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Volumn 2, Issue 6, 2010, Pages 674-682

Phosphonite ligand design for nickel-catalyzed 2-methyl-3-butenenitrile isomerization and styrene hydrocyanation

Author keywords

Homogeneous catalysis; Hydrocyanation; Isomerization; Ligand design; Nickel

Indexed keywords


EID: 79952398322     PISSN: 18673880     EISSN: 18673899     Source Type: Journal    
DOI: 10.1002/cctc.201000022     Document Type: Article
Times cited : (30)

References (48)
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    • Diploma Thesis, University of Heidelberg.
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    • PhD Thesis, University of Heidelberg.
    • D. C. M. Warth, Ph D Thesis, University of Heidelberg, 2004;
    • (2004)
    • Warth, D.C.M.1
  • 20
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    • P. Hofmann, quot;New Catalysts for an Old Reaction: Towards Rational Ligand Design in Hydroformylation", invited lecture, 14th International Symposium on Homogeneous Catalysis, Munich, 2004, Abstract IL7.
    • P. Hofmann, "New Catalysts for an Old Reaction: Towards Rational Ligand Design in Hydroformylation", invited lecture, 14th International Symposium on Homogeneous Catalysis, Munich, 2004, Abstract IL7;
  • 21
    • 72449128543 scopus 로고    scopus 로고
    • Beginning in 2006, Gelman et al. reported a series of papers on the chemistry of P-dialkylphosphino derivatives of TTP (1). For related references see
    • Beginning in 2006, Gelman et al. reported a series of papers on the chemistry of P-dialkylphosphino derivatives of TTP (1). For related references see: C. Azerraf, D. Gelman, Organometallics 2009, 28, 6578-6584;
    • (2009) Organometallics , vol.28 , pp. 6578-6584
    • Azerraf, C.1    Gelman, D.2
  • 31
    • 79957756682 scopus 로고    scopus 로고
    • -1; 37417 reflections measured; 16344 unique reflections; R1=0.051 and wR2=0.123; GOF=1.03.
    • -1; 37417 reflections measured; 16344 unique reflections; R1=0.051 and w R2=0.123; GOF=1.03.
  • 32
    • 79957732099 scopus 로고    scopus 로고
    • -1; 41705 reflections measured; 16479 unique reflections; R1=0.061 and wR2=0.142; GOF=1.02.
    • -1; 41705 reflections measured; 16479 unique reflections; R1=0.061 and w R2=0.142; GOF=1.02.
  • 33
    • 79957712069 scopus 로고    scopus 로고
    • -1; 35753 reflections measured; 13880 unique reflections; R1=0.065 and wR2=0.183; GOF=1.00.
    • -1; 35753 reflections measured; 13880 unique reflections; R1=0.065 and w R2=0.183; GOF=1.00.
  • 39
    • 79957760942 scopus 로고    scopus 로고
    • As a referee pointed out, 2M3BN and t3PN in Table 1 sum up to more than 100% in the cases of 21 and 22. The data for ligands 21 and 22 were taken directly from the Du Pont patent cited. The peculiar fact that 2M3BN and t3PN sum up to more than 100% is due to a certain margin of error when using calibrated GC analysis with an internal standard (valeronitrile).
    • As a referee pointed out, 2M3BN and t3PN in Table 1 sum up to more than 100% in the cases of 21 and 22. The data for ligands 21 and 22 were taken directly from the Du Pont patent cited. The peculiar fact that 2M3BN and t3PN sum up to more than 100% is due to a certain margin of error when using calibrated GC analysis with an internal standard (valeronitrile).
  • 40
    • 79957746092 scopus 로고    scopus 로고
    • Conditions: Catalyst (0.8 mol%), ligand/nickel=1.3, acetone cyanohydrine/styrene=1.2, T=60°C, toluene, DEG as internal standard for calibrated GC-analysis.
    • Conditions: Catalyst (0.8 mol%), ligand/nickel=1.3, acetone cyanohydrine/styrene=1.2, T=60°C, toluene, DEG as internal standard for calibrated GC-analysis.
  • 47
    • 79957731490 scopus 로고    scopus 로고
    • G. M. Sheldrick, SADABS 2008/1, Bruker Analytical X-ray-Division, Madison, Wisconsin 2008.
    • G. M. Sheldrick, SADABS 2008/1, Bruker Analytical X-ray-Division, Madison, Wisconsin 2008.
  • 48
    • 37549039510 scopus 로고    scopus 로고
    • G. M. Sheldrick, SHELXTL 2008/4, Acta Crystallogr. 2008, A64, 112-122.
    • G. M. Sheldrick, SHELXTL 2008/4, Acta Crystallogr. 2008, A64, 112-122.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.