Nanostructured Pt and Pt-Sn catalysts supported on oxidized carbon nanotubes for ethanol and ethylene glycol electro-oxidation

International Journal of Hydrogen Energy

Volumn 36, Issue 5, 2011, Pages 3313-3321

  Sieben, J M ^a   Duarte, M M E ^a  

^a UNIVERSIDAD NACIONAL DEL SUR   (Argentina)

Author keywords

Electrodeposition; Ethanol and ethylene glycol electro oxidation; Nanostructured catalysts; Pt Sn alloys

Indexed keywords

ALCOHOL OXIDATION; BIMETALLIC CATALYSTS; C-C BONDS; CARBON SUBSTRATES; COMPOSITION RANGES; GLYCOL OXIDATION; LATTICE PARAMETERS; METAL NANOPARTICLES; NANO-STRUCTURED; NANO-STRUCTURED CATALYST; OXYGEN-CONTAINING SPECIES; POTENTIOSTATIC PULSE; PT ATOMS; PT-SN ALLOYS; ROOM TEMPERATURE; SEM; SINGLE-PHASE MATERIALS; SN-CATALYST; SYNERGISTIC EFFECT; TEM; TIN CONTENT; XRD; XRD ANALYSIS;

ADSORPTION; AGGLOMERATION; ALLOYS; CARBON NANOTUBES; CHRONOAMPEROMETRY; CYCLIC VOLTAMMETRY; ELECTROCATALYSTS; ELECTRODEPOSITION; ELECTRONIC STRUCTURE; ETHANOL; ETHYLENE; ETHYLENE GLYCOL; GRAIN BOUNDARIES; METAL ANALYSIS; OXIDATION; OXYGEN; PLATINUM; PLATINUM ALLOYS; REACTION INTERMEDIATES; SULFURIC ACID; TIN; TIN ALLOYS;

CATALYST SUPPORTS;

EID: 79952242966     PISSN: 03603199     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ijhydene.2010.12.020     Document Type: Article

References (58)

