Icosahedral Pt-centered Pt13 and Pt19 carbonyl clusters decorated by [Cd5(μ-Br)5Br 5-x(solvent)x]x+ rings reminiscent of the decoration of Au-Fe-CO and Au-thiolate nanoclusters: A unifying approach to their electron counts

Journal of the American Chemical Society

Volumn 133, Issue 8, 2011, Pages 2406-2409

  Femoni, Cristina ^a   Iapalucci, Maria Carmela ^a   Longoni, Giuliano ^a   Zacchini, Stefano ^a   Zarra, Salvatore ^a  

^a UNIVERSITY OF BOLOGNA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL CLUSTERS; CO CLUSTERS; ELECTRON COUNT; GOOD YIELD; SURFACE DECORATION; THIOLATES;

CADMIUM COMPOUNDS; GOLD COMPOUNDS; NANOCLUSTERS; PLATINUM; X RAY DIFFRACTION;

PLATINUM COMPOUNDS;

BROMINE; CADMIUM; CARBONYL DERIVATIVE; COBALT; GOLD; IRON; PLATINUM; SOLVENT; WATER;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; CHEMICAL STRUCTURE; COVALENT BOND; ELECTRON; SURFACE PROPERTY; SYNTHESIS; X RAY DIFFRACTION;

CADMIUM; CARBON MONOXIDE; ELECTRONS; GOLD; IRON; MODELS, MOLECULAR; NANOSTRUCTURES; ORGANOMETALLIC COMPOUNDS; PLATINUM; SOLVENTS; SULFHYDRYL COMPOUNDS;

EID: 79952259534     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/ja111235v     Document Type: Article

References (40)

