Thermodynamic properties and stoichiometry of As(III) hydroxide complexes at hydrothermal conditions

Geochimica et Cosmochimica Acta

Volumn 60, Issue 5, 1996, Pages 737-749

  Pokrovski, Gleb ^a   Gout, Robert ^a   Schott, Jacques ^a   Zotov, Alexandre ^a   Harrichoury, Jean Claude ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ARSENIC; COMPLEXATION; HYDROTHERMAL CONDITIONS; HYDROXIDE; STOICHIOMETRY; THERMODYNAMICS;

EID: 0029772179     PISSN: 00167037     EISSN: None     Source Type: Journal    
DOI: 10.1016/0016-7037(95)00427-0     Document Type: Article

References (65)

1. Akinfiev N. N. (1992) HELGESON: IBM Computer Code for Calculating the Thermodynamic Properties of Aqueous Species using the HKF-revised Equation of State. Moscow State Geological Prospecting Academy, Chemical Dept. (unpubl.).
2. Akinfiev N. N., Zotov A. V., and Nikonorov A. P. (1992) Thermodynamic analysis of equilibria in the system As(III)-S(II)-O-H. Geochim. Intl. 29, 109-121.
3. Anderson E. and Story L. (1923) Studies of certain physical properties of arsenic trioxide in water solution. J. Amer. Chem. Soc. 45, 1102-1105.
4. Baes C. F. and Mesmer R. E. (1976) The Hydrolysis of Cations. Wiley.
5. Ballantine J. M. and Moore J. N. (1988) Arsenic geochemistry in geothermal systems. Geochim. Cosmochim. Acta 52, 475-483.
6. Bancroft G. M. and Jean G. E. (1982) Gold deposition at low temperatures on sulfide minerals. Nature 298, 730-731.
7. Barton P. B., Jr. (1969) Thermochemical study of the system Fe-As-S. Geochim. Cosmochim. Acta 33, 841-867.
8. 6. J. Chem. Soc., 449-451.
9. Beezer A. E., Mortimer C. T., and Tyler E. G. (1965) Heats of formation and bond energies. Part XIII. Arsenic tribromide, arsenious and arsenic oxides, and aqueous solutions of sodium arsenite and sodium arsenate. J. Chem. Soc., 4471-4478.
10. Blachnik V. R., Hoppe A., and Wickel U. (1980) Die Systeme Arsen-Schwefel und Arsen-Selen und die thermodynamischen Daten ihrer Verbindungen. Z. Anorg. Alleg. Chem. 463, 78-90.
11. Boitard E., Pilard R., and Carpeni G. (1977) Etude des interactions soluté-soluté en solution aqueuse: les systèmes borique et arsénieux. J. Chim. Phys. 74, 890-895.
12. Boyle R. W. (1979) The geochemistry of gold and its deposits. Canada Geol. Survey Bull. 280.
13. 3) by high-temperature direct-synthesis calorimetry. J. Chem. Thermodyn. 20, 755-764.
14. Chang S. S. and Bestul A. B. (1971) Heat capacities of cubic, monoclinic, and vitreous arsenious oxide from 5 to 360 K. J. Chem. Phys. 55, 933-946.
15. Diakonov I., Pokrovski G. S., Schott J., Castet S., and Gout R. (1996) An experimental and computational study of sodium-aluminum complexing in crustal fluids. Geochim. Cosmochim. Acta 60, 197-211.
16. 3 from 25 to 90°C. Geochim. Cosmochim. Acta 56, 2267-2280.
17. Ellis A. J. and Mahon W. A. J. (1977) Chemistry and Geothermal Systems. Denton Academic Press.
18. Fein J. B., Hemley J. J., D'Angelo W. M., Komninou A., and Sverjensky D. A. (1992) Experimental study of iron-chloride complexing in hydrothermal fluids. Geochim. Cosmochim. Acta 56, 3179-3190.
19. Fritz J. and Shenk G. (1978) Quantitative Chemical Analysis. Moscow, MIR (in Russian).
20. Gout R., Pokrovski G., Schott J., and Zwick A. (1996) A Raman spectroscopy study of arsenic speciation in aqueous solutions to 275°C (in prep.).
21. 4, by electron diffraction. J. Amer. Chem. Soc. 60, 1814-1822.
22. Heinrich C. A. and Eadington P. J. (1986) Thermodynamic predictions of the hydrothermal chemistry of arsenic and their significance for the paragenetic sequence of some cassiterite-arsenopyrite-base metal sulfide deposits. Econ. Geol. 81, 511-529.
