Calculation of thermodynamic properties of hydrated borates by group contribution method

Physics and Chemistry of Minerals

Volumn 27, Issue 5, 2000, Pages 342-346

  Li, J ^a   Li, B ^a   Gao, S ^a  

^a QINGHAI INSTITUTE OF SALT LAKES   (China)

Author keywords

Group contribution; Hydrated borates; Thermodynamic properties

Indexed keywords

BORATE; HYDRATION; THERMODYNAMICS;

EID: 0034085883     PISSN: 03421791     EISSN: None     Source Type: Journal    
DOI: 10.1007/s002690050263     Document Type: Article

References (24)

1. Bassett RL (1976) Ph D Dissertation, Stanford University
2. Benson SW, Cruickshank FR, Golden DM, Haugen GR, O'Neal HE, Rodgers AS, Shaw R, Walsh R (1969) Additivity rules for the estimation of thermochemical properties. Chem Rev 6: 279-324
3. f) of silicate minerals at 298 K from the sum of polyhedral contributions. Am Mineral 74: 1023-1031
4. Christ CL, Clark JR (1977) A crystal-chemical classification of borate structures with emphasis on hydrated borates. Phys Chem Miner 2: 59-87
5. Farmer JB (1982) Metal borates. In: Emelus HJ, Sharpe AG (eds) Advances in inorganic chemistry and radiochemistry, vol 25. Academic Press, London, pp 187-237
6. Gode H, Glybin V, Majore I, Sairko L (1981) Thermodynamic aspects of the borate rearrangement of metal borates containing mixed cations. Latv PSR Zinat Akad Vestis Khim Ser 5: 604-609
7. Gurevich VM, Sokolov VA (1976) Enthalpies of inyoite and colemanite formation. Geokhimiya 3: 455-457
8. Heller G (1986) A survey of structural types of borates and polyborates. In: Topics in current chemistry, vol 131. Springer, Berlin Heidelberg New York, pp 39-98
9. Hisham MWM, Benson SW (1985) Thermochemistry of inorganic solids. 5. Empirical relations among enthalpies of formation of oxides, carbonates, sulfates, hydroxides and nitrates. J Chem Eng Data 32: 243-247
10. Hisham MWM, Benson SW (1987) Thermochemistry of inorganic solids. 7. Empirical relations among enthalpies of formation of halides. J Phys Chem 91: 3631-3637
11. Hisham MWM, Benson SW (1988) Thermochemistry of inorganic solids. 8. Empirical relations among enthalpies of formation of different anionic compounds. J Phys Chem 92: 6107-6112
12. Holland TJB (1989) Dependence of entropy on volume for silicate and oxide minerals: a review and a predictive model. Am Mineral 74: 5-13
13. La Iglesa A, Felix JF (1994) Estimating of thermodynamic properties of mineral carbonates at high and low temperatures from the sum of polyhedral contributions. Geochim Cosmochim Acta 58: 3983-3991
14. Li J, Gao ShY, Xia ShP, Li B, Hu RZ (1997a) Thermochemistry of hydrated magnesium. J Chem Thermodyn 29: 491-497
15. Li J, Gao ShY, Xia ShP, Li B, Hu RZ (1997b) Thermochemistry of hydrated calcium. J Chem Thermodyn 29: 1071-1075
16. Li J, Li B, Gao ShY (1998a) Thermochemistry of hydrated potassium and sodium borates. J Chem Thermodyn 30: 425-430
17. Li J, Li B, Gao ShY (1998b) Thermochemistry of hydrated lithium borates. J Chem Thermodyn 30: 681-688
18. Mattigod SV (1983) A method for estimating the standard free energy of formation of borate minerals. Soil Sci Soc Am J 47: 654-655
19. Mostafa ATMG, Eakman JM, Yabro SL (1995) Prediction of standard heats and Gibbs free energies of formation of solid inorganic salts from group contributions. Ind Eng Chem Res 34: 4577-4582
20. Sposito G (1986) The polymer model of thermochemical clay mineral stability. Clays Clay Miner 34: 198-203
21. Vieillard Ph, Jenkins HDB (1986a) Empirical relationships for estimation of enthalpies of formation of simple hydrates. Part 1. Hydrates of alkali-metal cations, of hydrogen, and of monovalent cations. J Chem Res (S): 444-445
22. Vieillard Ph, Jenkins HDB (1986b) Empirical relationships for estimation of enthalpies of formation of simple hydrates. Part 2. Hydrates of alkaline-earth-metal cations. J Chem Res (S): 446-447
23. 2. J Chem Res (S): 448-449
24. 2 organic substances in SI units. J Phys Chem Ref Data 11, Suppl No 2