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Note that in supramolecular science occasionally chainlike entities embedded in the crystal lattice are denoted as polymers. They do not form chains beyond the lattice. By contrast, in this work distinct polymers are used as tectons.
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Note that in supramolecular science occasionally chainlike entities embedded in the crystal lattice are denoted as polymers. They do not form chains beyond the lattice. By contrast, in this work distinct polymers are used as tectons.
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Circular dichroism (CD) spectroscopy unfortunately cannot be applied for bulky solid samples, and hence it is not reliable for the present case.
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Circular dichroism (CD) spectroscopy unfortunately cannot be applied for bulky solid samples, and hence it is not reliable for the present case.
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Also PBLG is able to form β sheets, but only for short chain lengths of less than 20 units. Otherwise, the stabilization of the PBLG chains in the α-helical secondary conformation is typically observed.
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Also PBLG is able to form β sheets, but only for short chain lengths of less than 20 units. Otherwise, the stabilization of the PBLG chains in the α-helical secondary conformation is typically observed.
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47
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The calculated layer thickness is based on ideal PBLG helical structure, that is, a helix without kinks. Kinks can emerge along the helical rod, though, therefore PBLG can be slightly extended, and hence, PLL(dGMP) slightly reduced, thus keeping the total periodicity.
-
The calculated layer thickness is based on ideal PBLG helical structure, that is, a helix without kinks. Kinks can emerge along the helical rod, though, therefore PBLG can be slightly extended, and hence, PLL(dGMP) slightly reduced, thus keeping the total periodicity.
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