23. Helgeson H. C., Kirkham D. H., and Flowers G. S. (1981) Theoretical prediction of the thermodynamic behavior of aqueous electrolytes at high pressures and temperatures. IV: Calculation of activity coefficients, osmotic coefficients, and apparent molal and standard and relative partial molal properties to 600°C and 5 kb. Amer. J. Sci. 281, 1249-1516.
24. Heiz G. R., Tossel J. A., Charnock J. M., Pattrick R. A. D., Vaughan D. J., and Garner C. D. (1995) Oligomerization in As(III) sulfide solutions: Theoretical constraints and spectroscopic evidence. Geochim. Cosmochim. Acta 59, 4591-4604.
25. Hugi M. (1988) Die Quarze der Mineraliengrube Lengenbach (Binntal, VS) und ihre Einschlüsse. Unpubl. Ph.D. thesis, Univ. Bern.
26. Ivakin A. A., Vorob'eva S. V., Gertman E. M., and Voronova E. M. (1976) Acid-base equilibria and self-dissociation in solutions of arsenious acid. Zh. Neorg. Khim. 21, 442-448 (in Russian).
27. Jackson N. J., Halliday A. N., Sheppard S. M., and Mitchell J. G. (1982) Hydrothermal activity in the St. Just mining district, Cornwall, England. In Metallization Associated with Acid Magmatism (ed. A. M. Evans), pp. 137-179. Wiley.
28. Jackson K. J. and Helgeson H. C. (1985) Chemical and thermodynamic constraints on the hydrothermal transport and deposition of tin: I. Calculation of the solubility of cassiterite at high pressures and temperatures. Geochim. Cosmochim. Acta 49, 1-22.
29. 3. J. Chem. Thermodyn. 12, 545-557.
30. Johnson J. W., Oelkers E. H., and Helgeson H. C. (1992) SUPCRT92: A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species and reactions from 1 to 5000 bar and 0 to 1000°C. Comp. Geosci. 18, 899-947.
31. Kirschning H. J. and Plieth K. (1955) Electrochemische Bestimmung des Umwandlungspunktes der kubischen und monoklinen Arsenikmodifikationen. Z. Anorg. Alleg. Chem. 280, 346-352.
32. Kovalenker V. A., Levin K. A., Naumov V. B., Salazkin A. N., and Kabo A. E. (1994) Conditions of the formation of rich silver-arsenic ores at the Aktepe deposit (Central Tien-Shan). Geokhimia, 718-731 (in Russian).
33. Linke W. F. (1958) Solubilities of Inorganic and Metal-Organic Compounds, 4th ed., 1, pp. 234-240. ACS.
34. Loehr T. M. and Plane R. A. (1968) Raman spectra and structure of arsenious acid and arsenite in aqueous solution. J. Inorg. Chem. 7, 1708-1714.
35. Maier C. G. and Kelley K. K. (1932) An equation for the representation of high temperature heat content data. J. Amer. Chem. Soc. 54, 3243-3246.
36. Marczenko Z. (1986) Separation and Spectrophotometric Determination of Elements, Chap. 7; Arsenic, pp. 149-168. Ellis Horwood Ltd.
37. Marshall W. L. and Begun G. M. (1989) Raman spectroscopy of aqueous phosphate solutions at temperatures up to 450°C. J. Chem. Soc. Faraday Trans. 2, 85, 1963-1978.
38. Mironova G. D. and Zotov A. V. (1980) Solubility studies of the stability of As(III) sulfide complexes. Geochem. Intl. 17, 46-54.
39. Mironova G. D., Zotov A. V., and Gulko N. I. (1984) Determination of the solubility of orpiment in acid solutions at 25-150°C. Geochem. Intl. 21, 53-59.
40. Naumov G. B., Ryzhenko B. N., and Khodakovsky I. L. (1974) Handbook of Thermodynamic Data. USGS.
41. 4 in hydrothermal solutions using a new high temperature sodium selective electrode. Implications for boron isotopic fractionation. Chem. Geol. 124, 253-265.
42. 3 at 25 and 90°C. Geochim. Cosmochim. Acta 53, 255-267.
43. 5 Pascals) pressure and at higher temperatures. Bull. Geol. Survey 1452, 12-18.
44. Romanovski V. A. and Tarasov V. V. (1960) Low temperature heat capacity and entropy at 298.1K of the sulfides of the elements of the 5th group of the Periodic Table. Solid State Phys. 2, 1294 1299 (in Russian).