1. T. Iwasita W. Vielstich, Handbook of fuel cells Fundamentals, Technology and applications Vol. 2 2003 John Wiley & Sons New York
2. Z.D. Wei, and S.H. Chan Electrochemical deposition of PtRu on an uncatalyzed carbon electrode for methanol electrooxidation J Electroanal Chem 569 2004 23 33
3. J.M. Song, K. Miyatake, H. Uchida, and M. Watanabe Investigation of direct methanol fuel cell performance of sulfonated polyimide membrane Electrochim Acta 51 2006 4497 4504
4. L. An, T.S. Zhao, S.Y. Shen, Q.X. Wu, and R. Chen Performance of a direct ethylene glycol fuel cell with an anion-exchange membrane Int J Hydrogen Energy 35 2010 4329 4335
5. S. Rousseau, C. Coutanceau, C. Lamy, and J.-M. Léger Direct ethanol fuel cell (DEFC): electrical performances and reaction products distribution under operating conditions with different platinum-based anodes J Power Sourc 158 2006 18 24 (Pubitemid 43867967)
6. A.B. Anderson, S. Seong, and E. Grantscharova Molecular orbital investigation of water reactions with tin hydroxide complexes in association with platinum electrodes J Phys Chem 100 1996 17535 17538 (Pubitemid 126787081)
7. E. Antolini, F. Colmati, and E.R. González Effect of Ru addition on the structural characteristics and the electrochemical activity for ethanol oxidation of carbon supported Pt-Sn alloy catalysts Electrochem Commun 9 2007 398 404 (Pubitemid 46366830)
8. x (M = Sn, Mo, Os or W) electrodes Electrochem Commun 7 2005 703 709 (Pubitemid 40788989)
9. E.V. Spinace, M. Linardi, and A. Oliveira Neto Co-catalytic effect of nickel in the electro-oxidation of ethanol on binary Pt-Sn electrocatalysts Electrochem Commun 7 2005 365 369 (Pubitemid 40385124)
10. P.E. Tsiakaras PtM/C (M = Sn, Ru, Pd, W) based anode direct ethanol-PEMFCs: structural characteristics and cell performance J Power Sourc 171 2007 107 112 (Pubitemid 47332978)
11. W. Zhou, Z. Zhou, S. Song, W. Li, G. Sun, and P. Tsiakaras Pt based anode catalysts for direct ethanol fuel cells Appl Catal B 46 2003 273 285 (Pubitemid 37332302)
12. F. Kadirgan, A.M. Kannan, T. Atilan, S. Beyhan, S.S. Ozenler, and S. Suzer Carbon supported nano-sized Pt-Pd and Pt-Co electrocatalysts for proton exchange membrane fuel cells Int J Hydrogen Energy 34 2009 9450 9460
13. T. Lopes, E. Antolini, and E.R. Gonzalez Carbon supported Pt-Pd alloy as an ethanol tolerant oxygen reduction electrocatalyst for direct ethanol fuel cells Int J Hydrogen Energy 33 2008 5563 5570
14. H. Zhu, Y. Liu, L. Shen, Y. Wei, Z. Guo, and H. Wang Microwave heated polyol synthesis of carbon supported PtAuSn/C nanoparticles for ethanol electrooxidation Int J Hydrogen Energy 35 2010 3125 3128
15. S.Y. Shen, T.S. Zhao, and J.B. Xu Carbon supported PtRh catalysts for ethanol oxidation in alkaline direct ethanol fuel cell Int J Hydrogen Energy 35 2010 12911 12917
16. H.E. Hoster, T. Iwasita, E. Baumgrtner, and W. Vielstich Pt-Ru model catalysts for anodic methanol oxidation: influence of structure and composition on the reactivity Phys Chem Chem Phys 3 2001 337 346 (Pubitemid 32162150)
17. 1-x/Ru(0001) surface alloys-formation and atom distribution Phys Chem Chem Phys 10 2008 3812 3823
18. M.S. Löffler, H. Natter, R. Hempelmann, and K. Wippermann Preparation and characterisation of Pt-Ru model electrodes for the direct methanol fuel cell Electrochim Acta 48 2003 3047 3051
19. A. Lima, C. Coutanceau, J.-M. Léger, and C. Lamy Investigation of ternary catalysts for methanol electrooxidation J Appl Electrochem 31 2001 379 386 (Pubitemid 32427623)
20. C.R.K. Rao, and D.C. Trivedi Chemical and electrochemical depositions of platinum group metals and their applications Coord Chem Rev 249 2005 613 631 (Pubitemid 40222764)
