Microstructured reactors and supports for ionic liquids

Chemical Engineering Science

Volumn 66, Issue 7, 2011, Pages 1480-1489

  Kashid, M N ^a   Renken, A ^a   Kiwi Minsker, L ^a  

^a EPFL   (Switzerland)

Author keywords

Catalyst support; Chemical reactors; Ionic liquids; Microstructure; Multiphase reactors; Reaction engineering

Indexed keywords

CATALYTIC REACTIONS; CHEMICAL SYNTHESIS; CONVENTIONAL EQUIPMENT; GASPHASE; HEAT TRANSFER PERFORMANCE; HIGH TEMPERATURE; INTRINSIC KINETICS; LOW VISCOSITY; MICROSTRUCTURED MATERIALS; MICROSTRUCTURED REACTORS; MULTI-PHASE REACTOR; OPERATING CONDITION; PRODUCT SELECTIVITIES; REACTION ENGINEERING; REACTION MEDIA;

CATALYSIS; CATALYST SUPPORTS; CHEMICAL REACTORS; CHEMICALS; IONS; MICROSTRUCTURE; SYNTHESIS (CHEMICAL); VISCOSITY;

IONIC LIQUIDS;

EID: 79952313624     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2010.07.001     Document Type: Article

References (42)

1. Barkelew C.H. Stability of chemical reactors. A.I.Ch.E. Symposium Series 1959, 33:38-46.
2. Benaskar F., Hessel V., Kxtschil U., Lob P., Stark A. Intensification of the capillary-based Kolbe-Schmitt synthesis from resorcinol by reactive ionic liquids, microwave heating, or a combination thereof. Organic Process Research and Development 2009, 13(5):970-982.
3. Bilous O., Amundson N.R. Chemical reactor stability and sensitivity. AIChE Journal 1956, 2(17):117-126.
4. Falk L., Commenge J.-M. Characterization of mixing and segeregation in homgeneous flow systems. Micro Process Engineering 2009, Wiley-VCH, Weinheim. V. Hessel, A. Renken, J.C. Schouten, J. Yoshida (Eds.).
5. Fukuyama T., Rahman T., Sato M., Ryu I. Adventures in inner space: microflow systems for practical organic synthesis. Synlett 2008, 2:151-163.
6. Grosse Boewing A., Jess A. Kinetics of single-and two-phase sythesis of the ionic liquid 1-butyl-3-methylimidazolium chloride. Green Chemistry 2005, 7:230-235.
7. Grosse Böwing A., Jess A., Wasserscheid P. Kinetik und Reaktionstechnik der Synthese ionischer Flüssigkeiten. Chemie Ingenieur Technik 2005, 77(9):1430-1439.
8. Hagiwara R., Ito Y. Room temperature ionic liquids of alkylimidazolium cations and fluoroanions. Journal of Fluorine Chemistry 2000, 105(2):221-227.
9. Hessel V., Hofmann C., Löb P., Löhndorf J., Löwe H., Ziogas A. Aqueous Kolbe-Schmitt synthesis using resorcinol in a microreactor laboratory rig under high-p,T conditions. Organic Process Research and Development 2005, 9(4):479-489.
10. Hessel V., Löwe H., Schönfeld F. Micromixers-a review on passive and active mixing principles. Chemical Engineering Science 2005, 60(8-9):2479-2501. SPEC. ISS.
11. Holbrey J.D., Reichert W.M., Swatloski R.P., Broker G.A., Pitner W.R., Seddon K.R., Rogers R.D. Efficient, halide free synthesis of new, low cost ionic liquids: 1,3-dialkylimidazolium salts containing methyl- and ethyl-sulfate anions. Green Chemistry 2002, 4(5):407-413.
12. Horii D., Fuchigami T., Atobe M. A new approach to anodic substitution reaction using parallel laminar flow in a micro-flow reactor. Journal of the American Chemical Society 2007, 129(38):11692-11693.
13. Kashid M.N., Agar D.W., Renken A., Kiwi-Minsker L. Heterogeneous multiphase reactions. Micro Process Engineering 2009, Vol 1. Wiley-VCH, Weinheim.
14. Kirschning A., Solodenko W., Mennecke K. Combining enabling techniques in organic synthesis: continuous flow processes with heterogenized catalysts. Chemistry-a European Journal 2006, 12(23):5972-5990.
15. Kiwi-Minsker L., Renken A. Microstructured reactors for catalytic reactions. Catalysis Today 2005, 110(1-2):2-14.
16. Knight J.B., Vishwanath A., Brody L.P., Austin R.H. Hydrodynamic focussingon a silicon chip: mixing nanoliters in microseconds. Physical Review Letters 1998, 80(17):3863-3866.
17. Krtschil U., Hessel V., Reinhard D., Stark A. Flow chemistry of the Kolbe-Schmitt synthesis from resorcinol: process intensification by alternative solvents, new reagents and advanced reactor engineering. Chemical Engineering Technology 2009, 32(11):1774-1789.
18. Liu S., Fukuyama T., Sato M., Ryu I. Continuous microflow synthesis of butyl cinnamate by a Mizoroki-Heck reaction using a low-viscosity ionic liquid as the recycling reaction medium. Organic Process Research and Development 2004, 8(3):477-481.
19. Löwe H., Axinte R.D., Breuch D., Hofmann C. Heat pipe controlled syntheses of ionic liquids in microstructured reactors. Chemical Engineering Journal 2009.
