Association of a cylindrical polyelectrolyte brush with tetravalent counterions

Macromolecular Rapid Communications

Volumn 32, Issue 6, 2011, Pages 523-527

  Ruthard, Christian ^b   Maskos, Michael ^c   Yildiz, Hakan ^a   Gröhn, Franziska ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

^b MAX PLANCK INSTITUTE FOR POLYMER RESEARCH   (Germany)

^c BAM FEDERAL INSTITUTE FOR MATERIALS RESEARCH AND TESTING   (Germany)

Author keywords

bottle brush; electrostatic interaction; macromonomers; polyelectrolytes; self assembly

Indexed keywords

AFM; AQUEOUS SOLUTIONS; CHARGE RATIO; CHARGED MONOMERS; CONFORMATION CHANGE; COUNTERIONS; CYLINDRICAL BRUSHES; ELECTROSTATIC INTERACTIONS; ELECTROSTATIC SELF ASSEMBLY; FINITE SIZE; HYDRODYNAMIC RADIUS; MACRO-MONOMERS; MOLAR CONCENTRATION; ORGANIC CATIONS; POLY(STYRENE SULFONATE); POLYELECTROLYTE BRUSHES; POLYMER BRUSHES; RADIUS OF GYRATION; SOFT MATTER; TETRAVALENT COUNTERIONS;

BOTTLES; CONFORMATIONS; CYLINDERS (SHAPES); ELECTROSTATIC SEPARATORS; ELECTROSTATICS; POLYELECTROLYTES; PORPHYRINS; SELF ASSEMBLY; SOLUTIONS; STOICHIOMETRY; STYRENE;

BRUSHES;

1,4 DIAZABICYCLO[2.2.2]OCTANE; ELECTROLYTE; PIPERAZINE DERIVATIVE; POLYSTYRENE DERIVATIVE; POLYSTYRENESULFONIC ACID;

CHEMISTRY; HYDRODYNAMICS; SURFACE PROPERTY;

ELECTROLYTES; HYDRODYNAMICS; PIPERAZINES; POLYSTYRENES; SURFACE PROPERTIES;

EID: 79952609306     PISSN: 10221336     EISSN: 15213927     Source Type: Journal    
DOI: 10.1002/marc.201000622     Document Type: Article

References (55)

