Rhodium-catalyzed α-methylthiolation reaction of unactivated ketones using 1,2-diphenyl-2-methylthio-1-ethanone for the methylthio transfer reagent

Tetrahedron

Volumn 67, Issue 12, 2011, Pages 2305-2312

  Arisawa, Mieko ^a   Toriyama, Fumihiko ^b   Yamaguchi, Masahiko ^a  

^a TOHOKU UNIVERSITY   (Japan)

^b DAIICHI SANKYO CO   (Japan)

Author keywords

C H activation; Equilibrium; Ketone; Methylthiolation; Rhodium catalyst

Indexed keywords

1,2 BIS(DIPHENYLPHOSPHINO)ETHANE; 1,2 DIPHENYL 2 METHYLTHIO 1 ETHANONE; ACETONITRILE DERIVATIVE; ALDEHYDE; ALPHA PHENYLKETONE; BENZYL CYANIDE; CARBON; DIMETHYL DISULFIDE; KETONE; KETONE DERIVATIVE; PHENYLACETIC ACID; PHOSPHINE DERIVATIVE; RHODIUM; RHODIUM COMPLEX; THIOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; METHYLATION; METHYLTHIOLATION; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY; SUBSTITUTION REACTION; SYNTHESIS; THERMODYNAMICS;

EID: 79952193638     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2011.01.071     Document Type: Article

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