21. M.M.E. Duarte, A.S. Pilla, J.M. Sieben, and C.E. Mayer Platinum particles electrodeposition on carbon substrates Electrochem Commun 8 2006 159 164 (Pubitemid 43006176)
22. M.F. García, J.M. Sieben, M.M.E. Duarte, and C.E. Mayer Methanol/air fuel cells: catalytic aspects and experimental diagnostics Int J Hydrogen Energy 33 2008 3517 3521
23. R. Alcalá, J.W. Shabaker, G.W. Huber, M.A. Sanchez-Castillo, and J.A. Dumesic Experimental and Dft studies of the conversion of ethanol and acetic acid on PtSn-based catalysts J Phys Chem B 109 2005 2074 2085
24. F. Colmati, E. Antolini, and E.R. Gonzalez Ethanol oxidation on carbon supported pt-sn electrocatalysts prepared by reduction with formic acid J Electrochem Soc 154 2007 B39 B47
25. W. Watanabe, and S. Motoo Electrocatalysis by ad-atoms: part II. Enhancement of the oxidation of methanol on platinum by ruthenium ad-atoms J Electroanal Chem 60 1975 267 273
26. F. Vigier, C. Coutanceau, F. Hahn, E.M. Belgsir, and C. Lamy On the mechanism of ethanol electro-oxidation on Pt and PtSn catalysts: electrochemical and in situ IR reflectance spectroscopy studies J Electroanal Chem 563 2004 81 89
27. S.Q. Song, W.J. Zhou, Z.H. Zhou, L.H. Jiang, G.Q. Sun, and Q. Xin Direct ethanol PEM fuel cells: the case of platinum based anodes Int J Hydrogen Energy 30 2005 995 1001
28. Y.H. Chu, and Y.G. Shul Combinatorial investigation of Pt-Ru-Sn alloys as an anode electrocatalysts for direct alcohol fuel cells Int J Hydrogen Energy 35 2010 11261 11270
29. D.R. Lycke, and E.L. Gyenge Electrochemically assisted organosol method for Pt-Sn nanoparticle synthesis and in situ deposition on graphite felt support: extended reaction zone anodes for direct ethanol fuel cells Electrochim Acta 52 2007 4287 4298 (Pubitemid 46357536)
30. L. Jiang, G. Sun, Z. Zhou, W. Zhou, and Q. Xin Preparation and characterization of PtSn/C anode electrocatalysts for direct ethanol fuel cell Catal Today 93-95 2004 665 670
31. A.R. Boccaccini, J. Cho, J.A. Roether, B.J.C. Thomas, E.J. Minay, and M.S.P. Shaffer Electrophoretic deposition of carbon nanotubes Carbon 44 2006 3149 3160 (Pubitemid 44634404)
32. J.M. Sieben, M.M.E. Duarte, and C.E. Mayer Supported Pt and Pt-Ru catalysts prepared by potentiostatic electrodeposition for methanol electrooxidation J Appl Electrochem 38 2008 483 490
33. x catalysts by spectroscopic and diffraction methods J Appl Electrochem 31 2001 793 798 (Pubitemid 32694140)
34. A.K. Shukla, A.S. Arico, K.M. El Khatib, H. Kim, P.L. Antonucci, and V. Antonucci An X-ray photoelectron spectroscopic study on the effect of Ru and Sn additions to platinised carbons Appl Surf Sci 137 1999 20 29
35. M. Zhu, G. Sun, and Q. Xin Effect of alloying degree in PtSn catalyst on the catalytic behavior for ethanol electro-oxidation Electrochim Acta 54 2009 1511 1518
36. S.S. Gupta, S. Singh, and J. Datta Promoting role of unalloyed Sn in PtSn binary catalysts for ethanol electro-oxidation Mater Chem Phys 116 2009 223 228
37. F. Gloaguen, J.-M. Léger, C. Lamy, A. Marmann, U. Stimming, and R. Vogel Platinum electrodeposition on graphite: electrochemical study and STM imaging Electrochim Acta 44 1999 1805 1816
38. J.V. Zoval, J. Lee, S. Gorer, and R.M. Penner Electrochemical preparation of platinum nanocrystallites with size selectivity on basal plane oriented graphite surfaces J Phys Chem B 102 1998 1166 1175 (Pubitemid 128576862)
39. L.M. Plyasova, I.Yu. Molina, A.N. Gavrilov, S.V. Cherepanova, O.V. Cherstiouk, and N.A. Rudina Electrodeposited platinum revisited: tuning nanostructure via the deposition potential Electrochim Acta 51 2006 4477 4488 (Pubitemid 43732442)
40. E.R. Savinova, F. Hahn, and N. Alonso-Vante The assessment of nanocrystalline surface defects on real versus model catalysts probed via vibrational spectroscopy of adsorbed CO Surf Sci 603 2009 1892 1899
