Thermodynamics of phase equilibria in aqueous strong electrolyte systems

Industrial and Engineering Chemistry Research

Volumn 50, Issue 6, 2011, Pages 3621-3631

  Li, Mi Yi ^a   Wang, Li Sheng ^a   Gmehling, Jürgen ^b  

^a BEIJING INSTITUTE OF TECHNOLOGY   (China)

^b UNIVERSITY OF OLDENBURG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

AQUEOUS ELECTROLYTE SYSTEMS; AQUEOUS SYSTEM; CONCENTRATION RANGES; DATA BANK; DORTMUND; EXPERIMENTAL DATA; GROUP CONTRIBUTION METHOD; HEAT CAPACITIES; LIQUAC MODEL; MEAN ION ACTIVITY COEFFICIENTS; NEW PARAMETERS; OSMOTIC COEFFICIENT; SALT SOLUBILITY; SOLUBILITY PRODUCT; STANDARD ENTHALPIES OF FORMATION; STANDARD GIBBS ENERGY; STRONG ELECTROLYTE; VAPOR-LIQUID EQUILIBRIUM;

BINARY MIXTURES; ELECTROLYTES; PHASE DIAGRAMS; SCHEMATIC DIAGRAMS; SOLUBILITY; TEMPERATURE; THERMODYNAMICS;

PHASE EQUILIBRIA;

EID: 79952605857     PISSN: 08885885     EISSN: 15205045     Source Type: Journal    
DOI: 10.1021/ie101428j     Document Type: Article

References (29)

1. E Model for Single and Mixed Solvent Electrolyte Systems. 1. Model and Results for Strong Electrolytes Fluid Phase Equilib. 1994, 94, 89
2. E Model for Single and Mixed Solvent Electrolyte Systems. 2. Results and Comparison with Other Models Fluid Phase Equilib. 1994, 94, 115
3. Dortmund Data Bank, version 2008; DDBST Software and Separation Technology GmbH: Oldenburg, Germany, 2008; www.ddbst.de.
4. Robinson, R. A.; Stokes, R. H. Electrolyte Solutions; 2nd ed., Butterworth: London, 1970.
5. Pitzer, K. S. Activity Coefficients in Electrolyte Solutions; 2nd ed.; CRC Press: Boca Raton, FL, 1991.
6. Barthel, J.; Krienke, H.; Kunz, W. Physical Chemistry of Electrolyte Solutions: Modern Aspects; Steinkopff/Springer: Darmstadt/New York, 1998.
7. Pitzer, K. S. Thermodynamics of Electrolytes. I: Theoretical and General Equations J. Phys. Chem. 1973, 77, 268
8. Blum, L. Mean spherical model for asymmetric electrolytes I. Method of solution Mol. Phys. 1975, 30, 1529
9. Henderson, D. Perturbation Theory, Ionic Fluids, and the Electric Double Layer ACS Advances in Chemistry Series 1983, 204, 47
10. Renon, H.; Cruz, J. L. A New Thermodynamic Representation of Binary Electrolyte Solutions Nonideality in the Whole Range of Concentrations AIChE J. 1978, 24, 817
11. Chen, C. C.; Britt, H. I.; Boston, J. F. Local Composition Model for Excess Gibbs Energy of Electrolyte Systems AIChE J. 1982, 28, 588
12. Sander, B.; Fredenslund, A. Calculation of Vapor-Liquid Equilibria in Mixed Solvent/Salt Systems using an Extended UNIQUAC Equation Chem. Eng. Sci. 1986, 41, 1171
13. Kikic, I. UNIFAC Prediction of Vapor-Liquid Equilibria in Mixed Solvent-Salt Systems Chem. Eng. Sci. 1991, 46, 2775
14. E Model for Single- and Mixed-Solvent Electrolyte Systems. 3. Prediction of Salt Solubilities in Aqueous Electrolyte Systems Ind. Eng. Chem. Res. 2005, 44, 1602
15. Huang, J.; Li, J.; Gmehling, J. Prediction of Solubilities of Salts, Osmotic Coefficients and Vapor-Liquid Equilibria for Single and Mixed Solvent Electrolyte Systems using the LIQUAC Model Fluid Phase Equilib. 2009, 275, 8
16. 2 organic Substances in SI Units. J. Phys. Chem. Ref. Data 1982, 11, suppl. no. 2.
17. Fowler, R. H.; Guggenheim, E. A. Statistical Thermodynamics; Cambridge University Press: Cambridge, U.K., 1949.
18. Yan, W.; Topphoff, M.; Rose, C.; Gmehling, J. Prediction of Vapor-Liquid Equilibria in Mixed-Solvent Electrolyte Systems using the Group Contribution Concept Fluid Phase Equilib. 1999, 162, 97
19. Mullin, J. W.; Crystallization; 3rd ed.; Butterworth: London, 1992.
20. Kiepe, J.; Noll, O.; Gmehling, J. Modified LIQUAC and Modified LIFAC-A Further Development of Electrolyte Models for the Reliable Prediction of Phase Equilibria with Strong Electrolytes Ind. Eng. Chem. Res. 2006, 45, 2361
21. 2O Fluid Phase Equilib. 2006, 250, 138
22. 2O System J. Chem. Eng. Data 2002, 47, 1331
23. Li, J.; Li, B.; Gao, S. Calculation of Thermodynamic Properties of hydrated Broates by Group Contribution Method Phys. Chem. Miner. 2000, 27, 342
24. Mostafa, A. T.; Eakman, J. M.; Yarbro, S. L. Prediction of Standard Heats and Gibbs Free Energies of Formation of Solid Inorganic Salts from Group Contributions Ind. Eng. Chem. Res. 1995, 34, 4577
25. Hamer, W. J.; Wu, Y.-C. Osmotic Coefficients and Mean Activity Coefficients of Uni-UniValent Electrolytes in Water at 25 °C J. Phys. Chem. Ref. Data 1972, 4, 1047
26. Patil, R.; Tripathi, A. D.; Pathak, G.; Katti, S. S. Thermodynamic Properties of Aqueous-Electrolyte Solutions. 1. Vapor-Pressure of Aqueous-Solutions of LiCl, LiBr, and LiI J. Chem. Eng. Data 1990, 35, 166
27. -1, and related properties J. Chem. Eng. Data 1974, 19, 281
28. Simonin, J. P.; Bernard, O.; Papaiconomou, N.; Kunz, W. Description of Dilution Enthalpies and Heat Capacities for Aqueous Solutions within the MSA-NRTL Model with Ion Solvation Fluid Phase Equlib. 2008, 264, 211
29. Robinson, R. A.; Wood, R. H.; Reilly, P. J. Calculation of Excess Gibbs Energies and Activity Coefficients from Isopiestic Measurements on Mixtures of Lithium and Sodium Salts J. Chem. Thermodyn. 1971, 3, 461