 23p.
94. Pudack, C., Halter, W. E., Heinrich C. A., and Pettke, T., 2009, Evolution of magmatic vapor to gold-rich epithermal liquid: The porphyry to epithermal transition at Nevados de Famatina, northwest Argentina: ECONOMIC GEOLOGY, v. 104, p. 449-477.
95. Pye, E.G., 1968, Geology of the Lac des Iles area: Ontario Department of Mines, Geological Report 64, 47 p.
96. Raveendran, P., Ikushima, Y., and Wallen, S.L., 2005, Polar attributes of super critical carbon dioxide: Accounts of Chemical Research, v. 38, p. 478-485. (Pubitemid 40994870)
97. Ripley, E.M., 2005, Re/Os isotopic and fluid inclusion studies of fluid-rock interaction in the contact aureole of the Duluth Complex, Minnesota:Geochimica et Cosmochimica Acta, v. 69, Supplemental 332.
98. 2O: Geochimica et Cosmochimica Acta, v. 54, p. 611-619.
99. 2 content of fluid inclusions in gold mineralisations in the Ashanti Belt, Ghana: a new category of ore forming fluids?: Mineralium Deposita, v. 32, p. 107-118.
100. Seo, J.H., Guillong, M., and Heinrich, C.A., 2009a, The role of sulfur in the formation of magmatic-hydrothermal copper-gold deposits: Earth and Planetary Science Letters, v. 282, p. 323-328.
101. - 2009b, Role of sulfur in hydrothermal metal fractionation and the formation of porphyry-type ore deposits: Goldschmidt Abstracts 2009, A1197.
102. rd ed., in Barnes, H.L., ed., Geochemistry of hydrothermal ore deposits: New York, Wiley, p. 435-477.
103. Shepherd, T.J., Rankin, A.H., and Alderton, D.H.M., 1985, A practical guideto fluid inclusions: Glasgow, Blackie Publishing, 239 p.
104. 2O in calc-alkaline differentiation and subduction zone magmatism: Contributions to Mineralogy and Petrology, v. 113, p. 143-166. (Pubitemid 23389918)
105. Somarin, A.K., Kissin, S.A., Heerema, D.D., and Bihari, D.J., 2009, Hydrothermal alteration, fluid inclusion and stable isotope studies of the North Roby zone, Lac des Iles PGE mine, Ontario, Canada: Resource Geology, v. 59, p. 107-120.
106. Sonnenthal, E.L., 1992, Geochemistry of dendritic anorthosites and associated petmatites in the Skaergaard intrusion, east Greenland-evidence for metasomatism by a chlorine-rich fluid: Journal of Volcanology and Geothermal Research, v. 52, p. 209-230. (Pubitemid 23386228)
107. 2O under vapor-saturated conditions: Geochimica et Cosmochimica Acta, v. 52, p. 989-1006.
108. Sutcliffe, R.R., and Sweeney, J.N., 1986, Precambrian geology of the Lac des Iles Complex, District of Thunder Bay: Ontario Geological Survey, Map 3047, scale 1:15840.
109. Taylor, H.P., and Forester, R.W., 1979, An oxygen and hydrogen isotope study of the Skaergaard intrusion and its country rocks: A description of a 55-m.y. old fossil hydrothermal system: Journal of Petrology, v. 20, p. 355-419.
110. Tellier, M.L., Brügmann, G.E., and Naldrett, A.J., 1991, Gabbro-hosted PGE mineralization in the Lac des Iles Complex: A geochemistry and fluid inclusions study: Geological Association Canada-Mineral Association of Canada-Society of Economic Geologists Joint Annual Meeting, Program with Abstracts 16, A123, p. 123.
111. Thomas, J.B., Watson, E.B., Spear, F.S., Shemella, P.T., Nayak, S.K., and Lanzirotti, A., 2009, TitaniQ under pressure: the effect of pressure and temperature on Ti-in-quartz solubility. Contributions to Mineralogy and Petrology, v. 160, p. 743-759.
112. Tomlinson, K.Y., Davis, D.W., Stone, D., and Hart, T., 2003, U-Pb age and Nd isotopic evidence for Archean terrane development and crustal recycling in the south-central Wabigoon subprovince, Canada: Contributions to Mineralogy and Petrology, v. 144, p. 684-702. (Pubitemid 36440340)
113. Tomlinson, K.Y., Stott, G.M., Percival, J.A., and Stone, D., 2004, Basement terranes and crustal recycling in the western Superior province: Nd isotopic character of granitoid and felsic volcanic rocks in the Wabigoon subprovince, northern Ontario, Canada: Precambrian Research, v. 132, p. 245-274. (Pubitemid 38987116)
114. 2 inclusions in Cretaceous quartz-stibnite veins hosted in lowgrade Variscan basement of the Western Carpathians, Slovakia: Mineralium Deposita, v. 40, p. 867-873. (Pubitemid 43280317)
115. Voicu, G., and Hallbauer, D.K., 2005, Determination of the physico-chemical characteristics of hydrothermal fluids from the postmetamorphic Omaigold deposit, Guiana Shield, using analysis of ionic species by crush-leach tecnique and capillary electrophoresis: Mineralogy and Petrology, v. 83, p. 243-270. (Pubitemid 40350770)
116. Walther, J.V., and Orville, P.M., 1983, The extraction-quench technique for determination of the thermodynamic properties of solute complexes: Application to quartz solubility in fluid mixtures: American Mineralogist, v. 68, p. 731-741.
117. Wark, D.A., and Watson, E.B., 2006, TitaniQ: A titanium-in-quartz geothermometer: Contributions to Mineralogy and Petrology, v. 152, p. 743-754. (Pubitemid 44741391)
118. Watkinson, D.H., and Dunning, G., 1979, Geology and platinum group mineralization, Lac-des-Iles Complex, northwestern Ontario: The Canadian Mineralogist, v. 17, p. 453-462.
119. Wood, S.A., 2002, The aqueous geochemistry of the platinum group elements with applications to ore deposits: Canadian Institute of Mining and Metallurgy, Special Volume 54, p. 211-249.
120. Wood, S.A., and Samson, I.M., 1998, Solubility of ore minerals and complexation of ore metals in hydrothermal solutions: Reviews in Economic Geology, v. 10, p. 33-80.
121. Wyllie, P.J., and Wolf, M.B., 1993, Amphibolite dehydration-melting: sorting out the solidus: London, Geological Society Special Publications, v. 76, p. 405-416. (Pubitemid 24422060)
122. Yoder, H.S., Jr., and Tilley, C.E., 1962, Origin of basaltic magma: An experimental study of natural and synthetic rock systems: Journal of Petrology, v. 3, p. 342-532.
123. Zajácz, Z., and Halter, W., 2009, Copper transport by high temperature, sulfur- rich magmatic vapor: Evidence from silicate melt and vapor inclusions in a basaltic andesite from the Villarrica volcano (Chile): Earth and Planetary Science Letters, v. 282, p. 115-121.
124. Zeng, Y., and Liu, J., 1999, Short-chain carboxylates in fluid inclusions in minerals: Applied Geochemistry, v. 15, p. 13-25.
125. 2O using synthetic fluid inclusions: Chemical Geology, v. 64, p. 335-350.
126. Zhu, C. and Sverjensky, D. A., 1992, F ± Cl ± OH partitioning between biotiteand apatite: Geochimica et Cosmochimica Acta, v. 56, p. 3435-3467.