Pseudo-bimolecular [2+2] cycloaddition studied by time-resolved photoelectron spectroscopy

Chemistry - A European Journal

Volumn 17, Issue 14, 2011, Pages 3922-3931

  Brogaard, Rasmus Y ^a,c   Boguslavskiy, Andrey E ^a   Schalk, Oliver ^a   Enright, Gary D ^a   Hopf, Henning ^b   Raev, Vitaly A ^b   Jones, Peter G ^b   Thomsen, Ditte L ^c   Sølling, Theis I ^c   Stolow, Albert ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^b TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

^c UNIVERSITY OF COPENHAGEN   (Denmark)

Author keywords

ab initio calculations; cycloaddition; cyclophanes; photochemistry; photoelectron spectroscopy

Indexed keywords

[2 + 2] CYCLOADDITION; [2 + 2] PHOTOCYCLOADDITION; [2.2]PARACYCLOPHANE; AB INITIO CALCULATIONS; CONICAL INTERSECTION; CYCLOADDITION REACTION; CYCLOPHANES; FEMTOSECOND TIME-RESOLVED; GASPHASE; GROUND-STATE MOLECULES; MODEL SYSTEM; PHOTOCHEMISTRY; TIME-RESOLVED PHOTOELECTRON SPECTROSCOPY; VINYL GROUP; X RAY CRYSTALS;

CALCULATIONS; CYCLOADDITION; ELECTRONS; GROUND STATE; PHOTOELECTRICITY; PHOTONS; X RAY PHOTOELECTRON SPECTROSCOPY;

EXCITED STATES;

POLYCYCLIC HYDROCARBON; PSEUDO PARA DIVINYL(2.2)PARACYCLOPHANE; PSEUDO-PARA-DIVINYL(2.2)PARACYCLOPHANE; VINYL DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; CONFORMATION; CYCLIZATION; METHODOLOGY; QUANTUM THEORY; X RAY DIFFRACTION; X RAY PHOTOELECTRON SPECTROSCOPY;

CYCLIZATION; MODELS, MOLECULAR; MOLECULAR CONFORMATION; PHOTOELECTRON SPECTROSCOPY; POLYCYCLIC COMPOUNDS; QUANTUM THEORY; VINYL COMPOUNDS; X-RAY DIFFRACTION;

EID: 79952860549     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.201002928     Document Type: Article

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