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Volumn 115, Issue 5, 2011, Pages 2489-2496

Synthesis mechanism of alkali borohydrides by heterolytic diborane splitting

Author keywords

[No Author keywords available]

Indexed keywords

ALANATES; ALKALI HYDRIDES; BOROHYDRIDES; DIBORANE; DIBORANE GAS; H-BONDS; HETEROLYTIC SPLITTING; INFRARED SPECTROMETRY; ISOTOPE LABELING; MASS TRANSPORT; SOLID GAS REACTION; SYNTHESIS MECHANISM;

EID: 79952649874     PISSN: 19327447     EISSN: 19327455     Source Type: Journal    
DOI: 10.1021/jp107266d     Document Type: Article
Times cited : (9)

References (68)
  • 33
    • 79952632820 scopus 로고    scopus 로고
    • Relative intensity with respect to the corresponding LiD second-order peaks.
    • Relative intensity with respect to the corresponding LiD second-order peaks.
  • 37
    • 79952668420 scopus 로고    scopus 로고
    • note
    • 6) at 100 °C did not yield any evidence in the spectra for B-D or B-H bonds.
  • 54
    • 79952668092 scopus 로고    scopus 로고
    • note
    • + is not expected as a free species in the gas phase or at the surface of the solid at any time. The term recombination used here originates from the artificial splitting of the overall reaction into steps of known energy. The experimental observation of heterolytic splitting of diborane on a LiH surface is per se not sufficient to conclude on the charge transfer mechanism at hand.
  • 57
    • 79952664561 scopus 로고    scopus 로고
    • Although some heating is expected during ball-milling, the temperature does not exceed 50-80 °C. (68)
    • Although some heating is expected during ball-milling, the temperature does not exceed 50-80 °C. (68)


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.