1. D. E. Discher, A. Eisenberg, Science 2002, 297, 967.
2. M. Antonietti, S. Förster, Adv. Mater. 2003, 15, 1323.
3. D. J. Pochan, Z. Y. Chen, H. G. Cui, K. Hales, K. Qi, K. L. Wooley, Science 2004, 306, 94.
4. H. G. Börner, B. M. Smarsly, J. Hentschel, A. Rank, R. Schubert, Y. Geng, D. R. Discher, T. Hellweg, A. Brandt, Macromolecules 2008, 41, 1430.
5. S. Amajjahe, S. Choi, M. Munteanu, H. Ritter, Angew. Chem., Int. Ed. 2008, 47, 3435.
6. R. J. Murphy, D. Pristinski, K. Migler, J. F. Douglas, V. M. Prabhu, J. Chem. Phys. 2010, 132, 194903.
7. F. Gröhn, K. Klein, K. Koynov, Macromol. Rapid Commun. 2010, 31, 75.
8. M. Wintermantel, M. Schmidt, Y. Tsukahara, K. Kajiwara, S. Kohjiya, Macromol. Rapid Commun. 1994, 15, 279.
9. M. Wintermantel, M. Gerle, K. Fischer, M. Schmidt, I. Wataoka, H. Urakawa, K. Kajiwara, Y. Tsukahara, Macromolecules 1996, 29, 978.
10. P. Dziezok, S. S. Sheiko, K. Fischer, M. Schmidt, M. Möller, Angew. Chem., Int. Ed. 1997, 36, 2812.
11. M. Gerle, K. Fischer, S. Roos, A. H. E. Müller, M. Schmidt, S. S. Sheiko, S. Prokhorova, M. Möller, Macromolecules 1999, 32, 2629.
12. A. D. Schlüter, J. P. Rabe, Angew. Chem., Int. Ed. 2000, 39, 864.
13. G. L. Cheng, A. Boker, M. F. Zhang, G. Krausch, A. H. E. Müller, Macromolecules 2001, 34, 6883.
14. M. Zhang, A. H. E. Müller, J. Polym. Sci. A 2005, 43, 3461.
15. B. Zhang, F. Gröhn, J. S. Pedersen, K. Fischer, M. Schmidt, Macromolecules 2006, 39, 8440.
16. S. S. Sheiko, B. S. Sumerlin, K. Matyjaszewski, Prog. Polym. Sci. 2008, 33, 759.
17. H. Lee, J. Pietrasik, S. S. Sheiko, K. Matyjaszewski, Prog. Polym. Sci. 2010, 35, 24.
18. K. Fischer, M. Schmidt, Macromol. Rapid Commun. 2001, 22, 787.
19. T. Stephan, S. Muth, M. Schmidt, Macromolecules 2002, 35, 9857.
20. C. Li, N. Gunari, K. Fischer, A. Janshoff, M. Schmidt, Angew. Chem., Int. Ed. 2004, 43, 1101.
21. H. Lee, J. R. Boyce, A. Nese, S. S. Sheiko, K. Matyjaszewski, Polymer 2008, 49, 5490.
22. S. Yamamoto, J. Pietrasik, K. Matyjaszewski, Macromolecules 2008, 41, 7013.
23. A. F. Thünemann, M. Müller, H. Dautzenberg, J.-F. Joanny, H. Löwen, Adv. Polym. Sci. 2004, 166, 113.
24. G. Goerigk, K. Huber, R. Schweins, J. Chem. Phys. 2007, 127, 154908.
25. P. Loh, G. R. Deen, D. Vollmer, K. Fischer, M. Schmidt, M. Kundagrami, M. Muthukumar, Macromolecules 2008, 41, 9352.
26. U. H. Yildiz, K. Koynov, F. Gröhn, Macromol. Chem. Phys. 2009, 210, 1678.
27. M. Lemmers, J. Sprakel, I. K. Voets, J. Gucht, M. A. Cohen Stuart, Angew. Chem., Int. Ed. 2010, 49, 708.
28. I. Moreno-Villoslada, C. Torres-Gallegos, R. Araya-Hermosilla, H. Nishide, J. Phys. Chem. B 2010, 114, 4151.
29. M. Antonietti, J. Conrad, A. Thünemann, Macromolecules 1994, 27, 6007.
30. I. Koltover, T. Salditt, J. O. Rädler, C. R. Safinya, Science 1998, 281, 78.
31. A. F. Thünemann, J. Beyermann, Macromolecules 2000, 33, 6878.
32. S. Hanski, S. Junnila, L. Almasy, J. Ruokolainen, O. Ikkala, Macromolecules 2008, 41, 866.
33. J. Rühe, M. Ballauff, M. Biesalski, P. Dziezok, F. Gröhn, D. Johannsmann, N. Houbenov, N. Hugenberg, R. Konradi, S. Minko, M. Motornov, R. R. Netz, M. Schmidt, C. Seidel, M. Stamm, T. Stephan, D. Usov, H. N. Zhang, Adv. Polym. Sci. 2004, 165, 79; [33a] The combination of PSS brushes with divalent barium ions was first described on pp. 137-146 of ref. [33].
34. I. Gössl, L. Shu, A. D. Schlüter, J. P. Rabe, J. Am. Chem. Soc. 2002, 125, 6860.
35. D. Störkle, S. Duschner, N. Heimann, M. Maskos, M. Schmidt, Macromolecules 2007, 40, 7998.
36. K. Lienkamp, L. Noe, M.-H. Breniaux, I. Lieberwirth, F. Groehn, G. Wegner, Macromolecules 2007, 40, 2486.
37. Y. Y. Xu, S. Bolisetty, M. Drechsler, B. Fang, J. Y. Yuan, M. Ballauff, A. H. E. Müller, Polymer 2008, 49, 3957.
38. S. Duschner, D. Störkle, M. Schmidt, M. Maskos, Macromolecules 2008, 41, 9067.
39. A. Ossenbach, H. Rüegger, A. Zhang, K. Fischer, A. D. Schlüter, M. Schmidt, Macromolecules 2009, 42, 8781.
40. Y. Xu, O. V. Borisov, M. Ballauff, A. H. E. Müller, Langmuir 2010, 26, 6919.
41. I. Popa, B. Z. Zhang, P. Maroni, A. D. Schlüter, M. Borkovec, Angewandte Chemie Int. Ed. 2010, 49, 4250.
42. S. Duschner, F. Gröhn, M. Maskos, Polymer 2006, 47, 7391.
43. N. Gunari, Y. Cong, B. Zhang, K. Fischer, A. Janshoff, M. Schmidt, Macromol. Rapid Commun. 2008, 29, 821.
44. Y. Cong, N. Gunari, B. Zhang, K. Fischer, A. Janshoff, M. Schmidt, Langmuir 2009, 25, 6392.
45. Y. Xu, S. Bolisetty, M. Ballauf, A. H. E. Müller, J. Am Chem. Soc. 2009, 131, 1640.
46. Y. Xu, S. Bolisetty, M. Drechsler, B. Fang, J. Yuan, L. Harnau, M. Ballauff, A. H. E. Müller, Soft Matter 2009, 5, 379.
47. C. Ruthard, M. Maskos, U. Kolb, F. Gröhn, Macromolecules 2009, 42, 830.
48. F. Gröhn, K. Klein, S. Brand, Chem. Eur. J. 2008, 14, 6866.
49. F. Gröhn, Macromol. Chem. Phys. 2008, 209, 2295.
50. I. Willerich, H. Ritter, F. Gröhn, J. Phys. Chem. B 2009, 113, 3339.
51. F. Gröhn, Soft Matter 2010, 6, 4296.
52. Y. Li, U. H. Yildiz, K. Müllen, F. Gröhn, Biomacromolecules 2009, 10, 530.
53. [47]. As given by the synthetic route of macromonomer polymerization, the side chain length is very well defined ($\overline {M} -{{\rm w}} \overline {M} -{{\rm n}} $ = 1.06), the grafting density is 100% and the brush length shows a larger polydispersity.
54. L.-T. Yan, X. Zhang, X. Soft Matter 2009, 5, 2101.
55. L.-T. Yan, Y. Xu, M. Ballauff, A. H. E. Müller, A. Böker, J. Phys. Chem. B 2009, 113, 5104.