20. Matatov-Meytal Y., Sheintuch M. Catalytic fibers and cloths. Applied Catalysis A: General 2002, 231(1-2):1-16.
21. 2007, Wiley-VCH, Weinheim. G.W. Meindersma, M. Maase, A.B.D. Haan (Eds.).
22. Mikkola J.P., Wärnå J., Virtanen P., Salmi T. Effect of internal diffusion in supported ionic liquid catalysts: interaction with kinetics. Industrial and Engineering Chemistry Research 2007, 46(12):3932-3940.
23. Pârvulescu V.I., Hardacre C. Catalysis in ionic liquids. Chemical Reviews 2007, 107(6):2615-2665.
24. Rahman M.T., Fukuyama T., Kamata N., Sato M., Ryu I. Low pressure Pd-catalyzed carbonylation in an ionic liquid using a multiphase microflow system. Chemical Communications 2006, 21:2236-2238.
25. Renken, A., 2006. Chemische Reaktoren und deren reaktionstechnische Modellierung. In: Baerns, M., Behr, A., Brehmet, A. et al. (Eds.), Technische Chemie. Wiley-VCH, Weiheim, pp. 152-153 (Chapter 5).
26. Renken A., Hessel V., Lob P., Miszczuk R., Uerdingen M., Kiwi-Minsker L. Ionic liquid synthesis in a microstructured reactor for process intensification. Chemical Engineering and Processing 2007, 46(9):840-845.
27. Riisager A., Fehrmann R., Flicker S., Van Hal R., Haumann M., Wasserscheid P. Very stable and highly regioselective supported ionic-liquid-phase (SILP) catalysis: continuous-flow fixed-bed hydroformylation of propene. Angewandte Chemie-International Edition 2005, 44(5):815-819.
28. Riisager A., Fehrmann R., Haumann M., Wasserscheid P. Supported ionic liquid phase (SILP) catalysis. An innovative concept for homogeneous catalysis in continuous fixed-bed reactors. European Journal of Inorganic Chemistry 2006, 4:695-706.
29. Ruta, M. (2008). Novel catalytic applications of carbon nanofibers on sintered metal fibers filter as structured support. Ph.D. Thesis, Ecole Polytechnique Fédérale de Lausanne.
30. Ruta M., Laurenczy G., Dyson P.J., Kiwi-Minsker L. Pd nanoparticles in a supported ionic liquid phase: highly stable catalysts for selective acetylene hydrogenation under continuous-flow conditions. Journal of Physical Chemistry C 2008, 112(46):17814-17819.
31. Ruta M., Yuranov I., Dyson P.J., Laurenczy G., Kiwi-Minsker L. Structured fiber supports for ionic liquid-phase catalysis used in gas-phase continuous hydrogenation. Journal of Catalysis 2007, 247(2):269-276.
32. Scott K., Basov N., Jachuck R.J.J., Winterton N., Cooper A., Davies C. Reactor studies of supported ionic liquids-rhodium-catalysed hydrogenation of propene. Chemical Engineering Research and Design 2005, 83(A10):1179-1185.
33. Re-engineering the Chemical Processing Plant 2004, Marcel Dekker, New York, Basel. A. Stankiewicz, J.A. Moulijn (Eds.).
34. Stark A., Huebschnann S., Sellin M., Kralisch D., Trotzki R., Ondruschka B. Microwave-assisted Kolbe-Schmitt synthesis using ionic-liquids or dimcarb as reactive solvents. Chemical Engineering Technology 2009, 32(11):1730-1738.
35. Virtanen P., Karhu H., Kordas K., Mikkola J.P. The effect of ionic liquid in supported ionic liquid catalysts (SILCA) in the hydrogenation of α, Β-unsaturated aldehydes. Chemical Engineering Science 2007, 62(14):3660-3671.
36. Virtanen P., Mikkola J.P., Salmi T. Kinetics of citral hydrogenation by supported ionic liquid catalysts (SILCA) for fine chemicals. Industrial and Engineering Chemistry Research 2007, 46(26):9022-9031.
37. Virtanen P., Mikkola J.P., Toukoniitty E., Karhu H., Kordas K., Eränen K., Wärnå J., Salmi T. Supported ionic liquid catalysts-from batch to continuous operation in preparation of fine chemicals. Catalysis Today 2009, 147(Suppl).
38. Wasserscheid P., Welton T. Ionic Liquids in Synthesis 2008, Wiley-VCH, Weinheim.
39. Waterkamp D.A., Engelbert M., Etöming J. On the effect of enhanced mass transfer on side reactions in capillary microreactors during high temperature synthesis of an ionic liquid. Chemical Engineering Technology 2009, 32(11):1717-1723.
40. Waterkamp D.A., Heiland M., Schlueter M., Sauvageau J.C., Beyersdorff T., Thoeming J. Synthesis of ionic liquids in micro-reactors-a process intensification study. Green Chemistry 2007, 9(10):1084-1090.
41. Wilms D., Klos J., Kilbinger A.F.M., Lowe H., Frey H. Ionic liquids on demand in continuous flow. Organic Process Research and Development 2009, 13(5):961-964.
42. Wu, Z., Nguyen N.-T., 2009. Passive and active micromixers. In: Hessel, V., Renken, A., Schouten, J.C., Yoshida, J. (Eds.), Micro Process Engineering. Wiley-VCH, Weinheim.