Arsenic Eh-pH diagrams at 25°C and 1 bar

Environmental Earth Sciences

Volumn 62, Issue 8, 2011, Pages 1673-1683

  Lu, Peng ^a   Zhu, Chen ^a  

^a INDIANA UNIVERSITY   (United States)

Author keywords

Arsenic; Compilation; Eh pH diagrams

Indexed keywords

ARSENIC SPECIES; BARIUM ARSENATE; COMPILATION; DATA SETS; EH-PH DIAGRAMS; SCORODITE;

ARSENIC; BARIUM;

GRAPHIC METHODS;

ARSENIC; DATA SET; LITERATURE REVIEW; PH; THERMODYNAMICS;

EID: 79953163938     PISSN: 18666280     EISSN: 18666299     Source Type: Journal    
DOI: 10.1007/s12665-010-0652-x     Document Type: Article

References (55)

1. Allison JD, Brown DS, Novo-Gradac KJ (1991) MINTEQA2/PRODEFA2, a geochemical assessment model for environmental systems, version 3. 0 user's manual. U. S. Environmental Protection Agency Report EPA/600/3-91/021.
2. Amirbahman A, Kent DB, Curtis GP, Davis JA (2006) Kinetics of sorption and abiotic oxidation of arsenic(III) by aquifer materials. Geochim Cosmochim Acta 70: 533-547.
3. Ball JW, Nordstrom DK (1991) User's manual for WATEQ4F, with revised thermodynamic data base and test cases for calculating speciation of major, trace, and redox elements in natural waters. U. S. Geological Survey Open-File Report 91-183.
4. Bethke CM (2004) The Geochemist's Workbench, version 5. 0, GWB reference manual. Hydrogeology Program, University of Illinois.
5. Brookins DG (1986) Geochemical behavior of antimony, arsenic, cadmium and thallium: Eh-pH diagrams for 25°C, 1 bar pressure. Chem Geol 54: 271-278.
6. Brookins DG (1988) Eh-pH diagrams for geochemistry. Springer, Berlin.
7. Cherry JA, Shaikh AU, Tallman DE, Nicholson RV (1979) Arsenic species as an indicator of redox conditions in groundwater. J Hydrol 43: 373-392.
8. Christensen JJ, Eatough DJ, Izatt RM (1975) Handbook of metal ligand heats and related thermodynamic quantities, 2nd edn. Marcel Dekker, New York.
9. Chukhlantsev VG (1956) Solubility products of arsenates. J Inorganic Chem (USSR) 1: 1975-1982.
10. Craw D, Falconer D, Yongson JH (2003) Environmental arsenopyrite stability and dissolution: theory, experiment, and field observations. Chem Geol 179: 71-82.
11. 2O. Am Miner 70: 838-844.
12. Essington ME (1988) DIVISION S-2-SOIL CHEMISTRY-solubility of barium arsenate. Soil Sci Soc Am J 52: 1566-1570.
13. Ferguson JF, Gavis J (1972) A review of the arsenic cycle in natural waters. Water Res 6: 1259-1274.
14. Fukushi K, Sverjensky DA (2007) A predictive model (ETLM) for arsenate adsorption and surface speciation on oxides consistent with spectroscopic and theoretical molecular evidence. Geochim Cosmochim Acta 71: 3717-3745.
15. Garrels RM, Christ CL (1965) Minerals, solutions, and equilibria. Harper and Rowley, New York.
16. Hollibaugh JT, Carini S, Gurleyuk H, Jellison R, Joye SB, Lecleir G, Meile C, Vasquez L, Wallschlager D (2005) Arsenic speciation in Mono Lake, California: response to seasonal stratification and anoxia. Geochim Cosmochim Acta 69: 1925-1937.
17. Keimowitz AR, Zheng Y, Chillrud SN, Mailloux B, Jung HB, Stute M, Simpson HJ (2005) Arsenic redistribution between sediments and water near a highly contaminated source. Environ Sci Technol 39: 8606-8613.
18. 2O: new data and further discussion. Am Miner 73: 850-854.
19. Krauskopf KB, Bird DK (1995) Introduction to geochemistry. McGraw-Hill, New York.
20. Langmuir D (1979) Techniques of estimating thermodynamic properties for some aqueous complexes of geochemical interest. In: Jenne EA (ed) Chemical modeling in aqueous systems: speciation, sorption, solubility, and kinetics. ACS Symp. Ser. 93. American Chemical Society, Washington, pp 353-387.
21. 2O) and their application to arsenic behavior in buried mine tailings. Geochim Cosmochim Acta 70: 2942-2956.
22. Lindberg RD, Runnells DD (1984) Ground water redox reactions: an analysis of equilibrium state applied to Eh measurements and geochemical modeling. Science 225: 925-927.
23. Marini L, Accornero M (2007) Prediction of the thermodynamic properties of metal-arsenate and metal-arsenite aqueous complexes to high temperatures and pressures and some geological consequences. Environ Geol 52: 1343-1363.
24. Naumov GB, Ryzhenko BN, Khodakovsky IL (1974) Handbook of thermodynamic data. U. S. Geological Survey, Reston.
25. Nordstrom DK, Archer DG (2002) Arsenic thermodynamic data and environmental geochemistry. In: Welch AH, Stollenwerk KG (eds) Arsenic in ground water. Springer, Berlin.
26. Oremland RS, Stolz JF (2003) The ecology of arsenic. Science 300: 939-944.
27. Plant JA, Kinniburgh DG, Smedley PL, Fordyce FM, Klinck BA (2003) Arsenic and selenium. In: Lollar BS (ed) Environmental geochemistry. Elsevier, Amsterdam.