1. Stockhammer, A.; Dahmen, K.-H.; Gerfin, T.; Venanzi, L. M.; Gramlich, V.; Petter, W. Helv. Chim. Acta 1991, 74, 989
2. Femoni, C.; Iapalucci, M. C.; Longoni, G.; Ranuzzi, F.; Zacchini, S.; Fedi, S.; Zanello, P. Eur. J. Inorg. Chem. 2007, 4064
3. Femoni, C.; Kaswalder, F.; Iapalucci, M. C.; Longoni, G.; Zacchini, S. Chem. Commun. 2006, 2135
4. Bernardi, A.; Femoni, C.; Iapalucci, M. C.; Longoni, G.; Ranuzzi, F.; Zacchini, S.; Zanello, P.; Fedi, S. Chem.-Eur. J. 2008, 14, 1924
5. Bernardi, A.; Femoni, C.; Iapalucci, M. C.; Longoni, G.; Zacchini, S. Inorg. Chim. Acta 2009, 362, 1239
6. Bernardi, A.; Femoni, C.; Iapalucci, M. C.; Longoni, G.; Zacchini, S. Dalton Trans. 2009, 4245
7. Bernardi, A.; Femoni, C.; Iapalucci, M. C.; Longoni, G.; Zacchini, S.; Fedi, S.; Zanello, P. Eur. J. Inorg. Chem. 2010, 4831
8. -1, graphite-monochromatized Mo Kα radiation (λ = 0.71073 Å). Further details in SI.
9. -1, graphite-monochromatized Mo Kα radiation (λ = 0.71073 Å). Further details in SI.
10. Hogarth, G.; Kabir, S. E.; Nordlander, E. Dalton Trans. 2010, 39, 6153
11. Halet, J.-F.; Evans, D. G.; Mingos, D. M. P. J. Am. Chem. Soc. 1988, 110, 87
12. Wade, K. Adv. Inorg. Chem. Radiochem. 1976, 18, 1
13. Femoni, C.; Iapalucci, M. C.; Longoni, G.; Zacchini, S. Eur. J. Inorg. Chem. 2010, 1056
14. Ceriotti, A.; Demartin, F.; Heaton, B. T.; Ingallina, P.; Longoni, G.; Manassero, M.; Marchionna, M.; Masciocchi, N. J. Chem. Soc., Chem. Commun. 1989, 786
15. Femoni, C.; Iapalucci, M. C.; Longoni, G.; Tiozzo, C.; Zacchini, S.; Heaton, B. T.; Iggo, J. A. Dalton Trans. 2007, 3914
16. Vidal, J. L.; Troup, J. M. J. Organomet. Chem. 1981, 213, 351
17. Femoni, C.; Iapalucci, M. C.; Longoni, G.; Tiozzo, C.; Zacchini, S.; Heaton, B. T.; Iggo, J. A.; Zanello, P.; Fedi, S.; Garland, M. V.; Li, C. Dalton Trans. 2009, 2217
18. Briant, C. E.; Theobald, B. R. C.; White, J. W.; Bell, L. K.; Mingos, D. M. P. J. Chem. Soc., Chem. Commun. 1981, 201
19. Copley, R. C. B.; Mingos, D. M. P. J. Chem. Soc., Dalton Trans. 1996, 491
20. Copley, R. C. B.; Mingos, D. M. P. J. Chem. Soc., Dalton Trans. 1992, 1755
21. Mingos, D. M. P. J. Chem. Soc., Chem. Commun. 1985, 1352
22. Johansson, M. P.; Pyykkö, P. Chem. Commun. 2010, 46, 3756
23. de Silva, N.; Dahl, L. F. Inorg. Chem. 2005, 44, 9604
24. The covalent scheme is described in ref 21.
25. Nunokawa, K.; Ito, M.; Sunahara, T.; Onaja, S.; Ozeki, T.; Chiba, H.; Funahashi, Y.; Masuda, H.; Yonezawa, T.; Nishihara, H.; Nakamoto, M.; Yamamoto, M. Dalton Trans. 2005, 2726
26. Mingos, D. M. P.; May, A. S. In The Chemistry of Metal Cluster Complexes; Shriver, D. F.; Kaesz, H. D.; Adams, R. D., Eds.; VCH Publishers: New York, 1990; pp 11 - 119.
27. Van der Velden, J. W. A.; Beurskens, P. T.; Bour, J. J.; Bosman, W. P.; Noordik, J. H.; Kolenbrander, N.; Buskes, J. A. K. M. Inorg. Chem. 1984, 23, 146
28. Hall, K. P.; Gilmour, D. J.; Mingos, D. M. P. J. Organomet. Chem. 1984, 268, 275
29. Briant, C. E.; Hall, K. P.; Mingos, D. M. P. J. Chem. Soc., Chem. Commun. 1984, 248
30. Washecheck, D. M.; Wucherer, E. J.; Dahl, L. F.; Ceriotti, A.; Longoni, G.; Manassero, M.; Sansoni, M.; Chini, P. J. Am. Chem. Soc. 1979, 101, 6110
31. 8- herein reported.
32. Teo, B. K. Inorg. Chem. 1984, 23, 1251
33. Teo, B. K.; Longoni, G.; Chung, F. R. K. Inorg. Chem. 1984, 23, 1257
34. Fedi, S.; Zanello, P.; Laschi, F.; Ceriotti, A.; El Afefey, S. J. Solid State Electrochem. 2009, 13, 1497
35. Femoni, C.; Iapalucci, M. C.; Longoni, G.; Tiozzo, C.; Zacchini, S. Angew. Chem., Int. Ed. 2008, 137, 483
36. Zhu, M.; Aikens, C. M.; Hollander, F. J.; Schatz, G. C.; Jin, R. J. Am. Chem. Soc. 2008, 130, 5883
37. Qian, H.; Eckenhoff, W. T.; Zhu, Y.; Pintauer, T.; Jin, R. J. Am. Chem. Soc. 2010, 132, 8280
38. Jadzinsky, P. D.; Calero, G.; Ackerson, C. J.; Bushnell, D. A.; Komberg, R. D. Science 2007, 318, 430
39. Jansen, M. Angew. Chem., Int. Ed. Engl. 1987, 26, 1098
40. Longoni, G.; Iapalucci, M. C. In Clusters and Colloids; Schmid, G., Ed.; VCH: Weinheim, 1994; pp 91 - 177.