41. A.N. Gavrilov, E.R. Savinova, P.A. Simonov, V.I. Zaikovskii, S.V. Cherepanova, and G.A. Tsirlina On the influence of the metal loading on the structure of carbon-supported PtRu catalysts and their electrocatalytic activities in CO and methanol electrooxidation Phys Chem Chem Phys 9 2007 5476 5489
42. A.J. Bard, and C.R. Faulkner Electrochemical methods, fundamentals and applications 2nd ed. 2001 Wiley & Sons Inc. New York
43. J.M. Sieben, M.M.E. Duarte, and C.E. Mayer Pt-Ru supported electrodes deposited by multiple successive cycles of potentiostatic pulses: evaluation of nafion film effect on methanol oxidation J Solid State Electrochem 14 2010 1555 1563
44. D. Wolf, V. Yamakov, S.R. Phillpot, A. Mukherjee, and H. Gleiter Deformation of nanocrystalline materials by molecular-dynamics simulation: relationship to experiments Acta Materialia 53 2005 1 40
45. J.F.E. Gootzen, A.H. Wonders, A.P. Cox, W. Visscher, and J.A.R. van Veen On the adsorbates formed during the platinum catalyzed (electro)oxidation of ethanol, 1,2-ethanediol and methyl-α-image-glucopyranoside at high pH J Mol Catal A: Chem 127 1997 113 131 (Pubitemid 28012547)
46. S. Sun, M. Chojak Halseid, M. Heinen, Z. Jusys, and R.J. Behm Ethanol electrooxidation on a carbon-supported Pt catalyst at elevated temperature and pressure: a high-temperature/high-pressure DEMS study J Power Sourc 190 2009 2 13
47. N. Fujiwara, K.A. Friedrich, and U. Stimming Ethanol oxidation on PtRu electrodes studied by differential electrochemical mass spectrometry J Electroanal Chem 472 1999 120 125
48. G.A. Camara, R.B. de Lima, and T. Iwasita The influence of PtRu atomic composition on the yields of ethanol oxidation: a study by in situ FTIR spectroscopy J Electroanal Chem 585 2005 128 131 (Pubitemid 41436475)
49. R. Ianniello, V.M. Schmidt, J.L. Rodríguez, and E. Pastor Electrochemical surface reactions of intermediates formed in the oxidative ethanol adsorption on porous Pt and PtRu J Electroanal Chem 471 1999 167 179
50. J.P.I. de Souza, S.L. Queiroz, K. Bergamaski, E.R. Gonzalez, and F.C. Nart Electro-oxidation of ethanol on Pt, Rh, and PtRh electrodes. A study using DEMS and in-situ FTIR techniques J Phys Chem B 106 2002 9825 9830 (Pubitemid 35382746)
51. C. Lamy, E.M. Belgsir, and J.-M. Léger Electrocatalytic oxidation of aliphatic alcohols: application to the direct alcohol fuel cell (DAFC) J Appl Electrochem 31 2001 799 809 (Pubitemid 32694141)
52. H. Hitmi, E.M. Belgsir, J.-M. Leger, C. Lamy, and R.O. Lezna A kinetic analysis of the electro-oxidation of ethanol at a platinum electrode in acid medium Electrochim Acta 39 1994 407 415
53. 3Sn catalysts: a quantitative DEMS study J Power Sourc 154 2006 351 359 (Pubitemid 43343789)
54. H. Wang, Z. Jusys, and R.J. Behm Electrochemical oxidation kinetics and mechanism of ethylene glycol on a carbon supported Pt catalyst: a quantitative DEMS study J Electroanal Chem 595 2006 23 36 (Pubitemid 44233608)
55. B. Wieland, J.P. Lancaster, C.S. Hoaglund, P. Holota, and W.J. Tornquist electrochemical and infrared spectroscopic quantitative determination of the platinum-catalyzed ethylene glycol oxidation mechanism at CO adsorption potentials Langmuir 12 1996 2594 2601 (Pubitemid 126567815)
56. A. Dailey, J. Shin, and C. Korzeniewski Ethylene glycol electrochemical oxidation at platinum probed by ion chromatography and infrared spectroscopy Electrochim Acta 44 1998 1147 1152 (Pubitemid 128410136)
57. 2 Nat Mater 8 2009 325 330
58. S. Schauermann, J. Hoffmann, V. Johánek, J. Hartmann, J. Libuda, and H.-J. Freund Catalytic activity and poisoning of specific sites on supported metal nanoparticles Angew Chem Int Ed 41 2002 2532 2535 (Pubitemid 34808669)