45. Roux J. and Beny C. (1989) Exploitation informatique des données obtenues par spectrométrie Raman. Géoraman-89 Contributions, p. 21.
46. Ruaya J. R. and Seward T. M. (1987) The ion-pair constant and other thermodynamic properties of HCl up to 350°C. Geochim. Cosmochim. Acta 51, 121-130.
47. Schott J. and Dandurand J.-L. (1987) Prediction of the thermodynamic behavior of aqueous silica in aqueous complex solutions at various temperatures. In Chemical Transport in Metasomatic Processes (ed. H. C. Helgeson), pp. 733-755. D. Reidel.
48. Schuhmann R. (1924) The free energy and heat content of arsenic trioxide and the reduction potential of arsenic. J. Amer. Chem. Soc. 46, 1444-1449.
49. Schulman J. H. and Schumb W. C. (1943) The polymorphism of arsenious oxide. J. Amer. Chem. Soc. 65, 878-883.
50. Sergeeva E. I., Naumov N. B., and Khodakovsky I. L. (1971) Conditions of the arsenic sulfides formation in hydrothermal deposits. In Geochemistry of Hydrothermal Ore Formation, pp. 210-222. Nauka (in Russian).
51. Seylar P. and Martin J.-M. (1989) Biogeochemical processes affecting arsenic species distribution in a permanently stratified lake. Environ. Sci. Technol. 23, 1258-1263.
52. Shock E. L., Helgeson H. C., and Sverjensky D. A. (1989) Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Standard partial molal properties of inorganic neutral species. Geochim. Cosmochim. Acta 53, 2157-2183.
53. Shvarov Yu. V. (1993) UT-HEL: IBM Computer Code for Calculating the HKF-revised Equation of State Parameters for Aqueous Species. Moscow State Univ. Geol. Dept. (unpubl.).
54. Sorokin V. I., Pokrovskii V. A., and Dadze T. P. (1988) Physical Chemical Conditions of the Sb-Hg Ore Formation. Nauka (in Russian).
55. Spycher N. F. and Reed M. H. (1989a) As(III) and Sb(III) sulfide complexes: an evaluation of stoichiometry and stability from existing experimental data. Geochim. Cosmochim. Acta 53, 2185-2194.
56. Spycher N. F. and Reed M. H. (1989b) Evolution of a Broadlands-type epithermal ore fluid along alternative P-T paths: Implications for the transport and deposition of base, precious, and volatile metals. Econ. Geol 84, 328-359.
57. Stranski I. N., Plieth K., and Zoll I. (1958) Über die Auflösung, die Loslichkeit und die Umwandlung der beiden Arsenik Modifikationen in Wasser und wäßrigen Lösungen. Zeit. Electrochem. 62, 366-372.
58. Suschevskaya T. M., Kokina T. A., Bannykh L. N., Sedykh E. M., and Knyazeva S. N. (1992) Arsenic in tin-bearing hydrothermal solutions (atomic absorption spectroscopic study of water extracts from inclusions in quartz. Geokhimia, 1007-1015 (in Russian).
59. Tanger J. C. and Helgeson H. C. (1988) Calculation of the thermodynamic and transport properties of aqueous species at high pressures and temperatures: Revised equations of state for the standard partial molal properties of ions and electrolytes. Amer. J. Sci. 288, 19-98.
60. Tservadze Z. Ya., Akevadze D. V., and Kucher M. I. (1977) Physico-chemical parameters of As ore formation (Example of the Luhumi and Codis-Dzirskoye deposits). In Geochemistry of Migration Processes of Ore Elements, pp. 139-156. Nauka (in Russian).
61. 2 organic substances in SI units. J. Phys. Chem. Ref. Data 11, suppl. 2, 77-78.
62. Walther J. V. and Schott J. (1988) The dielectric constant approach to speciation and ion pairing at high temperature and pressure. Nature 332, 635-638.
63. 3 and speciation of As in dilute and sulfide-bearing fluids at 25 and 90°C. Geochim. Cosmochim. Acta 54, 1009-1017.
64. 2O at 50-200°C and 100-1500 bars, with geological applications. Geochim. Cosmochim. Acta 30, 815-827.
65. Wu X. and Delbove F. (1989) Hydrothermal synthesis of gold-bearing arsenopyrite. Econ. Geol. 84, 2029-2032.