28. Pokrovski GS, Gout R, Zotov A, Schott J, Harrichoury JC (1996) Thermodynamic properties and stoichiometry of the arsenic (III) hydroxide complexes at hydrothermal conditions. Geochim Cosmochim Acta 60: 737-749.
29. Pokrovski GS, Kara S, Roux J (2002) Stability and solubility of arsenopyrite, FeAsS, in crustal fluids. Geochim Cosmochim Acta 66: 2361-2378.
30. Pourbaix M (1966) Atlas of electrochemical equilibria. Pergamon Press, Oxford.
31. Robie RA, Waldbaum DR (1968) Thermodynamic properties of minerals and related substances at 298. 15 K and one atmosphere pressure and at higher temperatures. Geological Survey Bulletin No. 1259. U. S. Department of the Interior.
32. 5 Pa) pressure and at higher temperatures. U. S. Geological Survey Bulletin 1452.
33. 2O: discussion. Am Miner 72: 842-844.
34. Robins RG (1990) The stability and solubility of ferric arsenate-an update. In: Gaskell DR (ed) EPD congress '90, TMS annual meeting.
35. Root RA, Vlassopoulos D, Rivera NA, Rafferty MT, Andrews C, O'day PA (2009) Speciation and natural attenuation of arsenic and iron in a tidally influenced shallow aquifer. Geochim Cosmochim Acta 73: 5528-5553.
36. Sergeyeva EI, Khodakovsky IL (1969) Physicochemical conditions of formation of native arsenic in hydrothermal deposits. Geochem Inter 7: 846-859.
37. Shock EL, Helgeson HC (1988) Calculation of the thermodynamic and transport properties of aqueous species at high pressure and temperature: correlation algorithm for ionic species and equation of state predictions to 5 kb and 1000°C. Geochim Cosmochim Acta 52: 2009-2036.
38. Shock EL, Sassani DC, Willis M, Sverjensky DA (1997) Inorganic species in geologic fluids: correlations among standard molal thermodynamic properties of aqueous ions and hydroxide complexes. Geochim Cosmochim Acta 61: 907-950.
39. Sillen LG, Martell AE (1964) Solubility constants. Spec. Publ. No. 17. The chemical society, London.
40. Smedley PL, Kinniburg DG (2002) A review of the source, behaviour and distribution of arsenic in natural waters. Appl Geochem 17: 517-568.
41. Stumm W, Morgan JJ (1996) Aquatic chemistry, chemical equilibria and rates in natural waters, 3rd edn. Wiley, New York, p 1022.
42. Sverjensky DA, Fukushi K (2006) A predictive model (ETLM) for As(III) adsorption and surface speciation on oxides consistent with spectroscopic data. Geochim Cosmochim Acta 70: 3778-3802.
43. Swartz CH, Blute NK, Badruzzman B, Ali A, Brabander D, Jay J, Besancon J, Islam S, Hemond HF, Harvey CF (2004) Mobility of arsenic in a Bangladesh aquifer: inferences from geochemical profiles, leaching data, and mineralogical characterization. Geochim Cosmochim Acta 68: 4539-4557.
44. Takeno N (2005) Atlas of Eh-pH diagrams. Intercomparison of thermodynamic databases. Geological Survey of Japan Open File Report No. 419.
45. Tamaki S, Frankenberger WTJ (1992) Environmental biochemistry of arsenic. Rev Environ Contam Toxicol 124: 79-110.
46. Turner RR (1981) Oxidation state of arsenic in coal ash leachate. Environ Sci Technol 15: 1062-1066.
47. Vink BW (1996) Stability relations of antimony and arsenic compounds in the light of revised and extended Eh-pH diagrams. Chem Geol 130: 21-30.
48. Wagemann R (1978) Some theoretical aspects of stability and solubility of inorganic arsenic in the freshwater environment. Water Res 12: 139-145.
49. Wagman DD, Evans WH, Parker VB, Schumm RH, Halow I, Bailey SM, Churney KL, Nuttall RL (1982) The NBS tables of chemical thermodynamic properties: selected values for inorganic and C-1 and C-2 organic-substances in SI units. J Phys Chem Ref Data 11: 1-390.
50. Whiting KS (1992) The thermodynamics and geochemistry of arsenic, with application to subsurface waters at the Sharon Steel Superfund Site at Midvale, Utah. MS Thesis, Colorado School of Mines, Golden, CO.
51. WHO (2001) Environmental Health Criteria 224: arsenic and arsenic compounds. World Health Organization, Geneva.
52. Wilson FH, Hawkins DB (1978) Arsenic in streams, stream sediments, and ground water, Fairbanks Area, Alaska. Environ Geol 2: 195-202.
53. Wolery TJ (1992) EQ3/6, A software package for geochemical modeling of aqueous systems: package overview and installation guide (version 7. 0). URCL-MA-110662-PT-I, Livermore, Calif., Univ. California, Lawrence Livermore Laboratory.
54. Zhu Y, Merkel BJ (2001) The dissolution and solubility, FeAsO4: 2H2O evaluation and simulation with PHREEQC2. Wiss. Mitt. Inst. Fur Geologie, TU Bergakedemie Freiberg, Germany 18: 1-12.
55. Zhu YN, Zhang XH, Xie QL, Chen YD, Wang DQ, Liang YP, Lu J (2005) Solubility and stability of barium arsenate and barium hydrogen arsenate at 25°C. J Hazard Mater 120: 37-44.